Klorin A ve B Türevlerinin Farklı pH'larda H2O2, t-BuOOH ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı

Year 2006, Volume: 1 Issue: 6, 1 - 19, 01.06.2006

Hüseyin Berber, Sedat Yurdakul

Abstract

Keywords

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Klorin A ve B Türevlerinin Farklı pH'larda H2O2, t-BuOOH ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı

Abstract

Bu çalışmada feofitin a ve b, feoforbid a ve b ve klorofilid a ve b pH 1.00-14.00 aralığında oksidantsızve pH 8.00-14.00 aralığında H2O2, t-BuOOH ve NaOCl oksidantlarına karşı karanlıkta, oda sıcaklığındayapısal kararlılıkları incelenmiştir. İncelenen klorin kompleksleri, asidik ortamda (pH8.00) ise kararlı olduğu görülmektedir. Klorin komplekslerinin aynı koşullar altında, NaOCloksidantına göre HO2ve t-BuOOH oksidantlarında daha kararlı olduğu bulunmuştur. Feofitin a bütünoksidantlarda incelenen diğer molekülerden daha kararlı olduğu, H2O2ve t-BuOOH oksidantlarında feofitinb, NaOCl oksidantında ise klorofilid a’nın en kararsız olduğu görülmüştür. Feoforbid a ve b, feofitin a’yagöre kararsız olurken, klorofilid a ve b ve feoforbid b’ye göre daha kararlı olduğu bulunmuştur

Keywords

Klorin a ve b karalılığı, Klorinlerin bozunması, Feofitin, Klorofilid, Feoforbid

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