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Production of Sn-Co / CNT Composite Anodes by Pulse Current Method for Lithium Ion Batteries

Year 2016, Volume: 3 Issue: 2, 25 - 29, 16.12.2016

Abstract

The graphite is an anode material which is widely used as commercially for li-ion batteries. Because of
having low capacity, graphite led to investigate alternative materials with higher capacity and good cycle stability. As
an alternative to graphite, tin based electrode materials are of interest due to their high capacity values. In this study
Sn-Co/MWCNT composite electrodes were deposited on copper substrates by using pulse current (PC) plating
technique. The effect of peak current density to the battery performance was studied. As a result of studies, the best
result was obtained in the coatings which were prepared at 60 mAcm-2
peak current density.

References

  • UYSAL, M., Lityum İyon Piller İçin Kesikli Akım Yöntemi İle Kalay Esaslı Kompozit Anotların Geliştirilmesi,Doktora Tezi, Sakarya Üniversitesi, Fen Bilimleri Enstitüsü, 2015
  • ALAF M., GÜLTEKİN D., AKBULUT H., Double phase tinoxide/tin/MWCNT nanocomposite negative electrodes for lithium microbatteries, Microelectronic Engineering, 126, 143-147, 2014
  • SUBRAHMANYAM G., ERMANNO M., FRANCESCO DE A., ENZO Dİ F., REMO PROİETTİ Z., CLAUDİO C., Review on recent progress of nanostructured anode materials for Li-ion batteries, Journal of Power Sources 257, 421–443, 2014.
  • SCROSATİ B., GARCHE J., Lithium batteries: Status, prospects and future Journal of Power Sources, 195, 2419–2430, 2010.
  • MAO, O., TURNERB, R.L., COURTNEYA, I.A., FREDERICKSEN, B.D., BUCKETT, M.I., KRAUSE, L. J., DAHN, J.R., Active/Inactive Nanocomposites as Anodes for Li ‐ Ion Batteries, Journal of Electrochem. Society 2, 3–5, 1999.
  • XİAN-MİNG L., ZHEN DONG H., SEİ W. O., BİAO Z., PENG-C. M., MATTHEW M.F. Y., JANG-K. K., Carbon nanotube (CNT)-based composites as electrode material for rechargeable Li-ion batteries: A review, Composites Science and Technology, 72, 121–144, 2012.
  • ZHANG R., LEE J.Y., LIU Z.L., Pechini process-derived tin oxide and tin oxideegraphite composites for lithium-ion batteries, J Power Sources, 112, 596-605, 2012.
  • SHARMA S., FRANSSON L., SJOSTEDT E., NORDSTROM L., JOHANSSON B., EDSTROM K., A theoretical and experimental study of the lithiation of N-Cu6Sn5 in a lithium-ion battery. J ElectrochemSoc., 150, A330-A334, 2003.
  • VALVO M., LAFONT U., SIMONIN L., KELDER E.M., Sn–Co compound for Li-ion battery made via advanced electrospraying, Journal of Power Sources, 174, 428–434, 2007.
  • CHEN Z., QIAN J., AI X, CAO Y., YAN H., Preparation and electrochemical performance of Sn–Co–C composite as anode material for Li-ion batteries, , Journal of Power Sources, 189, 730–732, 2009.
  • DENNY T., RONNY L., ANDREAS B., Influence of pulse plating parameters on the electrocodeposition of matrix metal nanocomposites, Electrochimica Acta, 52, 7362–7371, 2007.
  • LAJEVARDİ S.A., SHAHRABİ T., Effects of pulse electrodeposition parameters on the properties of Ni–TiO2 nanocomposite coatings, Applied Surface Science, 256, 6775–6781, 2010.
  • CHENA W.X., LEE J.Y., LIU Z., The nanocomposites of carbon nanotube with Sb and SnSb0.5 as Li-ion battery anodes, Carbon, 41, 959-966, 2003.
  • COLINDRES S. C., AGUIR K., SODI F. C., VARGAS L. V., SALAZAR J.M., FEBLES C.G., Ozone Sensing Based on Palladium Decorated Carbon Nanotubes, Sensors 14(4), 6806-6818, 2014.

