BibTex RIS Kaynak Göster

Klorin A ve B Türevlerinin Farklı pH'larda H2O2, t-BuOOH ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı

Yıl 2006, Cilt: 1 Sayı: 6, 1 - 19, 01.06.2006

Öz

Kaynakça

  • E.S. Nymon and P.H. Hynninen, Research advances in the use of tetrapyrrolic photosensitizers for photodynamic therapy, Journal of Photochemistry and Photobiology B: Biology, 73 (2004) 1-28.
  • J. Helaja, F. P. Montforts, I. Kilpeläinen, P.H. Hynninen, NH tautomerism in the dimethyl ester of bonellin, a natural chlorin, J. Org. Chem., 64 (1999) 432-437.
  • J. Helaja, M Stapelbroek-Möllmann, I. Kilpeläinen, P.H. Hynninen, NH tautomerism in the a natural chlorin derivatives, J. Org. Chem., 65 (2000) 3700-3707.
  • C. Brükner, Jason R. McCarty, H.W. Daniell, Z.D. Pendon, R.P. Ilagan, T.M. Francis, L.Ren, R.R. Birge, H.A. Frank, A spectroscopic and computational study of the singlet and triplet excited states of synthetic b- functionalized chlorins, Chemical Physics, 294 (2003) 285-303.
  • M.O. Liu, A.T. Hu, Microwave-assisted synthesis of phthalocyanine–porphyrin complex and its photoelectric conversion properties, Journal of Organometallic Chemistry, 689 (2004) 2450-2455.
  • B. Meunier, Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage, Chemical Reviews, 92 (1992) 1411-1456.
  • D. Mansuy, Activation of alkanes: The biomimetic approach, Coordination Chemistry Reviews, 125 (1993) 129-141.
  • Eva R. Birnbaum, Jay A. Labinger, John E. Bercaw, Harry B. Gray, Catalysis of aerobic olefin oxidation by a ruthenium perhaloporphyrine complex, Inorganica Chimica Acta, 270 (1998) 433-439.
  • P. Battioni, E. Cardin, M. Louloudi, B. Schollhorn, G.A. Spyroulias, D. Munsuy, T.G. Traylor, Metalloporphyrinosilicas: A new class of hybrid organic-inorganic materials acting as selective biomimetic oxidation catalysts, Chemical Communications, 17 (1996) 2037-2038.
  • W. Nam, H.J. Han, S.Y. Oh, Y.J. Lee, M.H. Choi, S.Y. Han, C. Kim, S.K. Woo, W. Shin, New insights into the mechanisms of O-O bond cleavage of hydrogen peroxide and tert-alkyl hydroperoxides by iron (III) porphyrin complexes, Journal of The American Chemical Society, 122, (2000) 8677-8684.
  • A. Thellend, P. Battioni, D. Mansuy, Ammonium acetate as a very simle and efficient cocatalyst for manganese porphyrine-catalyzed oxygenation of hydrocarbons by hydrogen-peroxide, Journal of The Chemical Society- Chemical Communications, 9 (1994) 1035-1036.
  • M.C. Prado-Manso Cynthia, A.V. Ednava, F.S. Vinhado, H.C. Sacco, K.J. Ciuffi, P.R. Martins, A.G. Ferreira, J.R. Lindsey-Smith, O.R. Nascimento, Y. Iamamoto, Cynthia, Characterization and catalytic activity of iron (III) mono(4-N-methyl pyridil)-tris(halophenyl) porphyrins in homegeneous and heterogeneous systems, Journal of Molecular Catalysis A: Chemical, 150 (1999) 251-266.
  • W. Nam, Ho J. Lee, So-Young Oh, C. Kim, Ho G., Jang, First success of catalytic epoxidation of olefins by an electron-rich iron(III) porphyrine complex and H2O2: imidazole effect on the activation of H2O2 by iron porphyrine complexs in aprotic solvent, Journal of Inorganic Biochemistry, 80 (2000) 219-225.
  • A.M.D.R. Gonsalves, A.C. Serra, Metalloporphyrin catalytic oxidations of hyrocarbos by H2O2, Journal of Porphyrines and Phthalocyanines, 4 (6) 2000 598-603.
  • M. Milos, A comparative study of biomimetic oxidation of organo essential oil by H2O2 or KHSO5 catalyzed by Fe(III) meso-tetraphenylporphyrine or Fe(III) phthalocyianine, Applied Catalysis A: General, 219 (2001) 157-161.
  • R.R.L. Martins, M.G.P.M.S. Neves, A.J.D. Silvestre, A.M.S. Silva, J.A.S. Cavaleiro, Oxidation of aromatic monoterpenes with hydrogen peroxide catalysed by Mn(III) porphyrin complexes, Journal of Molecular Catalysis A: Chemeical 137 (1999) 41-47)
  • P. Hoffmann, G. Labat, A. Robert, B. Meunier, Highly selective bromination of tetramesitylporphyrin: An easy access to robust metalloporphyrins, M-Br8TMP and M-Br8TMPS. Examples of application in catalytic oxygenation and oxidation reactions Tetrahedron Letters 31, (1990) 1991-1994.
  • P. Hoffmann, A. Robert, B. Meunier, Preparation and catalytic activities of the manganese and iron derivatives of Br8TMP and Cl12TMP, two robust porphyrine ligands obtained by halogenation of tetramesitylporphyrine, Bulletin de la Societe Chimique de France 129 (1992) 85-97.
