Epoxy functional spherical polymer beads were synthesized by using precursor concentrated emulsions templates obtained by dispersing aqueous internal phase solution in the monomer mixture composed of glycidyl methacrylate (GMA) and 1,3-butandiol dimethacrylate having flexible groups. For this purpose, high internal phase emulsions (HIPEs) of GMA and BDDMA were obtained with the use of aqueous pullulan solutions as the internal phase. Polymerization step was achieved within the water/oil/water (w/o/w) systems that were prepared by dispersing precursor HIPEs in a secondary aqueous medium. On the other hand, by using aqueous pullulan solutions during the preparation of precursor emulsion templates, a semi-interpenetrating polymer network structure in which each individual phase or network retains their individual properties and causes synergistic interaction, was obtained. The morphological properties of the resulting polymer (polyHIPE) beads were investigated by using microscopic imaging techniques. The specific surface areas were calculated by applying Brunauer–Emmett–Teller (BET) equation to the N2 adsorption/desertion isotherms of the resulting beads.
|Subjects||Engineering, Basic Sciences|
|Supporting Institution||TÜBİTAK, Yalova Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi|
|Project Number||113Z465, 2013/YL/015|
|Thanks||Çalışmamıza sağladıkları destekten ötürü TÜBİTAK’a (TÜBİTAK Proje No: 113Z465) ve Yalova Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi’ne (Proje No: 2013/YL/015)teşekkür ederiz|
: January 8, 2020
|APA||Kekevi̇, B , Mert, E , Çi̇ra, F . (2020). Yüksek İç Fazlı Emülsiyon Kalıplama ile Metakrilat Esaslı Küresel Polimerlerin Hazırlanması . Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi , 7 (1) , 141-151 . DOI: 10.35193/bseufbd.665236|