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Yeni bir Sıvı Membran Sistemi (ÇDSM) ile Ağır Metal İyonlarının Ekstraksiyonu

Year 2020, , 329 - 341, 28.06.2020
https://doi.org/10.35193/bseufbd.705604

Abstract

Bu çalışmada, yeni tasarlanmış bir sıvı membran sistemi kullanılarak, Zn2+, Cd2+, Mo6+, Pb2+, Cu2+ ve Fe3+ iyonlarının taşınması ve taşınımı etkileyen faktörler incelenmiştir. Çalışmada, literatürde mevcut diğer sıvı membran tekniklerinden farklı yeni bir yöntem uygulanmıştır. Bu yöntem, donör ve akseptör fazdan ligand taşıyıcısı içeren organik fazın damlacıklar halinde geçirilmesiyle küçük bir farklılık göstermekle beraber, hacimli sıvı membran sistemi ile benzerdir. Sistem “Çok Damlalı Sıvı Membran Sistemi” (ÇDSM) olarak adlandırılmıştır. Bu tekniğin avantajları arasında basit yapı, hareketli parça azlığı, hafif ve taşınabilir olması, esnek çalışma, yüksek membran kapasitesi ve yüksek ayırma faktörü sayılabilir. Bu yeni yöntem ile çalışma süresi, kontaminasyon riski, kullanılan reaktif miktarları ve üretilen atık miktarlarının azaltılması amaçlanmaktadır. Sistem Zn2+, Cd2+, Mo6+, Pb2+, Cu2+ ve Fe3+ iyonlarının sulu çözeltilerden taşınması için uygulanmış ve başarılı sonuçlar elde edilmiştir. Her bir metal iyonu için uygun donör, taşıyıcı ve akseptör çözeltiler ile optimum taşınım koşulları (donör ve akseptör faz derişimleri ile pH’ları, organik faz derişimi, sıcaklık, akış hızı) belirlenmiştir. Ard arda tersinmez I. mertebe reaksiyon varsayımıyla k_1, k_2, C_B^mak, t_B^mak kinetik parametreleri, fazlar arası kütle aktarımı kanunları ile J_d^mak, J_a^mak değerleri ve aktivasyon enerjisi (E_a) değerleri hesaplanmıştır. Sonuçlar, mevcut deneysel çalışmalarda kullanılan ÇDSM sisteminin, ağır metal endüstrilerinin neden olduğu ağır metal iyonlarını gidermek için mükemmel bir alternatif ve ekonomik süreç olabileceğini düşündürmektedir.

Thanks

Bu araştırma çalışması finansal olarak Pamukkale Üniversitesi (Proje No: BAP2011FBE072, BAP2012FBE077) tarafından Bilimsel Araştırma Projesi olarak desteklenmiştir.