Lityum İyon Piller için Pulse Akım Yöntemi ile SnCo/CNT Kompozit Anotların Üretimi

Year 2016, Volume: 3 Issue: 2, 25 - 29, 16.12.2016

Abstract

t- Li iyon pilleri için anot malzemesi olarak grafit, ticari olarak yaygın kullanılan malzeme olmasına rağmen,
düşük kapasiteye (372 mAh g-1
) sahip olması daha yüksek kapasiteye ve iyi çevrim kararlılığına sahip alternatif
malzemeleri araştırmaya sebep olmuştur. Grafite alternatif olarak kalay esaslı elektrot malzemeleri yüksek kapasite
değerlerinden dolayı ilgi çekicidir. Bu çalışmada Sn-Co/ÇDKNT kompozit elektrotlar bakır altlıklar üzerine pulse
elektrolitik kaplama yöntemi ile biriktirilmiştir. Pik akım yoğunluğunun pil performansına olan etkileri incelenmiştir.
Yapılan çalışmalar sonucunda en iyi sonuç, 60 mAcm-2 pik akım yoğunluğunda, üretilen kaplamalarda elde edilmiştir.

References

  • UYSAL, M., Lityum İyon Piller İçin Kesikli Akım Yöntemi İle Kalay Esaslı Kompozit Anotların Geliştirilmesi,Doktora Tezi, Sakarya Üniversitesi, Fen Bilimleri Enstitüsü, 2015
  • ALAF M., GÜLTEKİN D., AKBULUT H., Double phase tinoxide/tin/MWCNT nanocomposite negative electrodes for lithium microbatteries, Microelectronic Engineering, 126, 143-147, 2014
  • SUBRAHMANYAM G., ERMANNO M., FRANCESCO DE A., ENZO Dİ F., REMO PROİETTİ Z., CLAUDİO C., Review on recent progress of nanostructured anode materials for Li-ion batteries, Journal of Power Sources 257, 421–443, 2014.
  • SCROSATİ B., GARCHE J., Lithium batteries: Status, prospects and future Journal of Power Sources, 195, 2419–2430, 2010.
  • MAO, O., TURNERB, R.L., COURTNEYA, I.A., FREDERICKSEN, B.D., BUCKETT, M.I., KRAUSE, L. J., DAHN, J.R., Active/Inactive Nanocomposites as Anodes for Li ‐ Ion Batteries, Journal of Electrochem. Society 2, 3–5, 1999.
  • XİAN-MİNG L., ZHEN DONG H., SEİ W. O., BİAO Z., PENG-C. M., MATTHEW M.F. Y., JANG-K. K., Carbon nanotube (CNT)-based composites as electrode material for rechargeable Li-ion batteries: A review, Composites Science and Technology, 72, 121–144, 2012.
  • ZHANG R., LEE J.Y., LIU Z.L., Pechini process-derived tin oxide and tin oxideegraphite composites for lithium-ion batteries, J Power Sources, 112, 596-605, 2012.
  • SHARMA S., FRANSSON L., SJOSTEDT E., NORDSTROM L., JOHANSSON B., EDSTROM K., A theoretical and experimental study of the lithiation of N-Cu6Sn5 in a lithium-ion battery. J ElectrochemSoc., 150, A330-A334, 2003.
  • VALVO M., LAFONT U., SIMONIN L., KELDER E.M., Sn–Co compound for Li-ion battery made via advanced electrospraying, Journal of Power Sources, 174, 428–434, 2007.
  • CHEN Z., QIAN J., AI X, CAO Y., YAN H., Preparation and electrochemical performance of Sn–Co–C composite as anode material for Li-ion batteries, , Journal of Power Sources, 189, 730–732, 2009.
  • DENNY T., RONNY L., ANDREAS B., Influence of pulse plating parameters on the electrocodeposition of matrix metal nanocomposites, Electrochimica Acta, 52, 7362–7371, 2007.
  • LAJEVARDİ S.A., SHAHRABİ T., Effects of pulse electrodeposition parameters on the properties of Ni–TiO2 nanocomposite coatings, Applied Surface Science, 256, 6775–6781, 2010.
  • CHENA W.X., LEE J.Y., LIU Z., The nanocomposites of carbon nanotube with Sb and SnSb0.5 as Li-ion battery anodes, Carbon, 41, 959-966, 2003.
  • COLINDRES S. C., AGUIR K., SODI F. C., VARGAS L. V., SALAZAR J.M., FEBLES C.G., Ozone Sensing Based on Palladium Decorated Carbon Nanotubes, Sensors 14(4), 6806-6818, 2014.
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Fuat Kayış This is me

Publication Date December 16, 2016
Submission Date November 20, 2017
Published in Issue Year 2016 Volume: 3 Issue: 2

Cite

APA Kayış, F. (2016). Lityum İyon Piller için Pulse Akım Yöntemi ile SnCo/CNT Kompozit Anotların Üretimi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 3(2), 25-29.