Structural and Optical Properties of Mn doped ZnS Nanoparticles: Sol-gel and Quantum Chemical Studies

Aslı Kaya

doi:10.35193/bseufbd.613777

Structural and Optical Properties of Mn doped ZnS Nanoparticles: Sol-gel and Quantum Chemical Studies

Abstract

A

bstract- In the present work, undoped and Mn-doped ZnS nanoparticles (ZnS:Mn) were growth by the spin coated method at room temperature. The concentration of the Mn ions was changed from 2 to 6%. Different analytical techniques including were used to investigate the influence of Mn concentration on optical properties of produced thin films. In summary, the influence of Mn doping on the optical properties of un-doped ZnS thin films was reported. These results were also compared to the ZnS:Mn thin films produced by different techniques. In UV-Vis. studies, the band gap energy was found to be 3.5–3.8 eV depending on the Mn doping ratio. In addition, undoped and Mn-doped ZnS nanoparticles were theoretically performed as a cluster by semi empirical calculations. In these calculations, the Zn₇S₇and Zn₅Mn₂S₇ were optimized as a hexagonal wurtzite phase structure by semi-empirical pm6 level. The theoretical band gaps for both molecules were calculated with same method.

Keywords

Sol-gel Process,Nanoparticles,Thin Film

References

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Aslı Kaya ^*
0000-0003-2693-6547
Türkiye

Publication Date

December 26, 2019

Submission Date

September 1, 2019

Acceptance Date

November 5, 2019

Published in Issue

Year 2019 Volume: 6 Number: 2

DOI

https://doi.org/10.35193/bseufbd.613777

IZ

https://izlik.org/JA77BC98LT

Cite

RIS / Bibtex

APA

Kaya, A. (2019). Structural and Optical Properties of Mn doped ZnS Nanoparticles: Sol-gel and Quantum Chemical Studies. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 6(2), 629-637. https://doi.org/10.35193/bseufbd.613777

AMA

1.Kaya A. Structural and Optical Properties of Mn doped ZnS Nanoparticles: Sol-gel and Quantum Chemical Studies. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi. 2019;6(2):629-637. doi:10.35193/bseufbd.613777

Chicago

Kaya, Aslı. 2019. “Structural and Optical Properties of Mn Doped ZnS Nanoparticles: Sol-Gel and Quantum Chemical Studies”. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi 6 (2): 629-37. https://doi.org/10.35193/bseufbd.613777.

EndNote

Kaya A (December 1, 2019) Structural and Optical Properties of Mn doped ZnS Nanoparticles: Sol-gel and Quantum Chemical Studies. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi 6 2 629–637.

IEEE

[1]A. Kaya, “Structural and Optical Properties of Mn doped ZnS Nanoparticles: Sol-gel and Quantum Chemical Studies”, Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, vol. 6, no. 2, pp. 629–637, Dec. 2019, doi: 10.35193/bseufbd.613777.

ISNAD

Kaya, Aslı. “Structural and Optical Properties of Mn Doped ZnS Nanoparticles: Sol-Gel and Quantum Chemical Studies”. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi 6/2 (December 1, 2019): 629-637. https://doi.org/10.35193/bseufbd.613777.

JAMA

1.Kaya A. Structural and Optical Properties of Mn doped ZnS Nanoparticles: Sol-gel and Quantum Chemical Studies. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi. 2019;6:629–637.

MLA

Kaya, Aslı. “Structural and Optical Properties of Mn Doped ZnS Nanoparticles: Sol-Gel and Quantum Chemical Studies”. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, vol. 6, no. 2, Dec. 2019, pp. 629-37, doi:10.35193/bseufbd.613777.

Vancouver

1.Aslı Kaya. Structural and Optical Properties of Mn doped ZnS Nanoparticles: Sol-gel and Quantum Chemical Studies. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi. 2019 Dec. 1;6(2):629-37. doi:10.35193/bseufbd.613777

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