[1] Ma, J., Su, Y., Zhou, Y., Zhang, Z. (2003). Simulation and prediction on the performance of a vehicle’s hydrogen engine. Int. J. Hydrogen Energy, 28, 77-83.
[2] Williams, MV., Russell Kunz, H., Fenton, JM. (2005). Analysis of polarization curves to evaluate polarization sources in hydrogen/air PEM fuel cells. Electrochem. Soc., 152(3), A635-A644.
[3] Xu, H., Russell Kunz, HR., Fenton, JM. (2007). Analysis of proton exchange membrane fuel cell polarization losses at elevated temperature 120 C and reduced relative humidity. Electrochim Acta, 52, 3525–33.
[4] Das, V., Padmanaban, S., Venkitusamy, K., Selvamuthukumaran, R., Blaabjerg, F., Siano, P. (2017). Recent advances and challenges of fuel cell based power system architectures and control–A review. Renewable and Sustainable Energy Review, 73, 10-18.
[5] Zoulias, E. I., Lymberopoulos, N. (2007). Techno-economic analysis of the integration of hydrogen energy technologies in renewable energy-based stand-alone power systems. Renewable Energy, 32(4), 680–696.
[6] Dursun, E., Kilic, O. (2012). Comparative evaluation of different power management strategies of a stand-alone PV/Wind/PEMFC hybrid power system. Electrical Power and Energy Syst, 34(1), 81–89.
[7] Bezmalinović, D., Barbir, F., Tolj, I. (2013). Techno-economic analysis of PEM fuel cells role in photovoltaic-based systems for the remote base stations. Int. J. Hydrogen Energy, 38(1), 417-425.
[8] Hosseini, M., Dincer, I. Rosen, M. A. (2013). Hybrid solar-fuel cell combined heat and power systems for residential applications: Energy and exergy analyses. J. Power Sources, 221, 372-380.
[9] Schlesinger, H.I., Brown, H.C., Finholt A.E., Gilbreath, J.R., et al., (1953). Sodium borohydride, its hydrolysis and its use as a reducing agent and in the generation of hydrogen. J. Am. Chem. Soc.,
[11] Hua, D., Hanxi, Y., Xinping, A., Chuansin, C. (2003). Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst. Int. J. Hydrogen Energy, 28, 1095-1100.
[12] Richardson, BS., Birdwell, JF., Pin, FG., Jansen, JF., Lind, RF. (2005). Sodium borohydride based hybrid power system. J. Power Sources, 145, 21-29.
[13] İnger, E., Özdemir, Z., Yaşar, İ., Tırıs, M., Bahar, T., San, FGB. (2006). Sodyum borhidrür üretimi ve doğrudan sodyum borhidrürlü yakıt pili üretimi ve entegrasyonu. Türkiye 10. Enerji Kongresi, 27-30 Kasım, İstanbul.
[14] Kojima, Y., Suzuki, K., Kawai Y. (2006). Hydrogen generation from lithium borohydride solution over nano-sized platinum dispersed on LiCoO2. J. Power Sources, 155, 325-328.
[15] Wee, J-H., Lee. K-Y., Kim, S.H. (2006). Sodium borohydride as the hydrogen supplier for proton exchange membrane fuelcell systems. Fuel Processing Technology, 87, 811-819.
[16] Marrero-Alfonso, E.Y., Gray, J.R., Davis, T.A., Matthews, M.A. (2007). Minimizing water utilization in hydrolysis of sodium borohydride: The role of sodium metaborate hydrates. Int. J. Hydrogen Energy, 32, 4723-4730.
[17] Sammes, N. Fuel cell technology–reaching towards commercialization. British Library Cataloguing in Publication Data, UK, 2005.
Cell-Based Experimental Analysis of a Proton Exchange Membrane Fuel Cell (PEMFC)
This study is focused on sodium borohydride (NaBH4) and a
cell based experimental analysis of Proton Exchange Membrane (PEM) fuel cell.
By keeping NaBH4, citric acid (C6H8O7)
which is used as a catalyzer and pure water at a static charge, the interchange
of a cell based voltage rating of PEM fuel cell with ten cells at two different
temperatures is evaluated. 3 g NaBH4, H2O/NaBH4: 2 mol/mol
(x=0) and C6H8O7 catalyzer/NaBH4: 0.1 g/g
and 250 cm3 of reactor volume production are realized. When the
water temperature was raised to 60 ºC from 40 ºC, total voltage rating increased 6.1%.
