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Petrography and geochemical decomposition parameters of crystalline rocks; Demirköy intrusive body (DIB), NW Turkey

Year 2021, Volume: 165 Issue: 165, 253 - 265, 19.08.2021
https://doi.org/10.19111/bulletinofmre.793795

Abstract

The crystalline rocks represent the most weathering rock groups due to their textural and mineralogical decomposition. This study, focused on the petrographic properties and geochemical variation of the altered rocks from Demirköy Intrusive Body (DIB) located at NW Turkey were examined based on the location of structural and morphological properties. DIB consists of intrusive rocks in the composition of ranging from granite to gabbro. The sampling made from the dominant rock units composing of granodiorite and quartz diorite, within the DIB a cross weathering section divided into three levels as regolit, saprolite and saprock. For each level of all the section Ruxton ratio (Ro), chemical alteration index (CIA), chemical weathering index (CIW), plagioclase alteration index (PIA) were determined. The results show a linear decrease from the surface to the core of the host rock. The chlorite-carbonate-pyrite index (CCPI) versus Ishikawa alteration index (AI) variation diagram shows that decomposition in profiles occurred in diagenetic alteration and where the hydrothermal alteration effect is not observed. On the other hand, Mg, Fe, Ti, Ca decreased remarkably while the ratio of the elements such as Si, Na, K, Al increased. The increasing and decreasing of geochemical elements are related to their physical strength and chemical behavior. The chemical variation diagrams of all the levels revealed that the regolites exhibit chemical compounds from hydrothermal fluids in the immediate vicinity of the source rocks.

Thanks

This study, was carried out within the scope of ‘Turkey’s Pluton Database’ conducted by MTA Geological Research in 2016 - 2017. The authors thank to Ayşegül Aydın (MTA) for supporting field works, Dr. Kıymet Deniz (Ankara University) for her support in the analysis process, Dr. Ebru Kavukçu (MTA) and Arif Talay (MTA) for their contribution in conducting the analyses. The authors also thank to two anonymous referees specially with their suggestions and critics on XRD results and Dr. Hafize Akıllı (MTA) to contribute to the development of the article with their constructive critics.

