An Investigation of the Strength Properties of Fly Ash and Metakaolin-Based Geopolymer Mortars Containing Multi-Wall Carbon Nanotube, Nano Silica, and Nano Zinc
Year 2023,
Volume: 12 Issue: 3, 842 - 852, 28.09.2023
Maksut Seloğlu
,
Harun Tanyıldızı
,
Mehmet Emin Öncü
Abstract
In this study, the mechanical properties of geopolymer mortar composites containing different nanomaterials were investigated. Metakaolin (MK) and fly ash (FA) were used as binders in geopolymer mortar samples. Sodium silicate (Na2SiO3) and sodium hydroxide (NaOH) solution (12 M) were used as alkali activators. Multi-walled carbon nanotube (MW-CNT), nano-SiO2 (NS), and nano-ZnO (NZ) were used in the study. Geopolymer mortar samples without nanomaterials were determined as control samples, and geopolymer mortar samples containing 0.5% by weight of MW-CNT, NS, and NZ were prepared. All prepared samples were cured at 20±2 °C laboratory conditions for 7 days and 28 days. The curing geopolymer mortar samples were carried out with compressive strength and flexural strength tests. As a result of this study, the mechanical strength of all geopolymer mortar samples containing nanomaterials increased compared to the control samples. The highest compressive strength and flexural strength were obtained from geopolymer mortar samples containing MW-CNT. These samples were followed by geopolymer mortar samples containing NS and NZ, respectively.
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Year 2023,
Volume: 12 Issue: 3, 842 - 852, 28.09.2023
Maksut Seloğlu
,
Harun Tanyıldızı
,
Mehmet Emin Öncü
References
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- [32] U. Durak, O. Karahan, B. Uzal, S. İlkentapar, and C. D. Atiş, “Influence of nano SiO2 and nano CaCO3 particles on strength, workability, and microstructural properties of fly ash‐based geopolymer”, Structural Concrete, 22, E352-E367, 2021.
- [33] B. B. Jindal, “Investigations on the properties of geopolymer mortar and concrete with mineral admixtures: A review”, Construction and building materials, 227, p. 116644, 2019.
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- [35] C. ASTM, “Specification for fly ash and raw or calcined natural pozzolana for use as a material admixture in Portland cement concrete”, pp. 618-78, 1978.
- [36] A. ASTM, “Test method for flexural strength of hydraulic mortar cement”, Annual Book of ASTM Standards C348, 401, 2002.
- [37] C. ASTM, “Standard Test Method for Compressive Strength of Hydraulic-Cement Mortars (Using Portions of Prisms Broken in Flexure)”, ASTM International, pp. 349-02, 2002.
- [38] Z. Zidi, M. Ltifi, Z. B. Ayadi, L. E. Mir, and X. R. Nóvoa, “Effect of nano-ZnO on mechanical and thermal properties of geopolymer”, Journal of Asian Ceramic Societies, vol.8, no. 1, pp. 1-9, 2020.
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- [40] M. Saafi, K. Andrew, P. L. Tang, D. McGhon, S. Taylor, M. Rahman, and X. Zhou, “Multifunctional properties of carbon nanotube/fly ash geopolymeric nanocomposites”, Construction and Building Materials, 49, pp. 46-55, 2013.
- [41] M. A. Kotop, M. S. El-Feky, Y. R. Alharbi, A. A. Abadel, and A. S. Binyahya, “Engineering properties of geopolymer concrete incorporating hybrid nano-materials”, Ain Shams Engineering Journal, vol. 12, no. 4, pp. 3641-3647, 2021.
- [42] P. Nuaklong, V. Sata, A. Wongsa, K. Srinavin, and P. Chindaprasirt, “Recycled aggregate high calcium fly ash geopolymer concrete with inclusion of OPC and nano-SiO2”, Construction and Building Materials, 174, pp. 244-252, 2018.
- [43] G. Quercia, P. Spiesz, G. Hüsken, and H. J. H. Brouwers, “SCC modification by use of amorphous nano-silica”, Cement and Concrete Composites, 45, pp. 69-81, 2014.
- [44] G. Saini and U. Vattipalli, “Assessing properties of alkali activated GGBS based self-compacting geopolymer concrete using nano-silica”, Case Studies in Construction Materials, 12, e00352, 2020.
- [45] P. Rovnaník, H. Šimonová, L. Topolář, P. Schmid, and Z. Keršner, “Effect of carbon nanotubes on the mechanical fracture properties of fly ash geopolymer”, Procedia Engineering, 151, pp. 321-328, 2016.
- [46] M. A. A. Alvi, M. Khalifeh, and M. B. Agonafir, “Effect of nanoparticles on properties of geopolymers designed for well cementing applications”, Journal of Petroleum Science and Engineering, 191, p.107128, 2020.
- [47] M. Oualit, and A. Irekti, “Mechanical performance of metakaolin-based geopolymer mortar blended with multi-walled carbon nanotubes”, Ceramics International, vol. 48, no.11, pp. 16188-16195, 2022.
[48] H. M. Khater, and H. A. Abd el Gawaad, “Characterization of alkali activated geopolymer mortar doped with MWCNT”, Construction and building materials, 102, pp. 329-337, 2016.
- [49] F. Collins, J. Lambert, and W. H. Duan, “The influences of admixtures on the dispersion, workability, and strength of carbon nanotube-OPC paste mixtures”, Cement and Concrete Composites, vol. 34, no. 2, pp. 201-207, 2012.
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- [51] S. M. Mustakim, S. K. Das, J. Mishra, A. Aftab, T. S. Alomayri, H. S. Assaedi, and C. R. Kaze, “Improvement in fresh, mechanical and microstructural properties of fly ash-blast furnace slag based geopolymer concrete by addition of nano and micro silica”, Silicon, 13, pp. 2415-2428, 2021.
- [52] K. Behfarnia, and M. Rostami, “Effects of micro and nanoparticles of SiO2 on the permeability of alkali activated slag concrete”, Construction and building materials, 131, pp. 205-213, 2017.
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