While, in the experiment of 40 ºC, the interchange in voltage ratings are
between 0.53 V and 0.78 V, mean values in the experiment of 60 ºC are between
0.61 V and 0.79 V.
[1] Ma, J., Su, Y., Zhou, Y., Zhang, Z. (2003). Simulation and prediction on the performance of a vehicle’s hydrogen engine. Int. J. Hydrogen Energy, 28, 77-83.
[2] Williams, MV., Russell Kunz, H., Fenton, JM. (2005). Analysis of polarization curves to evaluate polarization sources in hydrogen/air PEM fuel cells. Electrochem. Soc., 152(3), A635-A644.
[3] Xu, H., Russell Kunz, HR., Fenton, JM. (2007). Analysis of proton exchange membrane fuel cell polarization losses at elevated temperature 120 C and reduced relative humidity. Electrochim Acta, 52, 3525–33.
[4] Das, V., Padmanaban, S., Venkitusamy, K., Selvamuthukumaran, R., Blaabjerg, F., Siano, P. (2017). Recent advances and challenges of fuel cell based power system architectures and control–A review. Renewable and Sustainable Energy Review, 73, 10-18.
[5] Zoulias, E. I., Lymberopoulos, N. (2007). Techno-economic analysis of the integration of hydrogen energy technologies in renewable energy-based stand-alone power systems. Renewable Energy, 32(4), 680–696.
[6] Dursun, E., Kilic, O. (2012). Comparative evaluation of different power management strategies of a stand-alone PV/Wind/PEMFC hybrid power system. Electrical Power and Energy Syst, 34(1), 81–89.
[7] Bezmalinović, D., Barbir, F., Tolj, I. (2013). Techno-economic analysis of PEM fuel cells role in photovoltaic-based systems for the remote base stations. Int. J. Hydrogen Energy, 38(1), 417-425.
[8] Hosseini, M., Dincer, I. Rosen, M. A. (2013). Hybrid solar-fuel cell combined heat and power systems for residential applications: Energy and exergy analyses. J. Power Sources, 221, 372-380.
[9] Schlesinger, H.I., Brown, H.C., Finholt A.E., Gilbreath, J.R., et al., (1953). Sodium borohydride, its hydrolysis and its use as a reducing agent and in the generation of hydrogen. J. Am. Chem. Soc.,
[11] Hua, D., Hanxi, Y., Xinping, A., Chuansin, C. (2003). Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst. Int. J. Hydrogen Energy, 28, 1095-1100.
[12] Richardson, BS., Birdwell, JF., Pin, FG., Jansen, JF., Lind, RF. (2005). Sodium borohydride based hybrid power system. J. Power Sources, 145, 21-29.
[13] İnger, E., Özdemir, Z., Yaşar, İ., Tırıs, M., Bahar, T., San, FGB. (2006). Sodyum borhidrür üretimi ve doğrudan sodyum borhidrürlü yakıt pili üretimi ve entegrasyonu. Türkiye 10. Enerji Kongresi, 27-30 Kasım, İstanbul.
[14] Kojima, Y., Suzuki, K., Kawai Y. (2006). Hydrogen generation from lithium borohydride solution over nano-sized platinum dispersed on LiCoO2. J. Power Sources, 155, 325-328.
[15] Wee, J-H., Lee. K-Y., Kim, S.H. (2006). Sodium borohydride as the hydrogen supplier for proton exchange membrane fuelcell systems. Fuel Processing Technology, 87, 811-819.
[16] Marrero-Alfonso, E.Y., Gray, J.R., Davis, T.A., Matthews, M.A. (2007). Minimizing water utilization in hydrolysis of sodium borohydride: The role of sodium metaborate hydrates. Int. J. Hydrogen Energy, 32, 4723-4730.
[17] Sammes, N. Fuel cell technology–reaching towards commercialization. British Library Cataloguing in Publication Data, UK, 2005.
A. Yılmaz, S. Şevik, and R. Yakut, “Cell-Based Experimental Analysis of a Proton Exchange Membrane Fuel Cell (PEMFC)”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol. 8, no. 4, pp. 1446–1457, 2019, doi: 10.17798/bitlisfen.544205.