References

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  • Aydın, Y. 1982. Geology of the Yıldız mountains (Strandja). (Doctoral dissertation, Habilitation thesis, Istanbul Technical University).
  • Aykol, A., Tokel, S. 1991. The geochemistry and tectonic setting of the Demirköy pluton of the Srednogorie - Istranca granitoid chain, NW Turkey. Mineralogical Magazine 55(379), 249-256.
  • Bates, R.L., Jackson, J.A. 1987. Glossary of geology (3rd edition) American Geological Institute, Alexandria, Virginia.
  • Borrelli, L., Greco, R., Gullà, G. 2007. Weathering grade of rock masses as a predisposing factor to slope instabilities: reconnaissance and control procedures. Geomorphology 87(3), 158-175.
  • Boyraz, D., Cangir, C. 2009. Yıldız Orman Ekosisteminde Yer Alan Tipik Toprakların Sınıflandırılması ve Amenajmanları. Journal of Tekirdag Agricultural Faculty 6(1).
  • Catto, S., Cavazza, W., Zattin, M., Okay, A. I. 2018. No significant Alpine tectonic overprint on the Cimmerian Strandja Massif (SE Bulgaria and NW Turkey). International Geology Review 60(4), 513-529.
  • Çağlayan, M. A., Yurtsever, A. 1998. Burgaz-A3, Edirne B-2 ve B-3; Burgaz A-4 ve Kırklareli B-4; Kırklareli B-5 ve B-6; Kırklareli C-6 paftaları, 1:100.000 ölçekli açınsama nitelikli Türkiye Jeoloji haritaları No: 20, 21, 22, 23. Maden Tetkik ve Arama Genel Müdürlüğü, Ankara.
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  • Fedo, C. M., Wayne Nesbitt, H., Young, G. M. 1995. Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols, with implications for paleoweathering conditions and provenance. Geology 23(10), 921-924.
  • Fiantis, D., Nelson, M., Shamshuddin, J., Goh, T. B., Van Ranst, E. 2010. Determination of the geochemical weathering indices and trace elements content of new volcanic ash deposits from Mt. Talang (West Sumatra) Indonesia. Eurasian Soil Science 43(13), 1477-1485.
  • Graham, R. C., O’Geen, A. T. 2010. Soil mineralogy trends in California landscapes. Geoderma 154(3-4), 418-437.
  • Harnois, L. 1988. The CIW index: a new chemical index of weathering. SedG, 55(3), 319-322.
  • Hillel, D. 1998. Environmental Soil Physics, Academic Press, San Diego.
  • Ietto, F., Le Pera, E., Perri, F. 2013. Weathering of the ‘Rupe di Tropea’ (southern Calabria): consolidation criteria and erosion - rate estimate. Rend Online Soc Geol Ital 24, 178-180.
  • Ishikawa, Y., Sawaguchi, T., Iwaya, S., Hariuchi, M. 1976. Delineation of prospecting targets for Kuroko deposits based on modes of volcanism underlying dacite and alteration halos. Mining Geology 26, 105-117.
  • Karacık, Z., Tüysüz, O. 2010. Petrogenesis of the Late Cretaceous Demirköy Igneous Complex in the NW Turkey: implications for magma genesis in the Strandja Zone. Lithos 114(3-4), 369-384.
  • Large, R. R., Gemmell, J. B., Paulick, H., Huston, D. L. 2001. The alteration box plot: A simple approach to understanding the relationship between alteration mineralogy and lithogeochemistry associated with volcanic-hosted massive sulfide deposits. Economic Geology 96(5), 957-971.
  • Meunier, A. 2005. Clays in soils and weathered rocks. Clays 231-293.
  • Migon, P., Thomas, M. F. 2002. Grus weathering mantles - problems of interpretation. Catena 49(1-2), 5-24.
  • Moore, W. J., McKee, E. H., Akıncı, Ö. 1980. Chemistry and chronology of the plutonic rocks in the Pontid Mountains, Northern Turkey. Belgrade: Europe Copper Deposits 209-216.
  • Nahon, D. B. 1991. Introduction to the petrology of soils and chemical weathering. John Wiley and Sons, Inc.
  • Nesbitt, H., Young, G. M. 1982. Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature 299(5885), 715-717.
  • Okay, A. I., Tüysüz, O. 1999. Tethyan sutures of northern Turkey. Geological Society, London, Special Publications 156(1), 475-515.
  • Okay, A. I., Nikishin, A. M. 2015. Tectonic evolution of the southern margin of Laurasia in the Black Sea region. International Geology Review 57, 5-8, 1051-1076.
  • Ollier, C. D. 2010. Very deep weathering and related landslides. Geological Society, London, Engineering Geology Special Publications 23(1), 5-14.
  • Ollier, C., Calcaterra, D., Parise, M. 2007. Studies in weathering and slope movements - an introduction. Geomorphology 3(87), 101-103.
  • Power, E. T., Smith, B. J. 1994. A comparative study of deep weathering and weathering products: case studies from Ireland, Corsica and Southeast Brazil. In “Rock weathering and landform evolution”, 21- 40.
  • Ruxton, B. P. 1968. Measures of the Degree of Chemical Weathering of Rocks,” J. Geol 76, 518-527.
  • Sharma, A., Rajamani, V. 2000. Weathering of gneissic rocks in the upper reaches of Cauvery river, south India: implications to neotectonics of the region. Chemical Geology 166(3-4), 203-223.
  • Taylor, G., Eggleton, R. A. 2001. Regolith geology and geomorphology. John Wiley and Sons.
  • Ulusoy, E. 2012. Demirköy (Kırklareli) intrüzif kayaçlarının jeolojisi ve petrolojisi (Msc thesis, University of Ankara).
  • Ulusoy, E., Kadıoğlu, Y. K. 2015. Temporal and Spatial Position of Magmatic Rocks within Eastern part of Strandja Massif: Demirköy, Kırklareli, NW Turkey. İstanbul Üniversitesi’nde Jeoloji’nin 100. Yılı Sempozyumu Bildiri Özleri Kitabı, 53-54.
  • Üşümezsoy, Ş. 1982. Istranca masifinin petrojenetik evrimi (Doctoral dissertation, PhD Thesis, İstanbul University, Eathsciences Faculty).
  • Velde, B. B., Meunier, A. 2008. The origin of clay minerals in soils and weathered rocks. Springer Science and Business Media.
  • Whalley, W. B., Turkington, A. V. 2001. Weathering and geomorphology. Geomorphology (Amsterdam) 41(1).
  • Williams, N. C., Davidson, G. J. 2004. Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia. Economic Geology 99(5), 987-1002.
Year 2021, Volume: 165 Issue: 165, 253 - 265, 19.08.2021
https://doi.org/10.19111/bulletinofmre.793795

