Research Article

The Semi-Empirical Determination of K X-ray, KLL Auger Line and L subshell level widths for 3d transition elements at 59.5 keV

Volume: 15 Number: 1 March 22, 2019
EN

The Semi-Empirical Determination of K X-ray, KLL Auger Line and L subshell level widths for 3d transition elements at 59.5 keV

Abstract

The emission of X-rays in Ka and KLL Auger energy regions were analyzed for transition metals by using energy dispersive X-ray fluorescence (EDXRF) system. To acquire more information in this energy region, the semi-empirical determination of Ka, Auger line-widths and the L sub-shell level widths were performed. Since K shell is a core shell for transition metals and it is not easily be affected by valence shell electronic distributions, K shell fluorescence yields were used for the semi-empirical determinations. In the experiment, elemental form of transition metals were excited by 59.5 keV g-rays from 241Am annular source and the emitted  X-ray photons were counted by Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. The obtained results were compared with the other studies in the literature

Keywords

References

  1. 1. Neumann, M, Kuepper, K. 2009. X-ray spectroscopic techniques are powerful tools for electronic structure investigations of transition metal oxides. Surface Science; 603: 1613–1621.
  2. 2. Haas, T.W, Grant, J.T, Dooley G.J. 1970. Auger electron spectroscopy of transition metals. Physical Review B; 1: 1449–1459.
  3. 3. Nemethy, A, Köver, L, Cserny, I, Varga, D, Barna P.B. 1996. The KLL and KLM Auger Spectra of 3d transition metals Z=23–26. Journal of Electron Spectroscopy and Related Phenomena; 82: 31–40.
  4. 4. Ursic, M, Kavcic, M, Budnar, M. 2003. Second order radiative contributions in the K1,3 X-ray spectra of 3d transition metals and their dependence on the chemical state of the element. Nuclear Instruments and Methods in Physics Research B; 211: 7–14.
  5. 5. Ito, Y, Tochio, T, Ohashi, H, Yamashita, M, Fukushima, S, Polasik, M, Slabkowska, K, Syrocki, L, Szymanska, E, Rzadkiewicz, J, Indelicato, P, Marques, J.P, Martins, M.C, Santos, J.P, Parente, F. 2016. K1,2 X-ray linewidths, asymmetry indices, and [KM] shake probabilities in elements Ca to Ge and comparison with theory for Ca, Ti and Ge. Physical Review A; 94: 042506.
  6. 6. Hölzer, G, Fritsch, M, Deutsch, M, Hartwig, J, Förster, E. 1997. K1,2andK1,3 X-ray emission lines of the 3d transition metals. Physical Review A; 56: 4554.
  7. 7. Ito, Y, Tochio, T, Oohashi, H, Vlaicu, A.M. 2006. Contribution of the [1s3d] shake process to K1,2 spectra in 3d elements. Radiation Physics and Chemistry; 75: 1534–1537.
  8. 8. Deutsch M,Hölzer G, Hartwig J, Wolf J, Fritsch M, Förster E, Kand K X-ray emission spectra of copper, Physical Review A 1995,51, 283.

Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Kadriye Kündeyi This is me

Publication Date

March 22, 2019

Submission Date

September 12, 2018

Acceptance Date

February 8, 2019

Published in Issue

Year 2019 Volume: 15 Number: 1

APA
Kündeyi, K., & Küp Aylıkcı, N. (2019). The Semi-Empirical Determination of K X-ray, KLL Auger Line and L subshell level widths for 3d transition elements at 59.5 keV. Celal Bayar University Journal of Science, 15(1), 57-64. https://doi.org/10.18466/cbayarfbe.459295
AMA
1.Kündeyi K, Küp Aylıkcı N. The Semi-Empirical Determination of K X-ray, KLL Auger Line and L subshell level widths for 3d transition elements at 59.5 keV. CBUJOS. 2019;15(1):57-64. doi:10.18466/cbayarfbe.459295
Chicago
Kündeyi, Kadriye, and Nuray Küp Aylıkcı. 2019. “The Semi-Empirical Determination of K X-Ray, KLL Auger Line and L Subshell Level Widths for 3d Transition Elements at 59.5 KeV”. Celal Bayar University Journal of Science 15 (1): 57-64. https://doi.org/10.18466/cbayarfbe.459295.
EndNote
Kündeyi K, Küp Aylıkcı N (March 1, 2019) The Semi-Empirical Determination of K X-ray, KLL Auger Line and L subshell level widths for 3d transition elements at 59.5 keV. Celal Bayar University Journal of Science 15 1 57–64.
IEEE
[1]K. Kündeyi and N. Küp Aylıkcı, “The Semi-Empirical Determination of K X-ray, KLL Auger Line and L subshell level widths for 3d transition elements at 59.5 keV”, CBUJOS, vol. 15, no. 1, pp. 57–64, Mar. 2019, doi: 10.18466/cbayarfbe.459295.
ISNAD
Kündeyi, Kadriye - Küp Aylıkcı, Nuray. “The Semi-Empirical Determination of K X-Ray, KLL Auger Line and L Subshell Level Widths for 3d Transition Elements at 59.5 KeV”. Celal Bayar University Journal of Science 15/1 (March 1, 2019): 57-64. https://doi.org/10.18466/cbayarfbe.459295.
JAMA
1.Kündeyi K, Küp Aylıkcı N. The Semi-Empirical Determination of K X-ray, KLL Auger Line and L subshell level widths for 3d transition elements at 59.5 keV. CBUJOS. 2019;15:57–64.
MLA
Kündeyi, Kadriye, and Nuray Küp Aylıkcı. “The Semi-Empirical Determination of K X-Ray, KLL Auger Line and L Subshell Level Widths for 3d Transition Elements at 59.5 KeV”. Celal Bayar University Journal of Science, vol. 15, no. 1, Mar. 2019, pp. 57-64, doi:10.18466/cbayarfbe.459295.
Vancouver
1.Kadriye Kündeyi, Nuray Küp Aylıkcı. The Semi-Empirical Determination of K X-ray, KLL Auger Line and L subshell level widths for 3d transition elements at 59.5 keV. CBUJOS. 2019 Mar. 1;15(1):57-64. doi:10.18466/cbayarfbe.459295

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