A comparison of ion-exchange resins and activated carbon in recovering gold from cyanide leach solutions with low levels of copper
Yıl 2022,
, 35 - 41, 18.08.2022
Deus Albert Msumange
Ersin Yener Yazıcı
Oktay Celep
Hacı Deveci
Öz
This study was conducted to determine the effectiveness of three different adsorbents for the adsorption of gold from a real cyanide leach liquor. An activated carbon (NORIT GAC 1240), strong base (Purogold A194), and weak base (Purogold S992) resins were tested as the adsorbents. The pregnant leach solution (PLS) was derived from cyanide leaching (1.5 g/L NaCN, 25% w/w solids ratio, 1.5 L/min air flow rate, pH 10.5 – 11, 24 h) of the roasted copper-rich refractory gold ore pretreated with H2SO4. Gold and copper concentrations in the PLS were analysed to be 26.1 mg/L Au and 62.4 mg/L Cu, respectively. Activated carbon was found to be the best performing adsorbent as it achieved the highest gold loading. Purogold A194 loaded the highest amount of copper amongst the adsorbents tested. Despite the fact that activated carbon loaded a high amount of gold, it was less selective than Purogold S992. Purogold A194 exhibited the lowest selectivity, which was defined as the distribution ratio of gold to copper, compared with Purogold S992 and activated carbon. Therefore, the order of selectivity of the adsorbents tested was as follows: Purogold S992 > Activated carbon > Purogold A194.
Destekleyen Kurum
Karadeniz Technical University
Proje Numarası
FBA-2018-7399
Teşekkür
The authors would like to express their sincere thanks to the Scientific Research Foundation of Karadeniz Technical University for the financial support (Project no: FBA-2018-7399), to PUROLITE for kindly providing resin samples and to Koza Gold Co. (Gümüşhane/Mastra, Turkey) for kindly providing copper-rich gold ore samples.
Kaynakça
- Adams, M. D. 2016. Gold Ore Processing: Project Development and Operations. Elsevier, 15(2).
- Ahlatcı, F., Koç, E., Yazıcı, E., Celep, O., Deveci, H. 2018. Adsorption of heavy metals from waste cyanide solutions with anionic resins, Scientific Mining Journal 57, 17-22.
- Bas, A. D., Yazıcı, E. Y., Deveci, H. 2012. Treatment of copper - rich gold ores by ammonia assisted cyanide leaching. Proceedings of the XXVI International Mineral Processing Congress (IMPC), New Delhi, India, 356−365.
- Bas, A. D., Koç, E., Yazıcı, E. Y., Deveci, H. 2015. Treatment of copper - rich gold ore by cyanide leaching, ammonia pretreatment, and ammoniacal cyanide leaching. Transactions of Nonferrous Metals Society of China 25 (2), 597-607.
- Chryssoulis, S. L., Mcmullen, J. 2016. Mineralogical Investigation of Gold Ores: Gold Ore Processing - Project Development and Operations. Elsevier, 57-93.
- Dai, X., Simons, A., Breuer, P. 2012. A Review of copper cyanide recovery technologies for the cyanidation of copper containing gold ores. Minerals Engineering 25, 1-13.
- Fleming, C. A., Cromberge, G. 1984. The elution of aurocyanide from strong- and weak- base resins. Journal of the South African Institute of Mining and Metallurgy 84(9), 269-280.
- Fleming, C. A., Mezei, A., Bourricaudy, E., Canizares, M., Ashbury, M. 2011. Factors influencing the rate of gold cyanide leaching and adsorption on activated carbon, and their impact on the design of CIL and CIP circuits. Minerals Engineering 24(6), 484–494.
- Habashi, F. 1999. A Textbook of Hydrometallurgy. Metallurgie Extractive Quebec Publications, Canada, 220-223.
- Kotze, M. 2010. Gold ion exchange. ALTA 2010 Gold Conference. ALTA Metallurgical Services, Melbourne, Australia.
- Kotze, M., Green, B., Mackenzie, M., Virnig, M. 2005. Resin - in - Pulp and Resin – in - Solution.: Advances in Gold Ore Processing. Elsevier Science, 15.
- Marsden, J., House, I. 2006. The Chemistry of Gold Extraction. The Society for Mining Metallurgy and Exploration Incorporated, USA 2, 318-392.
- Medusa, 2009. Software for chemical equilibrium diagrams, 32 bit version. Royal Institute of Technology, Sweden.
