NiO Nanoparticles Via Calcination of Dithiocarbamate Pioneers: Characterization and Photocatalytic Activity

Year 2024, , 969 - 978, 31.12.2024

Ayşegül Şenocak , Hüseyin Akbaş , Beyza İşgör

https://doi.org/10.17798/bitlisfen.1485060

Abstract

By this work, the preparation of NiO nanoparticles (NPs) from a dithiocarbamate complex through calcination, both a cost-effective and practical way for NPs synthesis, was presented. This preparation process involves the decomposition of the precursor to yield highly pure and crystalline NPs. The dithiocarbamate complex was synthesized in a sequential reaction starting from p-anisaldehyde and 3-aminopropanol. Particle size of the NPs, whose formation was confirmed by FT-IR spectroscopy and UV-Vis spectroscopy, were calculated as 10.97 nm using Debye-Scherer equation from X-ray Diffraction Spectroscopy (XRD). In addition, Scanning Electron Microscopy (SEM) revealed generally aggregated and spherical particles, which are stable in colloidal environment according to -15.1 zeta potential value. Besides, the NPs were employed as a photocatalyst for the decomposition of Methylene Blue (MB), one of the most frequently used synthetic dyes in industry and, at the same time, one of the primary water pollutants, resulting in 38% degradation rate.

Keywords

Dithiocarbamates, NiO nanoparticles, Calcination, Photocatalytic activity, Methylene blue

Ethical Statement

The study is complied with research and publication ethics.

Supporting Institution

TUBİTAK

Project Number

TUBİTAK 2209-A-1919B012206215

Thanks

The authors would like to thank to TUBİTAK (the Scientific and Technological Research Council of Türkiye) for supporting this study through the 2209-A Research Project Support Programme for Undergrad-uate Students (Project Number: 1919B012206215).

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