Research Article
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Green Synthesıs Of Cosmetıc Soaps Obtaıned From Laurel Nobılıs

Year 2024, , 1099 - 1110, 31.12.2024
https://doi.org/10.17798/bitlisfen.1517262

Abstract

In this study, Laurel nobilis oil was obtained from Laurel nobilis fruits. Qualitative analysis of Laurel fixed oil was performed by GC-MS. Additionally, saponification value (SV), acid value (AV), free fatty acid value (% FFA) and peroxide value (PV) values of bay Laurel oil were determined as 140.0 mg KOH/g, 26.5 mg KOH/g, 13.25 mg KOH/g, and 10.28 meq O2/kg, respectively. Activated carbon was obtained as a result of carbonization of the Laurel fruit seeds, which were waste as a result of oil extraction, at 500 oC. Activated carbon was characterized by FT-IR, BET, SEM and TGA. Soap is made of different fatty acid salts, either sodium or potassium. The obtained Laurel fruit oil and activated carbon were used in the preparation of solid soaps with peeling effect by the cold process method. pH, foam test, total alkaline test, and total fatty matter determination (TFM) of the prepared soaps were determined. Thus, the synthesis of activated carbon with peeling effect, which has good cleaning and foaming properties, was carried out.

Ethical Statement

The study is complied with research and publication ethics.

Supporting Institution

Dicle Universityscientific research project commission (DÜBAP)

Project Number

Project Number: FEN.23.024

Thanks

The authors thank Dicle Universityscientific research project commission (DÜBAP) for support with the project number (Project Number: FEN.23.024).