- Msumange, D. A. 2019. Recovery of gold from copper -rich ores using ion exchange resins. Master Thesis, Karadeniz Technical University, The Graduate School of Natural and Applied Sciences, Department of Mining Engineering, Trabzon.
- Msumange, D. A., Yazıcı, E. Y., Celep, O., Deveci, H. 2020. Investigation of the amenability of a copper - rich refractory gold ore to cyanide leaching. Scientific Mining Journal 59(4), 225-234.
- Msumange, D. A., Yazıcı, E. Y., Celep, O., Deveci, H. 2021. The effectiveness of the adsorbents for selective recovery of gold from copper - bearing cyanide leach solutions. Scientific Mining Journal 60(1), 21-30.
- NORIT. 2003. Data sheet. NORIT GAC 1240, Granular Activated Carbon, Report No: 2201, 2.
- PUROLITE. 2015. Purogold ion exchange resins for metals recovery applications: P - 000033 - 250PP – 0515 - PCO, 2.
- PUROLITE. 2016a. Product data sheet. Purogold A193, 1 August, 1.
- PUROLITE. 2016b. Product data sheet. Purogold S992, 1 August, 1.
- PUROLITE. 2020. Product information. Purolite product guide: P-000023-NPOLD-0120-R2-ENG-PCO, 25.
Sceresini, B. 2005. Gold - Copper Ores. Advances in Gold Ore Processing Developments in Mineral Processing. Elsevier, Amsterdam, 89-824.
- Van Deventer, J. 2014. New developments in ion exchange resins for the recovery of gold from complex ores: Hydrometallurgy. Canadian Institute of Mining, Metallurgy and Petroleum, Montreal, Canada, 677-687.
- Van Deventer, J., Kotze, M., Yahorava, V. 2012. Gold recovery from copper - rich ores employing the Purolite S992 gold - selective ion exchange resin. ALTA 2012 Gold Conference. ALTA Metallurgical Services, Melbourne, Australia, 8.
- Van Deventer, J., Bazhko, V., Yahorava, V. 2014. Comparison of gold - selective ion exchange resins and activated carbon for the recovery of gold from copper gold leach liquors. ALTA 2014 Gold - Precious Metals Conference, ALTA Metallurgical Service, Melbourne, Australia, 18.
- Voiloshnikova, N., Deementyev, V., Voiloshnikov, G., Grigoryeva, I., Moskaeva, N. 2014a. Comparison of anion exchange resins for adsorption processes in the gold industry. XXVII International Mineral Processing Congress, Santiago - Chile, 1-10.
- Yazıcı, E. Y., Ahlatcı, F., Koc, E., Celep, O., Deveci, H. 2015. Pre - treatment of a copper - rich gold ore for elimination of copper interference. 8th European Metallurgical Conference (EMC), Duesseldorf, 2, 601-613.
- Yen, W. T., Aghamirian, M. M. 2002. Effect of sulfide minerals and dissolved ions on gold dissolution. Canadian Institute of Mining, Metallurgy and Petroleum, Montreal, 79-86.
Yıl 2022,
, 35 - 41, 18.08.2022
Deus Albert Msumange
Ersin Yener Yazıcı
Oktay Celep
Hacı Deveci
Proje Numarası
FBA-2018-7399
Kaynakça
- Adams, M. D. 2016. Gold Ore Processing: Project Development and Operations. Elsevier, 15(2).
- Ahlatcı, F., Koç, E., Yazıcı, E., Celep, O., Deveci, H. 2018. Adsorption of heavy metals from waste cyanide solutions with anionic resins, Scientific Mining Journal 57, 17-22.
- Bas, A. D., Yazıcı, E. Y., Deveci, H. 2012. Treatment of copper - rich gold ores by ammonia assisted cyanide leaching. Proceedings of the XXVI International Mineral Processing Congress (IMPC), New Delhi, India, 356−365.
- Bas, A. D., Koç, E., Yazıcı, E. Y., Deveci, H. 2015. Treatment of copper - rich gold ore by cyanide leaching, ammonia pretreatment, and ammoniacal cyanide leaching. Transactions of Nonferrous Metals Society of China 25 (2), 597-607.
- Chryssoulis, S. L., Mcmullen, J. 2016. Mineralogical Investigation of Gold Ores: Gold Ore Processing - Project Development and Operations. Elsevier, 57-93.