  • H.Y. Adamson, R.G. Hiller, J. Walmsley, Protochlorophyllide reduction and greening in angiosperms: an evolutionary perspective, Journal of photochemistry and photobiology B: Biology, 41 (1997) 201-221.
  • K.Kalyanasundaran, N. Vlachopoulos, V. Krishan, A. Monier, and , M. Gratzel, Sensitizition of titanium dioxide in the visible light region using zinc porphyrines, Journal of Physical Chemistry, 91 (1987) 2342-2347.
  • G.A. Kostenich, I.N. Zhuraukin, E.A. Zhaurid, Experimental grounds for using chlorin r6 in the photodinamik therapy of malignant tumors, Journal of Photochemistry and Photobiology B: Biology, 22 (1994) 211-217.
  • K. Takahashi, K. Etoh, Y. Tsuda, T. Yamaguchi, T. Komura, S. Ito, K. Murata, Photoinduced electron transfer from porphyrin to C60 in a C60|porphyrin double-layer photoelectrochemical cell, Journal of Electroanalytical Chemistry, 426 (1997) 85-90.
  • K. Uosaki, T. Kondo, X.Q. Zhang, M. Yanagida, Very efficient visible-light-induced uphill electron transfer at a self-assembled monolayer with a porphyrin-ferrocene-thiol linked molecule, Journal of the American Chemical Society, 119 (1997) 8367-8368.
  • M.A. Fox, J.V. Grant, D. Melamed, T. Torimoto, C. Liu, A.J. Bard, Effect of structural variation on photocurrent efficiency in alkyl-substituted porphyrin solid-state thin layer photocells, Chemistry of Materials, 10 (1998) 1771-1776.
  • T. Yamazaki, I. Yamazaki, A. Osuka, Photoinduced electron transfer and molecular orientation of zinc porphyrin- imide dyads in Langmuir-Blodgett monolayer films, Journal of Physical Chemistry B, 102 (1998) 7858- 7865.
  • H. Imahori, S. Ozawa, K. Ushida, M. Takahashi, T. Azuma, A. Ajavakom, T. Akiyama, M. Hasegawa, S. Taniguchi, T. Okada, Y. Sakata, Organic photoelectrochemical cell mimicking photoinduced multistep elctron transfer in photosynthesis: Interfacial structure and photoelectrochemical properties of slef-asembled monolayers of porphyrine-linked fullerens on gold electrodes, Bulletin of Chemical Society of Japan, 72 (1999) 485-502.
  • José L. Garrido, F. Roriguez, E. Campana, M. Zapata, Rapid separation of chlorophylls a and b and their demetallated and dephytylated derivatives using a monolithic silica C18 column and a pyridine-containing mobile phase, Journal of Cromatography A, 994 (2003) 85-92.
  • M.M. Hegazi, A. Pérez-Ruzafa, L. Almela, M.E. Candela, Separation and identification of chlorophylls and carotenoids from Caulerpa, Jania rubens and padina pavonica by reversed-phase high-performance liquid chromatography, Journal of Chromatography A, 829 (1998) 153-159.
  • H. Türk, H. Berber, Structural stabilities of water-saluble MnTDCSPP, MnTSPP, and supported analogues toward hydrogen peroxide and sodium hypochlorite, International Journal of Chemical Kinetics, 32 (5) (2000) 271- 278.
  • H. Türk, T. Tay, H. Berber, Sructural stabilities of sulfonated manganese tetramesitylporphyrine and its b- brominated analogues toward NaOCl, HOand (CH)COOH, Journal of Molecular Catalysis A : Chemical, 160:(2) (2000) 323-330. 22
  • COOH, Journal of Molecular Catalysis A :
  • H. Türk, H. Berber, Structural studies of water-soluble b-brominated manganese porphyrins: Stabilities of MnTDSSPPBrand MnTSPPBras homogeneous and supported reagents towartd hydrogen peroxide and 8 sodium hypochlorite, Turkish Journal of Chemistry, 25 (2001) 215-222.
  • H. Berber, Klorofil a ve b’nin ışığa bağımlılığının petrol eteri, metanol ve su çözücülerinde yapı kararlılığı, Anadolu Üniversitesi Fen Fakültesi Dergisi, 8 (2004) 85-97)
  • H. Berber, Klorofil b’nin pH’ya bağımlı H2O, (CH3)3COOH ve NaOCl oksidantlarına karşı yapı kararlılığının incelenmesi, Anadolu Üniversitesi Fen Fakültesi Dergisi ,8 (2004) 57-69.
  • H. Berber, S. Yurdakal, Klorofil a’nın pH’ya bağımlı HO, (CH)COOH ve NaOCl oksidantlarına karşı yapı 22 33 kararlılığının incelenmesi Anadolu Üniversitesi Fen Fakültesi Dergisi, 8 (2004) 71-83)
  • Y. Suzuki, K. Tanabe, And Y., Shioi, Determination of Chemical Oxidation Products of Chlorophyll and Porphyrine by High-Performance Liquid Chromatography, Journal of Chromatography A,. 839 (1999) 85-91.

