Research Article
BibTex RIS Cite

Synthesis of Co2B nanostructures and their catalytic properties for hydrogen generation

Year 2017, Volume: 2 Issue: 1, 28 - 36, 16.03.2017

Abstract

Pure cobalt
(II) boride nanoparticles/nanocylinders were synthesized in aqueous media under
Argon blanket using cobalt chloride (CoCl2) and sodium borohydride (NaBH4)
as reactants.
CoCl2 (0.325 g) was
dissolved in cold distilled water (DDI) and the solution was introduced into a
sealed glass reactor. Then, NaBH4 was then dissolved in DDI (90 mL)
and the solution was added drop-wise into the reactor and stirred magnetically
at 300 rpm. By the addition of NaBH4 (10 mL, 0.225 g) solution,
amorphous
black cobalt boride particles were synthesized
immediately.
 The presence of crystalline Co2B phase with high purity in
the nanocylinders
which is obtained by calcination at 500oC was shown by X-ray
diffraction spectroscopy. An amorphous Co2B structure was observed with the sample dried under
vacuum. In the synthesis runs, Co2B nanoparticles with different morphological
characteristics were achieved by changing the initial CoCl2
concentration and the reaction period. A microscopic structure in the form of nanocylinders
was observed for the calcined products. The nanocylinder diameter increased
from ca. 30 nm to 100 nm by increasing the reaction time from 3 to 120 min.
CoCl2 initial concentration was also found another factor increasing
the nanocylinder diameter. The nanocylinders with diameters between 80-500 nm were
obtained by increasing CoCl2 concentration from 12.6 to 100.1
mM. The lowest and highest saturation
magnetization values were obtained 19 and 69 emu/g for crystalline sample
calcined under air (Co-Co2B mixture) and amorphous Co2B sample
obtained by vacuum-drying, respectively. Amorphous and crystalline Co2B
samples were used as catalyst for Hydrogen generation by the hydrolysis of NaBH4
in aqueous media. Amorphous Co2B gave significantly higher H2
generation rate with respect to the catalysts prepared by calcination of
amorphous Co2B under air or Argon at 500oC.  The maximum H2 generation rate was
obtained as 1.1 L/g catalyst.min by using amorphous Co2B with
1 % w/w of initial NaBH4 concentration. 

References

  • Akdim A., Demirci U., Muller D., Miele P., Cobalt (II) salts, performing materials for generating hydrogen from sodium borohydride, Int. J. Hydrogen Energy, 34, 2631-2637, 2009.
  • Zhao J., Ma H., Chen J., Improved hydrogen generation from alkaline NaBH4 solution using carbon-supported Co-B as catalysts, Int. J. Hydrogen Energy, 32, 4711-4716, 2007.
  • Ye W., Zhang H., Xu D., Ma L., Yi B., Hydrogen generation utilizing alkaline sodium borohydride solution and supported cobalt catalyst, J. Power Sources, 164, 544-548, 2007.
  • Xu D., Dai P., Liu X., Cao C., Guo Q., Carbon-supported cobalt catalyst for hydrogen generation from alkaline sodium borohydride solution, J. Power Sources, 182, 616-620, 2008.
  • Lin S. S. Y., Kim D. H., Ha S. Y., Hydrogen production from ethanol steam reforming over supported cobalt catalysts, Catal. Lett., 122, 295-301, 2008.
  • Dai H. B., Liang Y., Wang P., Yao X., Rufford T., Lu M., Cheng H., High-performance cobalt–tungsten–boron catalyst supported on Ni foam for hydrogen generation from alkaline sodium borohydride solution, Int. J. Hydrogen Energy, 33, 4405-4412, 2008.
  • Hung T. F., Kuo H. C., Tsai C. W., Chen H. M., Liu R. S., Bing-Jhih Weng B. J., Lee J. F., An alternative cobalt oxide-supported platinum catalyst for efficient hydrolysis of sodium borohydride, J. Mater. Chem., 21, 11754-11759. 2011.
  • Shubhanwita S., Abhirup B., Debnath D., Saibal G., Dipali B., Kajari K., Novel graphene supported Co rich connected core(Pt)-shell(Co) nano-alloy catalyst for improved hydrogen generation and electro-oxidation, Int. J. Hydrogen Energy, 41, (41), 18451–18464, 2016.
  • Yuyao H., Kunyang W., Liang C., Wenxin Z., Abdullah M. A., Xuping S., Effective hydrolysis of sodium borohydride driven by self-supported cobalt oxide nanorod array for on-demand hydrogen generation, Catal. Commun., 87, 94–97, 2016.
  • Netskina O. V., Komova O. V., Simagina V. I., Odegova G.V., Prosvirin I. P., Bulavchenko O. A., Aqueous-alkaline NaBH4 solution: The influence of storage duration of solutions on reduction and activity of cobalt catalysts, Renewable Energy, 99, 1073–1081, 2016.
Year 2017, Volume: 2 Issue: 1, 28 - 36, 16.03.2017