Abstract

References

  • Arias, D., Pando, L., López-Fernández, C., Díaz-Díaz, L. M., Rubio-Ordóñez, Á. 2016. Deep weathering of granitic rocks: A case of tunnelling in NW Spain. Catena 137, 572-580.
  • Aydın, Y. 1982. Geology of the Yıldız mountains (Strandja). (Doctoral dissertation, Habilitation thesis, Istanbul Technical University).
  • Aykol, A., Tokel, S. 1991. The geochemistry and tectonic setting of the Demirköy pluton of the Srednogorie - Istranca granitoid chain, NW Turkey. Mineralogical Magazine 55(379), 249-256.
  • Bates, R.L., Jackson, J.A. 1987. Glossary of geology (3rd edition) American Geological Institute, Alexandria, Virginia.
  • Borrelli, L., Greco, R., Gullà, G. 2007. Weathering grade of rock masses as a predisposing factor to slope instabilities: reconnaissance and control procedures. Geomorphology 87(3), 158-175.
  • Boyraz, D., Cangir, C. 2009. Yıldız Orman Ekosisteminde Yer Alan Tipik Toprakların Sınıflandırılması ve Amenajmanları. Journal of Tekirdag Agricultural Faculty 6(1).
  • Catto, S., Cavazza, W., Zattin, M., Okay, A. I. 2018. No significant Alpine tectonic overprint on the Cimmerian Strandja Massif (SE Bulgaria and NW Turkey). International Geology Review 60(4), 513-529.
  • Çağlayan, M. A., Yurtsever, A. 1998. Burgaz-A3, Edirne B-2 ve B-3; Burgaz A-4 ve Kırklareli B-4; Kırklareli B-5 ve B-6; Kırklareli C-6 paftaları, 1:100.000 ölçekli açınsama nitelikli Türkiye Jeoloji haritaları No: 20, 21, 22, 23. Maden Tetkik ve Arama Genel Müdürlüğü, Ankara.
  • Delvigne, J. 1998. Atlas of micromorphology of mineral alteration and weathering: Ontario Canada Mineralogical Association of Canada and Orstom editions.
  • Fedo, C. M., Wayne Nesbitt, H., Young, G. M. 1995. Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols, with implications for paleoweathering conditions and provenance. Geology 23(10), 921-924.
  • Fiantis, D., Nelson, M., Shamshuddin, J., Goh, T. B., Van Ranst, E. 2010. Determination of the geochemical weathering indices and trace elements content of new volcanic ash deposits from Mt. Talang (West Sumatra) Indonesia. Eurasian Soil Science 43(13), 1477-1485.
  • Graham, R. C., O’Geen, A. T. 2010. Soil mineralogy trends in California landscapes. Geoderma 154(3-4), 418-437.
  • Harnois, L. 1988. The CIW index: a new chemical index of weathering. SedG, 55(3), 319-322.
  • Hillel, D. 1998. Environmental Soil Physics, Academic Press, San Diego.
  • Ietto, F., Le Pera, E., Perri, F. 2013. Weathering of the ‘Rupe di Tropea’ (southern Calabria): consolidation criteria and erosion - rate estimate. Rend Online Soc Geol Ital 24, 178-180.
  • Ishikawa, Y., Sawaguchi, T., Iwaya, S., Hariuchi, M. 1976. Delineation of prospecting targets for Kuroko deposits based on modes of volcanism underlying dacite and alteration halos. Mining Geology 26, 105-117.
  • Karacık, Z., Tüysüz, O. 2010. Petrogenesis of the Late Cretaceous Demirköy Igneous Complex in the NW Turkey: implications for magma genesis in the Strandja Zone. Lithos 114(3-4), 369-384.
  • Large, R. R., Gemmell, J. B., Paulick, H., Huston, D. L. 2001. The alteration box plot: A simple approach to understanding the relationship between alteration mineralogy and lithogeochemistry associated with volcanic-hosted massive sulfide deposits. Economic Geology 96(5), 957-971.
  • Meunier, A. 2005. Clays in soils and weathered rocks. Clays 231-293.
  • Migon, P., Thomas, M. F. 2002. Grus weathering mantles - problems of interpretation. Catena 49(1-2), 5-24.
  • Moore, W. J., McKee, E. H., Akıncı, Ö. 1980. Chemistry and chronology of the plutonic rocks in the Pontid Mountains, Northern Turkey. Belgrade: Europe Copper Deposits 209-216.
  • Nahon, D. B. 1991. Introduction to the petrology of soils and chemical weathering. John Wiley and Sons, Inc.
  • Nesbitt, H., Young, G. M. 1982. Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature 299(5885), 715-717.
  • Okay, A. I., Tüysüz, O. 1999. Tethyan sutures of northern Turkey. Geological Society, London, Special Publications 156(1), 475-515.
  • Okay, A. I., Nikishin, A. M. 2015. Tectonic evolution of the southern margin of Laurasia in the Black Sea region. International Geology Review 57, 5-8, 1051-1076.
  • Ollier, C. D. 2010. Very deep weathering and related landslides. Geological Society, London, Engineering Geology Special Publications 23(1), 5-14.
  • Ollier, C., Calcaterra, D., Parise, M. 2007. Studies in weathering and slope movements - an introduction. Geomorphology 3(87), 101-103.
  • Power, E. T., Smith, B. J. 1994. A comparative study of deep weathering and weathering products: case studies from Ireland, Corsica and Southeast Brazil. In “Rock weathering and landform evolution”, 21- 40.
  • Ruxton, B. P. 1968. Measures of the Degree of Chemical Weathering of Rocks,” J. Geol 76, 518-527.
  • Sharma, A., Rajamani, V. 2000. Weathering of gneissic rocks in the upper reaches of Cauvery river, south India: implications to neotectonics of the region. Chemical Geology 166(3-4), 203-223.
  • Taylor, G., Eggleton, R. A. 2001. Regolith geology and geomorphology. John Wiley and Sons.
  • Ulusoy, E. 2012. Demirköy (Kırklareli) intrüzif kayaçlarının jeolojisi ve petrolojisi (Msc thesis, University of Ankara).
  • Ulusoy, E., Kadıoğlu, Y. K. 2015. Temporal and Spatial Position of Magmatic Rocks within Eastern part of Strandja Massif: Demirköy, Kırklareli, NW Turkey. İstanbul Üniversitesi’nde Jeoloji’nin 100. Yılı Sempozyumu Bildiri Özleri Kitabı, 53-54.
  • Üşümezsoy, Ş. 1982. Istranca masifinin petrojenetik evrimi (Doctoral dissertation, PhD Thesis, İstanbul University, Eathsciences Faculty).
  • Velde, B. B., Meunier, A. 2008. The origin of clay minerals in soils and weathered rocks. Springer Science and Business Media.
  • Whalley, W. B., Turkington, A. V. 2001. Weathering and geomorphology. Geomorphology (Amsterdam) 41(1).
  • Williams, N. C., Davidson, G. J. 2004. Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia. Economic Geology 99(5), 987-1002.
There are 37 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Ezgi Ulusoy This is me 0000-0002-0727-5563

