Co(II) Adsorption onto Ferrous Chloride and Thermally Modified Diatomite: Surface Properties and Adsorption Mechanism

Year 2023, Volume: 12 Issue: 2, 307 - 319, 27.06.2023

Eda Gökırmak Söğüt , Metin Çelebi

https://doi.org/10.17798/bitlisfen.1181379

Abstract

As a potential alternative for heavy metal removal, adsorption using various low-cost materials is one of the most effective methods. This study presents the efficiency of local diatomite modified by ferrous chloride and heat treatment in removing Co(II) from an aqueous solution. The samples were characterized by ICP, XRD, TG-DTA, FTIR, SEM, and BET analyses and the adsorption efficiency of the samples for Co(II) ions was investigated under different factors such as contact time and pH. The adsorption equilibrium was well described by the Langmuir isotherm model, with the maximum adsorption capacities of DA, DM, DM-550°C and DM-850°C at about 18.18 mg L-1, 28.65 mg L-1, 48.30 mg L-1, and 66.22 mg L-1, respectively. The kinetic data were best fitted to the pseudo-second-order model. In addition, ion exchange and electrostatic surface complexation were predicted to play dominant roles in the adsorption mechanism. The results showed that the selected modification methods were effective in removing heavy metals from aqueous solutions, making the samples potentially cost-effective adsorbents to remove the water pollution problem