Klorin A ve B Türevlerinin Farklı pH'larda H2O2, t-BuOOH ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı

Yıl 2006, Cilt: 1 Sayı: 6, 1 - 19, 01.06.2006

Öz

Bu çalışmada feofitin a ve b, feoforbid a ve b ve klorofilid a ve b pH 1.00-14.00 aralığında oksidantsızve pH 8.00-14.00 aralığında H2O2, t-BuOOH ve NaOCl oksidantlarına karşı karanlıkta, oda sıcaklığındayapısal kararlılıkları incelenmiştir. İncelenen klorin kompleksleri, asidik ortamda (pH8.00) ise kararlı olduğu görülmektedir. Klorin komplekslerinin aynı koşullar altında, NaOCloksidantına göre HO2ve t-BuOOH oksidantlarında daha kararlı olduğu bulunmuştur. Feofitin a bütünoksidantlarda incelenen diğer molekülerden daha kararlı olduğu, H2O2ve t-BuOOH oksidantlarında feofitinb, NaOCl oksidantında ise klorofilid a’nın en kararsız olduğu görülmüştür. Feoforbid a ve b, feofitin a’yagöre kararsız olurken, klorofilid a ve b ve feoforbid b’ye göre daha kararlı olduğu bulunmuştur

Kaynakça

  • E.S. Nymon and P.H. Hynninen, Research advances in the use of tetrapyrrolic photosensitizers for photodynamic therapy, Journal of Photochemistry and Photobiology B: Biology, 73 (2004) 1-28.
  • J. Helaja, F. P. Montforts, I. Kilpeläinen, P.H. Hynninen, NH tautomerism in the dimethyl ester of bonellin, a natural chlorin, J. Org. Chem., 64 (1999) 432-437.
  • J. Helaja, M Stapelbroek-Möllmann, I. Kilpeläinen, P.H. Hynninen, NH tautomerism in the a natural chlorin derivatives, J. Org. Chem., 65 (2000) 3700-3707.
  • C. Brükner, Jason R. McCarty, H.W. Daniell, Z.D. Pendon, R.P. Ilagan, T.M. Francis, L.Ren, R.R. Birge, H.A. Frank, A spectroscopic and computational study of the singlet and triplet excited states of synthetic b- functionalized chlorins, Chemical Physics, 294 (2003) 285-303.
  • M.O. Liu, A.T. Hu, Microwave-assisted synthesis of phthalocyanine–porphyrin complex and its photoelectric conversion properties, Journal of Organometallic Chemistry, 689 (2004) 2450-2455.
  • B. Meunier, Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage, Chemical Reviews, 92 (1992) 1411-1456.
  • D. Mansuy, Activation of alkanes: The biomimetic approach, Coordination Chemistry Reviews, 125 (1993) 129-141.
  • Eva R. Birnbaum, Jay A. Labinger, John E. Bercaw, Harry B. Gray, Catalysis of aerobic olefin oxidation by a ruthenium perhaloporphyrine complex, Inorganica Chimica Acta, 270 (1998) 433-439.
  • P. Battioni, E. Cardin, M. Louloudi, B. Schollhorn, G.A. Spyroulias, D. Munsuy, T.G. Traylor, Metalloporphyrinosilicas: A new class of hybrid organic-inorganic materials acting as selective biomimetic oxidation catalysts, Chemical Communications, 17 (1996) 2037-2038.
  • W. Nam, H.J. Han, S.Y. Oh, Y.J. Lee, M.H. Choi, S.Y. Han, C. Kim, S.K. Woo, W. Shin, New insights into the mechanisms of O-O bond cleavage of hydrogen peroxide and tert-alkyl hydroperoxides by iron (III) porphyrin complexes, Journal of The American Chemical Society, 122, (2000) 8677-8684.
  • A. Thellend, P. Battioni, D. Mansuy, Ammonium acetate as a very simle and efficient cocatalyst for manganese porphyrine-catalyzed oxygenation of hydrocarbons by hydrogen-peroxide, Journal of The Chemical Society- Chemical Communications, 9 (1994) 1035-1036.