- Dai, X., Simons, A., Breuer, P. 2012. A Review of copper cyanide recovery technologies for the cyanidation of copper containing gold ores. Minerals Engineering 25, 1-13.
- Fleming, C. A., Cromberge, G. 1984. The elution of aurocyanide from strong- and weak- base resins. Journal of the South African Institute of Mining and Metallurgy 84(9), 269-280.
- Fleming, C. A., Mezei, A., Bourricaudy, E., Canizares, M., Ashbury, M. 2011. Factors influencing the rate of gold cyanide leaching and adsorption on activated carbon, and their impact on the design of CIL and CIP circuits. Minerals Engineering 24(6), 484–494.
- Habashi, F. 1999. A Textbook of Hydrometallurgy. Metallurgie Extractive Quebec Publications, Canada, 220-223.
- Kotze, M. 2010. Gold ion exchange. ALTA 2010 Gold Conference. ALTA Metallurgical Services, Melbourne, Australia.
- Kotze, M., Green, B., Mackenzie, M., Virnig, M. 2005. Resin - in - Pulp and Resin – in - Solution.: Advances in Gold Ore Processing. Elsevier Science, 15.
- Marsden, J., House, I. 2006. The Chemistry of Gold Extraction. The Society for Mining Metallurgy and Exploration Incorporated, USA 2, 318-392.
- Medusa, 2009. Software for chemical equilibrium diagrams, 32 bit version. Royal Institute of Technology, Sweden.
- Msumange, D. A. 2019. Recovery of gold from copper -rich ores using ion exchange resins. Master Thesis, Karadeniz Technical University, The Graduate School of Natural and Applied Sciences, Department of Mining Engineering, Trabzon.
- Msumange, D. A., Yazıcı, E. Y., Celep, O., Deveci, H. 2020. Investigation of the amenability of a copper - rich refractory gold ore to cyanide leaching. Scientific Mining Journal 59(4), 225-234.
- Msumange, D. A., Yazıcı, E. Y., Celep, O., Deveci, H. 2021. The effectiveness of the adsorbents for selective recovery of gold from copper - bearing cyanide leach solutions. Scientific Mining Journal 60(1), 21-30.
- NORIT. 2003. Data sheet. NORIT GAC 1240, Granular Activated Carbon, Report No: 2201, 2.
- PUROLITE. 2015. Purogold ion exchange resins for metals recovery applications: P - 000033 - 250PP – 0515 - PCO, 2.
- PUROLITE. 2016a. Product data sheet. Purogold A193, 1 August, 1.
- PUROLITE. 2016b. Product data sheet. Purogold S992, 1 August, 1.
- PUROLITE. 2020. Product information. Purolite product guide: P-000023-NPOLD-0120-R2-ENG-PCO, 25.
Sceresini, B. 2005. Gold - Copper Ores. Advances in Gold Ore Processing Developments in Mineral Processing. Elsevier, Amsterdam, 89-824.
- Van Deventer, J. 2014. New developments in ion exchange resins for the recovery of gold from complex ores: Hydrometallurgy. Canadian Institute of Mining, Metallurgy and Petroleum, Montreal, Canada, 677-687.
- Van Deventer, J., Kotze, M., Yahorava, V. 2012. Gold recovery from copper - rich ores employing the Purolite S992 gold - selective ion exchange resin. ALTA 2012 Gold Conference. ALTA Metallurgical Services, Melbourne, Australia, 8.
- Van Deventer, J., Bazhko, V., Yahorava, V. 2014. Comparison of gold - selective ion exchange resins and activated carbon for the recovery of gold from copper gold leach liquors. ALTA 2014 Gold - Precious Metals Conference, ALTA Metallurgical Service, Melbourne, Australia, 18.
- Voiloshnikova, N., Deementyev, V., Voiloshnikov, G., Grigoryeva, I., Moskaeva, N. 2014a. Comparison of anion exchange resins for adsorption processes in the gold industry. XXVII International Mineral Processing Congress, Santiago - Chile, 1-10.
- Yazıcı, E. Y., Ahlatcı, F., Koc, E., Celep, O., Deveci, H. 2015. Pre - treatment of a copper - rich gold ore for elimination of copper interference. 8th European Metallurgical Conference (EMC), Duesseldorf, 2, 601-613.
- Yen, W. T., Aghamirian, M. M. 2002. Effect of sulfide minerals and dissolved ions on gold dissolution. Canadian Institute of Mining, Metallurgy and Petroleum, Montreal, 79-86.