References

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  • H. Y. Nchimbi, “Quantitative and qualitative assessment on the suitability of seed oil from water plant (Trichilia emetica) for soap making,” Saudi J. Biol. Sci., vol. 27, no. 11, pp. 3161–3168, 2020.
  • K. O. Boadu, M. A. Anang, and S. K. Kyei, “Chemical characterization of shea butter oil soap (Butyrospermum parkii G. Don),” Int. J. Dev. Sustain., vol. 6, pp. 1282–1292, 2017.
  • Y. B. Yurtlu, E. Yesiloglu, and F. Arslanoglu, “Physical properties of bay laurel seeds,” Int. Agrophys., vol. 24, pp. 325–328, 2010.
  • B. Sırıken, C. Yavuz, and A. Güler, “Antibacterial Activity of Laurus nobilis: A review of literature,” Med. Sci. Discov., vol. 5, no. 11, pp. 374–379, 2018.
  • O. Elkıran, E. Akbaba, and E. Bagcı, “Constituents of essential oils from leaves and seeds of Laurus nobilis L.: A chemotaxonomic approach,” Bangl. J. Bot., vol. 47, no. 4, pp. 893–901, 2018.
  • E. Jayasathya and A. U. Santhoskumar, “Manufacture of activated carbon soap from areca nut shells,” Int. J. Eng. Appl. Sci. Technol., vol. 4, no. 12, pp. 261–264, 2020.
  • M. Sajjad, R. Sarwar, T. Ali, L. Khan, and S. U. R. Mahmood, “Cosmetic uses of activated charcoal,” Int. J. Community Med. Public Health, vol. 8, no. 9, pp. 4572–4574, 2021.
  • A. A. Warra, “Sesame (Sesamum indicum L.) seed oil: Methods of extraction and its prospects in cosmetic industry—a review,” Bayero J. Pure Appl. Sci., vol. 4, no. 2, pp. 164–168, 2011.
  • J. K. C. Nduka, P. O. Omozuwa, and O. E. Imanah, “Effect of heating time on the physicochemical properties of selected vegetable oils,” Arab. J. Chem., vol. 14, pp. 103063, 2021.
  • H. K. Yağmur and İ. Kaya, “Synthesis and characterization of magnetic ZnCl₂-activated carbon produced from coconut shell for the adsorption of methylene blue,” J. Mol. Struct., vol. 1232, p. 130071, 2021.
  • S. Berneckė, “Analysis of free fatty acids in soap samples by means of gas chromatography-mass spectrometry,” Chemija, vol. 24, no. 4, pp. 307–311, 2013.
  • “Saponification Process,” From Nature With Love. [Online]. Available: https://www.fromnaturewithlove.com/resources/sapon.asp. [Accessed: Dec. 26, 2024].
  • Z. Guoliang, “Bamboo charcoal handmade soap and preparation technology thereof,” U.S. Patent, 2016.
  • “Charcoal Soap,” Soapy Friends. [Online]. Available: https://soapyfriends.com/charcoal-soap/. [Accessed: Dec. 26, 2024].
  • I. Vermaak, G. P. P. Kamatou, B. Komane-Mofokeng, A. M. Viljoen, and K. Beckett, “African seed oils of commercial importance—Cosmetic applications,” South Afr. J. Bot., vol. 77, pp. 920–933, 2011.
  • A. B. Asen, B. A. Ikyenge, D. T. Nyiatagher, and J. T. Ageh, “Chemical analysis of Citrullus lanatus (Thunb.), Cucumeropsis mannii (Naud.), and Telfairia occidentalis (Hook. f.) seeds oils,” J. Appl. Sci. Res., vol. 6, no. 3, pp. 265–268, 2010.
  • X. Yu, Q. Li, D. Sun, X. Dong, and T. Wang, “Determination of the peroxide value of edible oils by FTIR spectroscopy using polyethylene films,” Anal. Methods, vol. 7, no. 5, 2014.
  • Z. Wu, J. Wei, T. Jiao, Q. Chen, M. Oyama, Q. Chen, and X. Chen, “A lead-based room-temperature phosphorescent metal–organic framework sensor for assessing the peroxide value of edible oils,” Food Chem., vol. 385, p. 132710, 2022.
  • A. C. S. A. Anconi, N. C. S. Brito, and C. A. Nunes, “Determination of peroxide value in edible oils based on digital image colorimetry,” J. Food Compos. Anal., vol. 113, p. 104724, 2022.
  • E. Ghohestani, J. Tashkhourian, and B. Hemmateenejad, “Colorimetric determination of peroxide value in vegetable oils using a paper-based analytical device,” Food Chem., vol. 403, p. 134345, 2023.
  • E. Derwich, Z. Benziane, and A. Boukir, “Chemical composition and antibacterial activity of leaves essential oil of Laurus nobilis from Morocco,” Aust. J. Basic Appl. Sci., vol. 3, no. 4, pp. 3818–3824, 2009.
  • S. Pakdeechot and L. Kaewsichan, “Tamanu and coconut oil blends for soap making from extraction of Tamanu kernel with coconut milk,” Eng. Appl. Sci. Res., vol. 47, no. 4, pp. 414–421, Oct.-Dec. 2020.
  • I. Owoicho, “Quality assessment of soaps produced from bleached palm oil and Moringa oleifera seed oil,” Glob. J. Eng. Technol. Adv., vol. 7, no. 1, pp. 001–005, 2021.
  • M. F. Zubair, O. Atolani, S. O. Ibrahim, O. S. Oguntoye, H. A. Abdulrahim, R. A. Oyegoke, and G. A. Olatunji, “Chemical and biological evaluations of potent antiseptic cosmetic products obtained from Momordica charantia seed oil,” Sust. Chem. Pharm., vol. 9, pp. 35–41, 2018.
  • B. Antonić and D. Dordević, “Physicochemical characterization of home-made soap from waste-used frying oils,” Processes, vol. 8, p. 1219, 2020.
  • J. Abba, I. Y. Magaji, H. O. Opara, and D. I. Onyemachi, “Determination of alkali content and total fatty matter of some soaps used within Zaria, Nigeria,” Niger. Res. J. Chem. Sci., vol. 9, no. 2, 2021.
  • K. J. Betsy, Mary Jilu, R. Fathima, and J. T. Varkey, “Determination of alkali content & total fatty matter in cleansing agents,” Asian J. Sci. Appl. Technol., vol. 2, no. 1, pp. 8–12, 2013.
  • M. Kamaraj, T. G. Nithya, S. Shyamalagowri, J. Aravind, and R. Mythili, “Activated carbon derived from almond tree dry leaves waste for enhanced multi dye removal from aqueous solutions,” Mater. Lett., vol. 308, p. 131216, 2022.
  • B. Belhamdi, H. Laksaci, C. Belabed, Z. Merzougui, S. Boudia, R. Tir, and M. Trari, “Synthesis of highly porous activated carbon derived from kernel oil treatment by-products of Argania spinosa as a recyclable adsorbent for amoxicillin removal from real wastewater,” Biomass Convers. Biorefinery, vol. 13, no. 3, pp. 1–15, 2021.
  • S. J. Rajasekaran and V. Raghavan, “Facile synthesis of activated carbon derived from Eucalyptus globulus seed as efficient electrode material for supercapacitors,” Diamond Relat. Mater., vol. 109, p. 108038, 2020.
  • A. Ikhtiar Bakti and P. L. Gareso, “Characterization of activated carbon prepared from coconut shells using FTIR, XRD and SEM techniques,” J. Ilmiah Pendidikan Fisika Al-BiRuNi, vol. 7, no. 1, pp. 33–39, 2018.
Year 2024, , 1099 - 1110, 31.12.2024
https://doi.org/10.17798/bitlisfen.1517262