  • M.C. Prado-Manso Cynthia, A.V. Ednava, F.S. Vinhado, H.C. Sacco, K.J. Ciuffi, P.R. Martins, A.G. Ferreira, J.R. Lindsey-Smith, O.R. Nascimento, Y. Iamamoto, Cynthia, Characterization and catalytic activity of iron (III) mono(4-N-methyl pyridil)-tris(halophenyl) porphyrins in homegeneous and heterogeneous systems, Journal of Molecular Catalysis A: Chemical, 150 (1999) 251-266.
  • W. Nam, Ho J. Lee, So-Young Oh, C. Kim, Ho G., Jang, First success of catalytic epoxidation of olefins by an electron-rich iron(III) porphyrine complex and H2O2: imidazole effect on the activation of H2O2 by iron porphyrine complexs in aprotic solvent, Journal of Inorganic Biochemistry, 80 (2000) 219-225.
  • A.M.D.R. Gonsalves, A.C. Serra, Metalloporphyrin catalytic oxidations of hyrocarbos by H2O2, Journal of Porphyrines and Phthalocyanines, 4 (6) 2000 598-603.
  • M. Milos, A comparative study of biomimetic oxidation of organo essential oil by H2O2 or KHSO5 catalyzed by Fe(III) meso-tetraphenylporphyrine or Fe(III) phthalocyianine, Applied Catalysis A: General, 219 (2001) 157-161.
  • R.R.L. Martins, M.G.P.M.S. Neves, A.J.D. Silvestre, A.M.S. Silva, J.A.S. Cavaleiro, Oxidation of aromatic monoterpenes with hydrogen peroxide catalysed by Mn(III) porphyrin complexes, Journal of Molecular Catalysis A: Chemeical 137 (1999) 41-47)
  • P. Hoffmann, G. Labat, A. Robert, B. Meunier, Highly selective bromination of tetramesitylporphyrin: An easy access to robust metalloporphyrins, M-Br8TMP and M-Br8TMPS. Examples of application in catalytic oxygenation and oxidation reactions Tetrahedron Letters 31, (1990) 1991-1994.
  • P. Hoffmann, A. Robert, B. Meunier, Preparation and catalytic activities of the manganese and iron derivatives of Br8TMP and Cl12TMP, two robust porphyrine ligands obtained by halogenation of tetramesitylporphyrine, Bulletin de la Societe Chimique de France 129 (1992) 85-97.
  • H.Y. Adamson, R.G. Hiller, J. Walmsley, Protochlorophyllide reduction and greening in angiosperms: an evolutionary perspective, Journal of photochemistry and photobiology B: Biology, 41 (1997) 201-221.
  • K.Kalyanasundaran, N. Vlachopoulos, V. Krishan, A. Monier, and , M. Gratzel, Sensitizition of titanium dioxide in the visible light region using zinc porphyrines, Journal of Physical Chemistry, 91 (1987) 2342-2347.
  • G.A. Kostenich, I.N. Zhuraukin, E.A. Zhaurid, Experimental grounds for using chlorin r6 in the photodinamik therapy of malignant tumors, Journal of Photochemistry and Photobiology B: Biology, 22 (1994) 211-217.
  • K. Takahashi, K. Etoh, Y. Tsuda, T. Yamaguchi, T. Komura, S. Ito, K. Murata, Photoinduced electron transfer from porphyrin to C60 in a C60|porphyrin double-layer photoelectrochemical cell, Journal of Electroanalytical Chemistry, 426 (1997) 85-90.
  • K. Uosaki, T. Kondo, X.Q. Zhang, M. Yanagida, Very efficient visible-light-induced uphill electron transfer at a self-assembled monolayer with a porphyrin-ferrocene-thiol linked molecule, Journal of the American Chemical Society, 119 (1997) 8367-8368.