References

  • Järup, L. (2003). Hazards of heavy metal contamination. British Medical Bulletin, 68(1), 167-182.
  • Isaac, R. A., Gil, L., Cooperman, A.N., Hulme, K., Eddy, B., Ruiz, M., Jacobson, K., Larson, C., Pancorbo, O.C. (1997). Corrosion in Drinking Water Distribution Systems:  A Major Contributor of Copper and Lead to Wastewaters and Effluents. Environmental Science and Technology, 31, 3198–3203.
  • Xiong, L., Chen, C., Chen, Q., Ni, J. (2011). Adsorption of Pb(II) and Cd(II) from aqueous solutions using titanate nanotubes prepared via hydrothermal method. Journal of Hazardous Materials 189, 741-748
  • Ahluwalia, S. S., Goyal, D., (2005). Removal of heavy metals from waste tea leaves from aqueous solution. Engineering in Life Sciences 5, 158–162.
  • Büyüktuncel, E. (2012). Gelişmiş Ekstraksiyon Teknikleri, Hacettepe Üniversitesi Eczacılık Fakültesi Dergisi 32(2), 209-242.
  • Gürel L., Büyükgüngör H., (2006). Liquid membranes in advanced treatment, Mühendislik ve Fen Bilimleri Dergisi, 2, (30-44).
  • Şenvar, C. (1986). Kimyasal Kinetik ve Makromoleküller,Fizikokimya Cilt IV, Marmara Üniversitesi Yayınları, İstanbul.
  • Erdoğdu, F., Şahmurat, F. (2007). Mathematical fundamentals to determine the kinetic constants of first-order consecutive reactions, Journal of Food Process Engineering, 30, 407-420.
  • Yilmaz, A., Kaya, A., Alpoguz, H.K. , Ersoz, M., Yilmaz, M. (2008). Kinetic analysis of chromium(VI) ions transport through a bulk liquid membrane containing p-tert-butylcalix[4]arene dioxaoctylamide derivative, Seperation and Purification Technology, 59(1), 1–8.
  • Erden, K. E., Donat, R. (2018). Transportation and kinetic analysis of Zn(II) ions via MDLM system containing D2EHPA as carrier, Membrane Water Treatment, 19(1), 23-31.
  • Donat, R., Eyice, M.İ. (2018). Extraction of Cd2+ ions from MDLM System with TNOA carrier, Marmara Fen Bilimleri Dergisi, 4, 467-477.
  • Donat, R., Durmaz, Ö., Cetisli, H. (2015). Transportation and kinetic analysis of Mo(VI) ions through a MDLM system containing TNOA as carrier, Journal of Hazardous Materials, 294, 17–26.
  • Durmaz, Ö. (2016). Sıvı membran tekniği ile bazı ağır metal iyonlarının ekstraksiyonunun incelenmesi, Doktora Tezi, Pamukkale Üniversitesi Fen Bilimleri Enstitüsü, Denizli.
  • Durmaz, Ö., Donat, R., Cetisli, H. (2016). Transportation of Pb(II) ions with D2EHPA as Carrier by MDLM System, International Journal of Innovative Research in Science, Engineering and Technology, 5(12), 47-56.
  • Donat, R., Durmaz, Ö., Cetisli H. (2017). The kinetic analysis of optimization and selective transportation of Cu(II) ions with TNOA as carrier by MDLM system, Chinese Journal of Chemical Engineering, 25, 415–425.
  • Donat, R., Durmaz, Ö. (2019). Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier, Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 9(2), 944-955.
  • Singh, R., Mehta, R., Kumar, V. (2011) Simultaneous removal of copper, nickel and zinc metal ions using bulk liquid membrane system, Desalination, 272 (1-3), 170-173.
  • Nowier, H.G., El-Said, N., Aly, H.F. (2000). Carrier-mediated transport of toxic elements through liquid membranes: Transport of Cd(II) from high salinity chloride medium through supported liquid membrane containing TBP/cyclohexane, Journal of Membrane Science, 177(1-2), 41–47.
  • Kulkarni, P.S., Mahajani, V.V. (2002). Application of liquid emulsion membrane (LEM) process for enrichment of molybdenum from aqueous solutions, Journal of Membrane Science 201, 123–135
  • Suren S., Pachaoren, U., Kheawhom, S. (2014). Simultaneous extraction and stripping of lead ions via a hollow fibersupported liquid membrane: Experiment and modeling. Journal of Industrial and Engineering Chemistry, (20), 2584-2593.
  • Leon, G., Guzman, M.A. (2008). Facilitated transport of copper through bulk liquid membranes containing different carriers: compared kinetic study, Desalination, 223, 330-336.
  • Buonomenna, M.G., Molinari, R., Drioli, E. (2002). Selective mass transfer of iron(II1) in supported liquid membrane using highly acidic extractants, 3-phenyl-4-acyl-5-isoxazolones, Desalination, 148, 257-262.

Extraction of Heavy Metal Ions through a Novel Liquid Membrane System (MDLM)

Year 2020, , 329 - 341, 28.06.2020
https://doi.org/10.35193/bseufbd.705604

Abstract

In this study, the transport and factors affecting the transport of Zn2+, Cd2+, Mo6+, Pb2+, Cu2+ ve Fe3+ ions using a newly designed liquid membrane system were investigated. In the study, a new method, different from other liquid membrane techniques available in the literature, has been applied. This method is similar to the bulk liquid membrane system, as it differs slightly by passing the organic phase containing the ligand carrier from the donor and acceptor phase into droplets. It is called as “Multi Dropped Liquid Membrane System” (MDLM). The advantages of this technique include simple structure, lack of moving parts, light and portable, flexible operation, high membrane capacity and high separation factor. With this new method, it is aimed to reduce the working time, the risk of contamination, the amount of reagents used and the amount of waste produced. The system has been applied for transport of Zn2+, Cd2+, Mo6+, Pb2+, Cu2+ and Fe3+ ions from aqueous solutions and successful results have been obtained. Optimum transport conditions (donor and acceptor phase concentrations and pH, organic phase concentration, temperature, flow rate) were determined with suitable donor, carrier and acceptor solutions for each metal ion. The kinetic parameters k_1, k_2, C_b^max, t_B^maxand activation energy (E_a) were calculated for the interface reactions assuming two consecutive, irreversible first-order reactions, J_d^max, J_a^max were calculated with interphase mass transfer laws. The results suggest that the MDLM system that used in the current experimental studies can be a great alternative and economical process in order to remove the heavy metal ions caused by heavy metal industries.