Abstract

References

  • Akdim A., Demirci U., Muller D., Miele P., Cobalt (II) salts, performing materials for generating hydrogen from sodium borohydride, Int. J. Hydrogen Energy, 34, 2631-2637, 2009.
  • Zhao J., Ma H., Chen J., Improved hydrogen generation from alkaline NaBH4 solution using carbon-supported Co-B as catalysts, Int. J. Hydrogen Energy, 32, 4711-4716, 2007.
  • Ye W., Zhang H., Xu D., Ma L., Yi B., Hydrogen generation utilizing alkaline sodium borohydride solution and supported cobalt catalyst, J. Power Sources, 164, 544-548, 2007.
  • Xu D., Dai P., Liu X., Cao C., Guo Q., Carbon-supported cobalt catalyst for hydrogen generation from alkaline sodium borohydride solution, J. Power Sources, 182, 616-620, 2008.
  • Lin S. S. Y., Kim D. H., Ha S. Y., Hydrogen production from ethanol steam reforming over supported cobalt catalysts, Catal. Lett., 122, 295-301, 2008.
  • Dai H. B., Liang Y., Wang P., Yao X., Rufford T., Lu M., Cheng H., High-performance cobalt–tungsten–boron catalyst supported on Ni foam for hydrogen generation from alkaline sodium borohydride solution, Int. J. Hydrogen Energy, 33, 4405-4412, 2008.
  • Hung T. F., Kuo H. C., Tsai C. W., Chen H. M., Liu R. S., Bing-Jhih Weng B. J., Lee J. F., An alternative cobalt oxide-supported platinum catalyst for efficient hydrolysis of sodium borohydride, J. Mater. Chem., 21, 11754-11759. 2011.
  • Shubhanwita S., Abhirup B., Debnath D., Saibal G., Dipali B., Kajari K., Novel graphene supported Co rich connected core(Pt)-shell(Co) nano-alloy catalyst for improved hydrogen generation and electro-oxidation, Int. J. Hydrogen Energy, 41, (41), 18451–18464, 2016.
  • Yuyao H., Kunyang W., Liang C., Wenxin Z., Abdullah M. A., Xuping S., Effective hydrolysis of sodium borohydride driven by self-supported cobalt oxide nanorod array for on-demand hydrogen generation, Catal. Commun., 87, 94–97, 2016.
  • Netskina O. V., Komova O. V., Simagina V. I., Odegova G.V., Prosvirin I. P., Bulavchenko O. A., Aqueous-alkaline NaBH4 solution: The influence of storage duration of solutions on reduction and activity of cobalt catalysts, Renewable Energy, 99, 1073–1081, 2016.
There are 10 citations in total.

Details

Journal Section Articles
Authors

Tuncay Şimşek This is me

Mustafa Barış

Publication Date March 16, 2017
Published in Issue Year 2017 Volume: 2 Issue: 1

Cite

APA Şimşek, T., & Barış, M. (2017). Synthesis of Co2B nanostructures and their catalytic properties for hydrogen generation. Journal of Boron, 2(1), 28-36.