Keywords

Adsorption, Co (II), Ferrous chloride, Isotherms, Mechanism, Thermal treatment

References

• [1] M. Ferri, S. Campisi, and A. Gervasini, “Nickel and cobalt adsorption on hydroxyapatite: a study for the de-metalation of electronic industrial wastewaters,” Adsorption, vol. 25, no. 3, pp. 649–660, Mar. 2019.
• [2] L. P. Lingamdinne, J. R. Koduru, H. Roh, Y. L. Choi, Y. Y. Chang, and J. K. Yang, “Adsorption removal of Co(II) from waste-water using graphene oxide,” Hydrometallurgy, vol. 165, pp. 90–96, Oct. 2016.
• [3] Y. V. Hete, S. B. Gholase, and R. U. Khope, “Adsorption Study of Cobalt on Treated Granular Activated Carbon” E-Journal Chem., vol. 9, no. 1, pp. 335–339, 2012.
• [4] Y. Aşçi and Ş. Kaya, “Removal of cobalt ions from water by ion-exchange method” New pub Balaban, vol. 52, no. 1–3, pp. 267–273, 2014.
• [5] F. L. Becker, D. Rodríguez, and M. Schwab, “Magnetic Removal of Cobalt from Waste Water by Ferrite Co-precipitation,” Procedia Mater. Sci., vol. 1, pp. 644–650, Jan. 2012.
• [6] B. S. Thaçi and S. T. Gashi, “Reverse Osmosis Removal of Heavy Metalsfrom Wastewater Effluents Using BiowasteMaterials Pretreatment,” Polish J. Environ. Stud., vol. 28, no. 1, pp. 337–341, Nov. 2018.
• [7] N. Tzanetakis, W. M. Taama, K. Scott, R. J. J. Jachuck, R. S. Slade, and J. Varcoe, “Comparative performance of ion exchange membranes for electrodialysis of nickel and cobalt,” Sep. Purif. Technol, vol. 30, no. 2, pp. 113–127, Feb. 2003.
• [8] Ö. Yavuz, Y. Altunkaynak, and F. Güzel, “Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite,” Water Res., vol. 37, no. 4, pp. 948–952, Feb. 2003.
• [9] N. Abdullah, N. Yusof, W. J. Lau, J. Jaafar, and A. F. Ismail, “Recent trends of heavy metal removal from water/wastewater by membrane technologies,” J. Ind. Eng. Chem., vol. 76, pp. 17–38, Aug. 2019.
• [10] S. A. Mirbagheri and S. N. Hosseini, “Pilot plant investigation on petrochemical wastewater treatmentfor the removal of copper and chromium with the objective of reuse,” Desalination, vol. 171, no. 1, pp. 85–93, Jan. 2005.
• [11] Y. Huang, X. Zeng, L. Guo, J. Lan, L. Zhang, and D. Cao, “Heavy metal ion removal of wastewater by zeolite-imidazolate frameworks,” Sep. Purif. Technol., vol. 194, pp. 462–469, Apr. 2018.
• [12] M. Çelebi and E. Gökirmak Söğüt, “High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism,” Turkish J. Chem., vol. 46, no. 5, pp. 1577–1593, Jan. 2022.
• [13] H. Peng and J. Guo, “Removal of chromium from wastewater by membrane filtration, chemical precipitation, ion exchange, adsorption electrocoagulation, electrochemical reduction, electrodialysis, electrodeionization, photocatalysis and nanotechnology: a review,” Environ. Chem. Lett. 186, vol. 18, no. 6, pp. 2055–2068, Jul. 2020.
• [14] E. S. Gokirmak and N. K. Caliskan, “Removal of lead, copper and cadmium ions from aqueous solution using raw and thermally modified diatomite,” Desalin. Water Treat., vol. 58, pp. 154–167, Jan. 2017.
• [15] Y. Fu, X. Xu, Y. Huang, J. Hu, Q. Chen, and Y. Wu, “Preparation of new diatomite–chitosan composite materials and their adsorption properties and mechanism of Hg(II),” R. Soc. Open Sci., vol. 4, no. 12, Dec. 2017.
• [16] E. S. Gökırmak and N. K. Çalışkan, “Isotherm and Kinetic Studies of Pb(II) Adsorption on Raw And Modified Diatomite By Using Non-Linear Regression Method,” Fresenius Environ. Bull., vol. 26, no. 4, pp. 2720–2728, 2017.
• [17] M. Šljivić, I. Smičiklas, S. Pejanović, and I. Plećaš, “Comparative study of Cu2+ adsorption on a zeolite, a clay and a diatomite from Serbia,” Appl. Clay Sci., vol. 43, no. 1, pp. 33–40, Jan. 2009.