References

  • Järup, L. (2003). Hazards of heavy metal contamination. British Medical Bulletin, 68(1), 167-182.
  • Isaac, R. A., Gil, L., Cooperman, A.N., Hulme, K., Eddy, B., Ruiz, M., Jacobson, K., Larson, C., Pancorbo, O.C. (1997). Corrosion in Drinking Water Distribution Systems:  A Major Contributor of Copper and Lead to Wastewaters and Effluents. Environmental Science and Technology, 31, 3198–3203.
  • Xiong, L., Chen, C., Chen, Q., Ni, J. (2011). Adsorption of Pb(II) and Cd(II) from aqueous solutions using titanate nanotubes prepared via hydrothermal method. Journal of Hazardous Materials 189, 741-748
  • Ahluwalia, S. S., Goyal, D., (2005). Removal of heavy metals from waste tea leaves from aqueous solution. Engineering in Life Sciences 5, 158–162.
  • Büyüktuncel, E. (2012). Gelişmiş Ekstraksiyon Teknikleri, Hacettepe Üniversitesi Eczacılık Fakültesi Dergisi 32(2), 209-242.
  • Gürel L., Büyükgüngör H., (2006). Liquid membranes in advanced treatment, Mühendislik ve Fen Bilimleri Dergisi, 2, (30-44).
  • Şenvar, C. (1986). Kimyasal Kinetik ve Makromoleküller,Fizikokimya Cilt IV, Marmara Üniversitesi Yayınları, İstanbul.
  • Erdoğdu, F., Şahmurat, F. (2007). Mathematical fundamentals to determine the kinetic constants of first-order consecutive reactions, Journal of Food Process Engineering, 30, 407-420.
  • Yilmaz, A., Kaya, A., Alpoguz, H.K. , Ersoz, M., Yilmaz, M. (2008). Kinetic analysis of chromium(VI) ions transport through a bulk liquid membrane containing p-tert-butylcalix[4]arene dioxaoctylamide derivative, Seperation and Purification Technology, 59(1), 1–8.
  • Erden, K. E., Donat, R. (2018). Transportation and kinetic analysis of Zn(II) ions via MDLM system containing D2EHPA as carrier, Membrane Water Treatment, 19(1), 23-31.
  • Donat, R., Eyice, M.İ. (2018). Extraction of Cd2+ ions from MDLM System with TNOA carrier, Marmara Fen Bilimleri Dergisi, 4, 467-477.
  • Donat, R., Durmaz, Ö., Cetisli, H. (2015). Transportation and kinetic analysis of Mo(VI) ions through a MDLM system containing TNOA as carrier, Journal of Hazardous Materials, 294, 17–26.
  • Durmaz, Ö. (2016). Sıvı membran tekniği ile bazı ağır metal iyonlarının ekstraksiyonunun incelenmesi, Doktora Tezi, Pamukkale Üniversitesi Fen Bilimleri Enstitüsü, Denizli.
  • Durmaz, Ö., Donat, R., Cetisli, H. (2016). Transportation of Pb(II) ions with D2EHPA as Carrier by MDLM System, International Journal of Innovative Research in Science, Engineering and Technology, 5(12), 47-56.
  • Donat, R., Durmaz, Ö., Cetisli H. (2017). The kinetic analysis of optimization and selective transportation of Cu(II) ions with TNOA as carrier by MDLM system, Chinese Journal of Chemical Engineering, 25, 415–425.
  • Donat, R., Durmaz, Ö. (2019). Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier, Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 9(2), 944-955.
  • Singh, R., Mehta, R., Kumar, V. (2011) Simultaneous removal of copper, nickel and zinc metal ions using bulk liquid membrane system, Desalination, 272 (1-3), 170-173.
  • Nowier, H.G., El-Said, N., Aly, H.F. (2000). Carrier-mediated transport of toxic elements through liquid membranes: Transport of Cd(II) from high salinity chloride medium through supported liquid membrane containing TBP/cyclohexane, Journal of Membrane Science, 177(1-2), 41–47.
  • Kulkarni, P.S., Mahajani, V.V. (2002). Application of liquid emulsion membrane (LEM) process for enrichment of molybdenum from aqueous solutions, Journal of Membrane Science 201, 123–135
  • Suren S., Pachaoren, U., Kheawhom, S. (2014). Simultaneous extraction and stripping of lead ions via a hollow fibersupported liquid membrane: Experiment and modeling. Journal of Industrial and Engineering Chemistry, (20), 2584-2593.
  • Leon, G., Guzman, M.A. (2008). Facilitated transport of copper through bulk liquid membranes containing different carriers: compared kinetic study, Desalination, 223, 330-336.
  • Buonomenna, M.G., Molinari, R., Drioli, E. (2002). Selective mass transfer of iron(II1) in supported liquid membrane using highly acidic extractants, 3-phenyl-4-acyl-5-isoxazolones, Desalination, 148, 257-262.
There are 22 citations in total.

Details

Primary Language Turkish
Journal Section Articles
Authors

Kadriye Esen Erden 0000-0002-6108-9489

Ramazan Donat 0000-0002-5701-5030

Publication Date June 28, 2020
Submission Date March 18, 2020
Acceptance Date June 3, 2020
Published in Issue Year 2020

Cite

APA Esen Erden, K., & Donat, R. (2020). Yeni bir Sıvı Membran Sistemi (ÇDSM) ile Ağır Metal İyonlarının Ekstraksiyonu. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 7(1), 329-341. https://doi.org/10.35193/bseufbd.705604