  • M.A. Fox, J.V. Grant, D. Melamed, T. Torimoto, C. Liu, A.J. Bard, Effect of structural variation on photocurrent efficiency in alkyl-substituted porphyrin solid-state thin layer photocells, Chemistry of Materials, 10 (1998) 1771-1776.
  • T. Yamazaki, I. Yamazaki, A. Osuka, Photoinduced electron transfer and molecular orientation of zinc porphyrin- imide dyads in Langmuir-Blodgett monolayer films, Journal of Physical Chemistry B, 102 (1998) 7858- 7865.
  • H. Imahori, S. Ozawa, K. Ushida, M. Takahashi, T. Azuma, A. Ajavakom, T. Akiyama, M. Hasegawa, S. Taniguchi, T. Okada, Y. Sakata, Organic photoelectrochemical cell mimicking photoinduced multistep elctron transfer in photosynthesis: Interfacial structure and photoelectrochemical properties of slef-asembled monolayers of porphyrine-linked fullerens on gold electrodes, Bulletin of Chemical Society of Japan, 72 (1999) 485-502.
  • José L. Garrido, F. Roriguez, E. Campana, M. Zapata, Rapid separation of chlorophylls a and b and their demetallated and dephytylated derivatives using a monolithic silica C18 column and a pyridine-containing mobile phase, Journal of Cromatography A, 994 (2003) 85-92.
  • M.M. Hegazi, A. Pérez-Ruzafa, L. Almela, M.E. Candela, Separation and identification of chlorophylls and carotenoids from Caulerpa, Jania rubens and padina pavonica by reversed-phase high-performance liquid chromatography, Journal of Chromatography A, 829 (1998) 153-159.
  • H. Türk, H. Berber, Structural stabilities of water-saluble MnTDCSPP, MnTSPP, and supported analogues toward hydrogen peroxide and sodium hypochlorite, International Journal of Chemical Kinetics, 32 (5) (2000) 271- 278.
  • H. Türk, T. Tay, H. Berber, Sructural stabilities of sulfonated manganese tetramesitylporphyrine and its b- brominated analogues toward NaOCl, HOand (CH)COOH, Journal of Molecular Catalysis A : Chemical, 160:(2) (2000) 323-330. 22
  • COOH, Journal of Molecular Catalysis A :
  • H. Türk, H. Berber, Structural studies of water-soluble b-brominated manganese porphyrins: Stabilities of MnTDSSPPBrand MnTSPPBras homogeneous and supported reagents towartd hydrogen peroxide and 8 sodium hypochlorite, Turkish Journal of Chemistry, 25 (2001) 215-222.
  • H. Berber, Klorofil a ve b’nin ışığa bağımlılığının petrol eteri, metanol ve su çözücülerinde yapı kararlılığı, Anadolu Üniversitesi Fen Fakültesi Dergisi, 8 (2004) 85-97)
  • H. Berber, Klorofil b’nin pH’ya bağımlı H2O, (CH3)3COOH ve NaOCl oksidantlarına karşı yapı kararlılığının incelenmesi, Anadolu Üniversitesi Fen Fakültesi Dergisi ,8 (2004) 57-69.
  • H. Berber, S. Yurdakal, Klorofil a’nın pH’ya bağımlı HO, (CH)COOH ve NaOCl oksidantlarına karşı yapı 22 33 kararlılığının incelenmesi Anadolu Üniversitesi Fen Fakültesi Dergisi, 8 (2004) 71-83)
  • Y. Suzuki, K. Tanabe, And Y., Shioi, Determination of Chemical Oxidation Products of Chlorophyll and Porphyrine by High-Performance Liquid Chromatography, Journal of Chromatography A,. 839 (1999) 85-91.
Toplam 36 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Bölüm Makaleler
Yazarlar