Abstract

Project Number

Project Number: FEN.23.024

References

  • O. Atolani, E. T. Olabiyi, A. A. Issa, H. T. Azeez, E. G. Onoja, S. O. Ibrahim, M. F. Zubair, O. S. Oguntoye, and G. A. Olatunji, “Green synthesis and characterisation of natural antiseptic soaps from the oils of underutilised tropical seed,” Sust. Chem. Pharm., vol. 4, pp. 32–39, 2016.
  • H. Y. Nchimbi, “Quantitative and qualitative assessment on the suitability of seed oil from water plant (Trichilia emetica) for soap making,” Saudi J. Biol. Sci., vol. 27, no. 11, pp. 3161–3168, 2020.
  • K. O. Boadu, M. A. Anang, and S. K. Kyei, “Chemical characterization of shea butter oil soap (Butyrospermum parkii G. Don),” Int. J. Dev. Sustain., vol. 6, pp. 1282–1292, 2017.
  • Y. B. Yurtlu, E. Yesiloglu, and F. Arslanoglu, “Physical properties of bay laurel seeds,” Int. Agrophys., vol. 24, pp. 325–328, 2010.
  • B. Sırıken, C. Yavuz, and A. Güler, “Antibacterial Activity of Laurus nobilis: A review of literature,” Med. Sci. Discov., vol. 5, no. 11, pp. 374–379, 2018.
  • O. Elkıran, E. Akbaba, and E. Bagcı, “Constituents of essential oils from leaves and seeds of Laurus nobilis L.: A chemotaxonomic approach,” Bangl. J. Bot., vol. 47, no. 4, pp. 893–901, 2018.
  • E. Jayasathya and A. U. Santhoskumar, “Manufacture of activated carbon soap from areca nut shells,” Int. J. Eng. Appl. Sci. Technol., vol. 4, no. 12, pp. 261–264, 2020.
  • M. Sajjad, R. Sarwar, T. Ali, L. Khan, and S. U. R. Mahmood, “Cosmetic uses of activated charcoal,” Int. J. Community Med. Public Health, vol. 8, no. 9, pp. 4572–4574, 2021.
  • A. A. Warra, “Sesame (Sesamum indicum L.) seed oil: Methods of extraction and its prospects in cosmetic industry—a review,” Bayero J. Pure Appl. Sci., vol. 4, no. 2, pp. 164–168, 2011.
  • J. K. C. Nduka, P. O. Omozuwa, and O. E. Imanah, “Effect of heating time on the physicochemical properties of selected vegetable oils,” Arab. J. Chem., vol. 14, pp. 103063, 2021.
  • H. K. Yağmur and İ. Kaya, “Synthesis and characterization of magnetic ZnCl₂-activated carbon produced from coconut shell for the adsorption of methylene blue,” J. Mol. Struct., vol. 1232, p. 130071, 2021.
  • S. Berneckė, “Analysis of free fatty acids in soap samples by means of gas chromatography-mass spectrometry,” Chemija, vol. 24, no. 4, pp. 307–311, 2013.
  • “Saponification Process,” From Nature With Love. [Online]. Available: https://www.fromnaturewithlove.com/resources/sapon.asp. [Accessed: Dec. 26, 2024].
  • Z. Guoliang, “Bamboo charcoal handmade soap and preparation technology thereof,” U.S. Patent, 2016.
  • “Charcoal Soap,” Soapy Friends. [Online]. Available: https://soapyfriends.com/charcoal-soap/. [Accessed: Dec. 26, 2024].
  • I. Vermaak, G. P. P. Kamatou, B. Komane-Mofokeng, A. M. Viljoen, and K. Beckett, “African seed oils of commercial importance—Cosmetic applications,” South Afr. J. Bot., vol. 77, pp. 920–933, 2011.
  • A. B. Asen, B. A. Ikyenge, D. T. Nyiatagher, and J. T. Ageh, “Chemical analysis of Citrullus lanatus (Thunb.), Cucumeropsis mannii (Naud.), and Telfairia occidentalis (Hook. f.) seeds oils,” J. Appl. Sci. Res., vol. 6, no. 3, pp. 265–268, 2010.
  • X. Yu, Q. Li, D. Sun, X. Dong, and T. Wang, “Determination of the peroxide value of edible oils by FTIR spectroscopy using polyethylene films,” Anal. Methods, vol. 7, no. 5, 2014.
  • Z. Wu, J. Wei, T. Jiao, Q. Chen, M. Oyama, Q. Chen, and X. Chen, “A lead-based room-temperature phosphorescent metal–organic framework sensor for assessing the peroxide value of edible oils,” Food Chem., vol. 385, p. 132710, 2022.
