Doğal Kabak Çekirdeği Kabuğunun Bor Adsorpsiyon Kapasitesi

Year 2020, , 1698 - 1710, 25.12.2020

Hakan Çelebi

https://doi.org/10.17798/bitlisfen.667331

Cited By: 2

Abstract

Endüstriyel gelişmelere bağlı olarak birçok sanayide ve yüzey sularında kullanılan bor bileşiklerinin konsantrasyonu artmaktadır. Bu nedenle bor giderimi hem insan sağlığı hem de sağlıklı tarım ürünü yetiştirilebilmesi açısından oldukça önemlidir. Bu çalışmada, kabak çekirdeği kabuğunun adsorpsiyon kapasitesi araştırılmıştır. Çalışma için, çözeltinin pH‘sının, kabak çekirdeği kabuğu konsantrasyonlarının ve temas süresinin adsorpsiyon sürecine etkisi sabit bir karıştırma hızı (150 rpm) ve sıcaklığı (20 0C) altında değerlendirilmiştir. Ayrıca, kabak çekirdeği kabuğu, taramalı elektron mikroskobu, X ışını floresansı ve Fourier dönüşümü kızılötesi teknikleri kullanılarak tanımlanmıştır. Elde edilen deneysel veriler kesikli proseste farklı izoterm ve kinetik modelleri kullanılarak analiz edilmiştir. Adsorpsiyon işlemi için optimum koşullar adsorbent dozu = 2 g/L, pH = 5.13 ve temas süresi = 5 dakika olarak belirlenmiştir. Kabak çekirdeği kabuğunun maksimum bor arıtma verimi, ideal şartlarda yaklaşık % 88 olarak elde edilmiştir. Langmuir izotermine dayalı maksimum adsorpsiyon kapasitesi 12.61 mg/g şeklinde olup bor elementinin kabak çekirdeği kabuğu üzerine adsorpsiyonu yalancı ikinci derece kinetik ile tanımlanmıştır. Sonuç olarak, bor elementinin, kabak çekirdeği kabuğu kullanılarak sulu çözeltiden etkili bir şekilde çıkarılabileceği kaydedilmiştir.

Keywords

Adsorpsiyon, Bor

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