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Year 2020, Volume 7 , Issue 2, Pages 638 - 648 2020-12-30

Süperkapasitör Uygulamaları için Elektrodepolanmış Kobalt Temelli Filmin Nikel Köpük Elektrot Üzerine Sentezi
Synthesis of Electrodeposition of Cobalt Based Film on a Nickel Foam Electrode for Supercapacitor Applications

Perihan YİLMAZ ERDOGAN [1] , Naime ÖZDEMİR [2] , Hüseyin ZENGİN [3] , Abdulcabbar YAVUZ [4]

Abstract

Bu çalışmada, kobalt temelli film, süperkapasitör uygulamaları için nikel köpük akım toplayıcıları üzerine elektrodepolanmıştır. Kobalt temelli film, -1,5 V'luk sabit bir voltaj uygulanarak doğrudan pirofosfat elektrolitinden nikel köpük üzerine büyütüldü. Kobalt birikiminin döngüsel voltamogram ve kronoamperometrik verileri sunuldu. Elde edilen kobalt temelli modifiye nikel köpük elektrot daha sonra KOH elektrolitine aktarıldı. Kaplanmamış ve kaplanmış nikel köpük elektrotun elektrokimyasal davranışı bazik ortamda karakterize edildi. Kaplanmamış nikel köpük elektrodun elektroaktivitesi, kobalt film ile kaplandığında önemli ölçüde artığı gözlendi. Kobaltla modifiye edilmiş nikel köpük elektrotu KOH elektrolitinde yüksek çevrim kararlılığına sahipti. Kaplanmamış ve kaplanmış nikel köpük elektrotun morfolojisi SEM ile karakterize edildi. Elektrotun 5 ve 100 mV s-1 tarama hızlarındaki spesifik kapasitansı, sırasıyla 538 F g-1 ve 261 F g-1 olarak ölçüldü. Elde edilen kobalt temelli elektrotun hız sınırlayıcı adımı, yüzey kontrollü bir mekanizmaya sahip olduğu gözlendi.

In this study, cobalt-based film was electrodeposited on nickel foam current collectors for supercapacitor applications. The cobalt-based film was grown directly from pyrophosphate electrolyte to nickel foam by applying a constant voltage of -1.5 V. Cyclic voltamogram and chroamperometric data of cobalt deposition were presented. The resulting cobalt based modified nickel foam electrode was then transferred into the KOH electrolyte. Electrochemical behavior of uncoated and coated nickel foam electrode was characterized in alkaline media. Electroactivity of bare nickel foam increased significantly when it was coated with cobalt film. Cobalt modified nickel foam electrode had high cycle stability in KOH. The morphology of uncoated and coated nickel foam electrode was characterized by SEM. The specific capacitance of the electrode at the scan rates of 5 and 100 mV s-1 was measured as 538 F g-1 and 261 F g-1, respectively. The rate-limiting step of the obtained cobalt based electrode had a surface controlled mechanism.

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Details

Primary Language tr
Subjects Engineering
Journal Section Articles
Authors

Orcid: 0000-0002-1375-603X
Author: Perihan YİLMAZ ERDOGAN (Primary Author)
Country: Turkey

Orcid: 0000-0003-4744-1316
Author: Naime ÖZDEMİR
Country: Turkey

Orcid: 0000-0002-5540-725X
Author: Hüseyin ZENGİN
Country: Turkey

Orcid: 0000-0002-7216-0586
Author: Abdulcabbar YAVUZ
Country: Turkey
Thanks Perihan Yilmaz Erdogan ve Naime Ozdemir doktora bursu için YÖK 100-2000 programına teşekkür ederler. Yazarlar, Gaziantep Üniversitesi BAP birimine FEF.DT.19.40 kodlu proje desteği için teşekkür ederler.
Dates

Application Date : July 4, 2019
Acceptance Date : July 6, 2020
Publication Date : December 30, 2020

Cite

APA Yilmaz Erdogan, P , Özdemir, N , Zengin, H , Yavuz, A . (2020). Süperkapasitör Uygulamaları için Elektrodepolanmış Kobalt Temelli Filmin Nikel Köpük Elektrot Üzerine Sentezi . Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi , 7 (2) , 638-648 . DOI: 10.35193/bseufbd.586983
Authors of the Article
Perihan YİLMAZ ERDOGAN [1]
Naime ÖZDEMİR [2]
Hüseyin ZENGİN [3]
Abdulcabbar YAVUZ [4]
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