• [18] N. K. Çalışkan, A. R. Kul, S. Alkan, E. S. Gökırmak, and I. Alacabey, “Adsorption of Zinc(II) on diatomite and manganese-oxide-modified diatomite: A kinetic and equilibrium study,” J. Hazard. Mater., vol. 193, pp. 27–36, Oct. 2011.
• [19] E. S. Gökırmak and N. K. Çalışkan, “Equilibrium and Kinetic Studies of a Cationic Dye Adsorption onto Raw Clay,” J. Turk.Chem.Soc. Sect. Chem., vol. 7, no. 3, pp. 713-720, 2020.
• [20] S. By and W. Xiong, “Development and application of ferrihydrite-modified diatomite and gypsum for phosphorus control in lakes and reservoirs,” 2009.
• [21] W. Xiong and J. Peng, “Development and characterization of ferrihydrite-modified diatomite as a phosphorus adsorbent,” Water Res., vol. 42, no. 19, pp. 4869–4877, Dec. 2008.
• [22] W. Xiong, J. Peng, Y. Hu, W. Xiong, J. Peng, and Y. Hu, “Chemical analysis for optimal synthesis of ferrihydrite-modified diatomite using soft X-ray absorption near-edge structure spectroscopy,” PCM, vol. 36, no. 10, pp. 557–566, Dec. 2009.
• [23] R. Goren, T. Baykara, and M. Marsoglu, “A study on the purification of diatomite in hydrochloric acid,” Scand. J. Metall., vol. 31, no. 2, pp. 115–119, Apr. 2002.
• [24] M. K. Faizi, A. B. Shahriman, M. S. A Majid, al -, K. Progo, and Y. Fahmiati, “Characteristics of Iron Sand Magnetic Material from Bugel Beach, Kulon Progo, Yogyakarta,” IOP Conf. Ser. Mater. Sci. Eng., vol. 172, no. 1, p. 012020, Feb. 2017.
• [25] J. M. Rimsza, R. E. Jones, and L. J. Criscenti, “Interaction of NaOH solutions with silica surfaces,” J. Colloid Interface Sci., vol. 516, pp. 128–137, Apr. 2018.
• [26] O. Heiri, A. F. Lotter, and G. Lemcke, “Loss on ignition as a method for estimating organic and carbonate content in sediments: reproducibility and comparability of results,” J. Paleolimnol. 2001 251, vol. 25, no. 1, pp. 101–110, 2001.
• [27] R. Zheng, Z. Ren, H. Gao, A. Zhang, and Z. Bian, “Effects of calcination on silica phase transition in diatomite,” J. Alloys Compd., vol. 757, pp. 364–371, Aug. 2018.
• [28] Q. Zhang, T. Zhang, T. He, and L. Chen, “Removal of crystal violet by clay/PNIPAm nanocomposite hydrogels with various clay contents,” Appl. Clay Sci., vol. 90, pp. 1–5, Mar. 2014.
• [29] J. Madejová, W. P. Gates, and S. Petit, “IR Spectra of Clay Minerals,” Dev. Clay Sci., vol. 8, pp. 107–149, Jan. 2017.
• [30] H. Aguiar, J. Serra, P. González, and B. León, “Structural study of sol–gel silicate glasses by IR and Raman spectroscopies,” J. Non. Cryst. Solids, vol. 355, no. 8, pp. 475–480, Apr. 2009.
• [31] B. B. Zviagina, V. A. Drits, and O. V. Dorzhieva, “Distinguishing Features and Identification Criteria for K-Dioctahedral 1M Micas (Illite-Aluminoceladonite and Illite-Glauconite-Celadonite Series) from Middle-Infrared Spectroscopy Data,” Miner. 2020, Vol. 10, Page 153, vol. 10, no. 2, p. 153, Feb. 2020.
• [32] B. A. Gaweł, A. Ulvensøen, K. Łukaszuk, A. M. F. Muggerud, and A. Erbe, “In situ high temperature spectroscopic study of liquid inclusions and hydroxyl groups in high purity natural quartz,” Miner. Eng., vol. 174, p. 107238, Dec. 2021.
• [33] K. Khivantsev, N. R. Jaegers, L. Kovarik, M. A. Derewinski, J. H. Kwak, and J. Szanyi, “On the Nature of Extra-Framework Aluminum Species and Improved Catalytic Properties in Steamed Zeolites,” Mol. 2022, Vol. 27, Page 2352, vol. 27, no. 7, p. 2352, Apr. 2022.
• [34] L. T. Zhuravlev, “The surface chemistry of amorphous silica. Zhuravlev model,” Colloids Surfaces A Physicochem. Eng. Asp., vol. 173, no. 1–3, pp. 1–38, Nov. 2000.
• [35] C. E. Fowler, C. Buchber, B. Lebeau, J. Patarin, C. Delacôte, and A. Walcarius, “An aqueous route to organically functionalized silica diatom skeletons,” Appl. Surf. Sci., vol. 253, no. 12, pp. 5485–5493, Apr. 2007.