  • A. C. S. A. Anconi, N. C. S. Brito, and C. A. Nunes, “Determination of peroxide value in edible oils based on digital image colorimetry,” J. Food Compos. Anal., vol. 113, p. 104724, 2022.
  • E. Ghohestani, J. Tashkhourian, and B. Hemmateenejad, “Colorimetric determination of peroxide value in vegetable oils using a paper-based analytical device,” Food Chem., vol. 403, p. 134345, 2023.
  • E. Derwich, Z. Benziane, and A. Boukir, “Chemical composition and antibacterial activity of leaves essential oil of Laurus nobilis from Morocco,” Aust. J. Basic Appl. Sci., vol. 3, no. 4, pp. 3818–3824, 2009.
  • S. Pakdeechot and L. Kaewsichan, “Tamanu and coconut oil blends for soap making from extraction of Tamanu kernel with coconut milk,” Eng. Appl. Sci. Res., vol. 47, no. 4, pp. 414–421, Oct.-Dec. 2020.
  • I. Owoicho, “Quality assessment of soaps produced from bleached palm oil and Moringa oleifera seed oil,” Glob. J. Eng. Technol. Adv., vol. 7, no. 1, pp. 001–005, 2021.
  • M. F. Zubair, O. Atolani, S. O. Ibrahim, O. S. Oguntoye, H. A. Abdulrahim, R. A. Oyegoke, and G. A. Olatunji, “Chemical and biological evaluations of potent antiseptic cosmetic products obtained from Momordica charantia seed oil,” Sust. Chem. Pharm., vol. 9, pp. 35–41, 2018.
  • B. Antonić and D. Dordević, “Physicochemical characterization of home-made soap from waste-used frying oils,” Processes, vol. 8, p. 1219, 2020.
  • J. Abba, I. Y. Magaji, H. O. Opara, and D. I. Onyemachi, “Determination of alkali content and total fatty matter of some soaps used within Zaria, Nigeria,” Niger. Res. J. Chem. Sci., vol. 9, no. 2, 2021.
  • K. J. Betsy, Mary Jilu, R. Fathima, and J. T. Varkey, “Determination of alkali content & total fatty matter in cleansing agents,” Asian J. Sci. Appl. Technol., vol. 2, no. 1, pp. 8–12, 2013.
  • M. Kamaraj, T. G. Nithya, S. Shyamalagowri, J. Aravind, and R. Mythili, “Activated carbon derived from almond tree dry leaves waste for enhanced multi dye removal from aqueous solutions,” Mater. Lett., vol. 308, p. 131216, 2022.
  • B. Belhamdi, H. Laksaci, C. Belabed, Z. Merzougui, S. Boudia, R. Tir, and M. Trari, “Synthesis of highly porous activated carbon derived from kernel oil treatment by-products of Argania spinosa as a recyclable adsorbent for amoxicillin removal from real wastewater,” Biomass Convers. Biorefinery, vol. 13, no. 3, pp. 1–15, 2021.
  • S. J. Rajasekaran and V. Raghavan, “Facile synthesis of activated carbon derived from Eucalyptus globulus seed as efficient electrode material for supercapacitors,” Diamond Relat. Mater., vol. 109, p. 108038, 2020.
  • A. Ikhtiar Bakti and P. L. Gareso, “Characterization of activated carbon prepared from coconut shells using FTIR, XRD and SEM techniques,” J. Ilmiah Pendidikan Fisika Al-BiRuNi, vol. 7, no. 1, pp. 33–39, 2018.
There are 32 citations in total.

Details

Primary Language English
Subjects Physical Chemistry (Other)
Journal Section Araştırma Makalesi
Authors

Hatice Yağmur 0000-0002-3728-1825

Kübra Baykara

Seyithan Sönmez

Project Number Project Number: FEN.23.024
Early Pub Date December 30, 2024
Publication Date December 31, 2024
Submission Date July 16, 2024
Acceptance Date October 14, 2024
Published in Issue Year 2024

Cite

IEEE H. Yağmur, K. Baykara, and S. Sönmez, “Green Synthesıs Of Cosmetıc Soaps Obtaıned From Laurel Nobılıs”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol. 13, no. 4, pp. 1099–1110, 2024, doi: 10.17798/bitlisfen.1517262.

Bitlis Eren University
Journal of Science Editor
Bitlis Eren University Graduate Institute
Bes Minare Mah. Ahmet Eren Bulvari, Merkez Kampus, 13000 BITLIS