Hüseyin Berber, Sedat Yurdakul Bu kişi benim

Yayımlanma Tarihi 1 Haziran 2006
Yayımlandığı Sayı Yıl 2006 Cilt: 1 Sayı: 6

Kaynak Göster

APA Yurdakul, H. B. S. . (2006). Klorin A ve B Türevlerinin Farklı pH’larda H2O2, t-BuOOH ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı. Cankaya University Journal of Arts and Sciences, 1(6), 1-19.
AMA Yurdakul HBS. Klorin A ve B Türevlerinin Farklı pH’larda H2O2, t-BuOOH ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı. Cankaya University Journal of Arts and Sciences. Haziran 2006;1(6):1-19.
Chicago Yurdakul, Hüseyin Berber, Sedat. “Klorin A Ve B Türevlerinin Farklı pH’larda H2O2, T-BuOOH Ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı”. Cankaya University Journal of Arts and Sciences 1, sy. 6 (Haziran 2006): 1-19.
EndNote Yurdakul HBS (01 Haziran 2006) Klorin A ve B Türevlerinin Farklı pH’larda H2O2, t-BuOOH ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı. Cankaya University Journal of Arts and Sciences 1 6 1–19.
IEEE H. B. S. . Yurdakul, “Klorin A ve B Türevlerinin Farklı pH’larda H2O2, t-BuOOH ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı”, Cankaya University Journal of Arts and Sciences, c. 1, sy. 6, ss. 1–19, 2006.
ISNAD Yurdakul, Hüseyin Berber, Sedat. “Klorin A Ve B Türevlerinin Farklı pH’larda H2O2, T-BuOOH Ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı”. Cankaya University Journal of Arts and Sciences 1/6 (Haziran 2006), 1-19.
JAMA Yurdakul HBS. Klorin A ve B Türevlerinin Farklı pH’larda H2O2, t-BuOOH ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı. Cankaya University Journal of Arts and Sciences. 2006;1:1–19.
MLA Yurdakul, Hüseyin Berber, Sedat. “Klorin A Ve B Türevlerinin Farklı pH’larda H2O2, T-BuOOH Ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı”. Cankaya University Journal of Arts and Sciences, c. 1, sy. 6, 2006, ss. 1-19.
Vancouver Yurdakul HBS. Klorin A ve B Türevlerinin Farklı pH’larda H2O2, t-BuOOH ve NaOCI Oksidantlarına Karşı Yapısal Kararlılığı. Cankaya University Journal of Arts and Sciences. 2006;1(6):1-19.