• [36] X. Ye et al., “Modified natural diatomite and its enhanced immobilization of lead, copper and cadmium in simulated contaminated soils,” J. Hazard. Mater., vol. 289, pp. 210–218, May 2015.
• [37] M. Aivalioti, I. Vamvasakis, and E. Gidarakos, “BTEX and MTBE adsorption onto raw and thermally modified diatomite,” J. Hazard. Mater., vol. 178, no. 1–3, pp. 136–143, Jun. 2010.
• [38] S. M. Glasauer, P. Hug, P. G. Weidler, and A. U. Gehring, “Inhibition of Sintering by Si During the Conversion of Si-Rich Ferrihydrite to Hematite,” Clays Clay Miner. 2000 481, vol. 48, no. 1, pp. 51–56, Feb. 2000.
• [39] Ç. Üzüm, T. Shahwan, A. E. Eroǧlu, I. Lieberwirth, T. B. Scott, and K. R. Hallam, “Application of zero-valent iron nanoparticles for the removal of aqueous Co2+ ions under various experimental conditions,” Chem. Eng. J., vol. 144, no. 2, pp. 213–220, Oct. 2008.
• [40] V. Srivastava and M. Sillanpää, “Synthesis of malachite@clay nanocomposite for rapid scavenging of cationic and anionic dyes from synthetic wastewater,” J. Environ. Sci., vol. 51, pp. 97–110, Jan. 2017.
• [41] Y. H. Magdy and H. Altaher, “Kinetic analysis of the adsorption of dyes from high strength wastewater on cement kiln dust,” J. Environ. Chem. Eng., vol. 6, no. 1, pp. 834–841, Feb. 2018.
• [42] C. Yao and T. Chen, “A film-diffusion-based adsorption kinetic equation and its application,” Chem. Eng. Res. Des., vol. 119, pp. 87–92, Mar. 2017.
• [43] K. K. H. Choy, D. C. K. Ko, C. W. Cheung, J. F. Porter, and G. McKay, “Film and intraparticle mass transfer during the adsorption of metal ions onto bone char,” J. Colloid Interface Sci., vol. 271, no. 2, pp. 284–295, Mar. 2004.
• [44] W. Fu-Qiang, L. Jian-Jun, and Z. Yi-Min, “Batch and column study: adsorption of Mo(VI) from aqueous solutions using FeCl2-modified fly ash,” New pub Balaban, vol. 51, no. 28–30, pp. 5727–5734, 2013.
• [45] M. H. Salmani, M. Abedi, and S. A. Mozaffari, “Adsorption Efficiency of Iron Modified Carbons for Removal of Pb(II) Ions from Aqueous Solution,” J. Community Heal. Res., vol. 5, no. 2, pp. 140–148, 2016.
• [46] L. Chunhui, T. Jin, Z. Puli, Z. Bin, B. Duo, and L. Xuebin, “Simultaneous removal of fluoride and arsenic in geothermal water in Tibet using modified yak dung biochar as an adsorbent,” R. Soc. Open Sci., vol. 5, no. 11, Nov. 2018.
• [47] R. Qi et al., “Effect of dispersant on the synthesis of cotton textile waste–based activated carbon by FeCl2 activation: characterization and adsorption properties,” Environ. Sci. Pollut. Res., vol. 27, no. 36, pp. 45175–45188, Dec. 2020.
• [48] C. E. R. Barquilha and M. C. B. Braga, “Adsorption of organic and inorganic pollutants onto biochars: Challenges, operating conditions, and mechanisms,” Bioresour. Technol. Reports, vol. 15, p. 100728, Sep. 2021.
• [49] M. Choudhary, R. Kumar, and S. Neogi, “Activated biochar derived from Opuntia ficus-indica for the efficient adsorption of malachite green dye, Cu+2 and Ni+2 from water,” J. Hazard. Mater., vol. 392, p. 122441, Jun. 2020.
• [50] B. Zhao, X. Xu, R. Zhang, and M. Cui, “Remediation of Cu(II) and its adsorption mechanism in aqueous system by novel magnetic biochar derived from co-pyrolysis of sewage sludge and biomass,” Environ. Sci. Pollut. Res., vol. 28, no. 13, pp. 16408–16419, Apr. 2021.
• [51] X. Zhao, H. Feng, P. Jia, Q. An, and M. Ma, “Removal of Cr(VI) from aqueous solution by a novel ZnO-sludge biochar composite,” Environ. Sci. Pollut. Res., vol. 1, pp. 1–15, Jun. 2022.
• [52] E. Gökırmak Söğüt, “Effect of Chemical and Thermal Treatment Priority on Physicochemical Properties and Removal of Crystal Violet Dye from Aqueous Solution,” Chemistry Select, vol. 7, no. 19, p. e202200262, May 2022.