Yusuf Kagan Kadıoğlu 0000-0002-7894-2220

Publication Date August 19, 2021
Published in Issue Year 2021 Volume: 165 Issue: 165

Cite

APA Ulusoy, E., & Kadıoğlu, Y. K. (2021). Petrography and geochemical decomposition parameters of crystalline rocks; Demirköy intrusive body (DIB), NW Turkey. Bulletin of the Mineral Research and Exploration, 165(165), 253-265. https://doi.org/10.19111/bulletinofmre.793795
AMA Ulusoy E, Kadıoğlu YK. Petrography and geochemical decomposition parameters of crystalline rocks; Demirköy intrusive body (DIB), NW Turkey. Bull.Min.Res.Exp. August 2021;165(165):253-265. doi:10.19111/bulletinofmre.793795
Chicago Ulusoy, Ezgi, and Yusuf Kagan Kadıoğlu. “Petrography and Geochemical Decomposition Parameters of Crystalline Rocks; Demirköy Intrusive Body (DIB), NW Turkey”. Bulletin of the Mineral Research and Exploration 165, no. 165 (August 2021): 253-65. https://doi.org/10.19111/bulletinofmre.793795.
EndNote Ulusoy E, Kadıoğlu YK (August 1, 2021) Petrography and geochemical decomposition parameters of crystalline rocks; Demirköy intrusive body (DIB), NW Turkey. Bulletin of the Mineral Research and Exploration 165 165 253–265.
IEEE E. Ulusoy and Y. K. Kadıoğlu, “Petrography and geochemical decomposition parameters of crystalline rocks; Demirköy intrusive body (DIB), NW Turkey”, Bull.Min.Res.Exp., vol. 165, no. 165, pp. 253–265, 2021, doi: 10.19111/bulletinofmre.793795.
ISNAD Ulusoy, Ezgi - Kadıoğlu, Yusuf Kagan. “Petrography and Geochemical Decomposition Parameters of Crystalline Rocks; Demirköy Intrusive Body (DIB), NW Turkey”. Bulletin of the Mineral Research and Exploration 165/165 (August 2021), 253-265. https://doi.org/10.19111/bulletinofmre.793795.
JAMA Ulusoy E, Kadıoğlu YK. Petrography and geochemical decomposition parameters of crystalline rocks; Demirköy intrusive body (DIB), NW Turkey. Bull.Min.Res.Exp. 2021;165:253–265.
MLA Ulusoy, Ezgi and Yusuf Kagan Kadıoğlu. “Petrography and Geochemical Decomposition Parameters of Crystalline Rocks; Demirköy Intrusive Body (DIB), NW Turkey”. Bulletin of the Mineral Research and Exploration, vol. 165, no. 165, 2021, pp. 253-65, doi:10.19111/bulletinofmre.793795.
Vancouver Ulusoy E, Kadıoğlu YK. Petrography and geochemical decomposition parameters of crystalline rocks; Demirköy intrusive body (DIB), NW Turkey. Bull.Min.Res.Exp. 2021;165(165):253-65.

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