Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties

Berk Özler; Serdar Yıldırım

doi:10.69560/cujast.1616786

EN TR

Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties

Abstract

3D printers have revolutionized many areas such as aviation, dentistry, health, construction, food, pharmacy and tissue engineering by forming the basis of additive manufacturing technology. These devices, which work by adding material layer by layer, combine with CAD software to enable the rapid and efficient production of complex designs. DLP printers in the photochemical category stand out in medical applications by polymerizing photosensitizer resins with UV light. While inorganic fillers in these resins increase mechanical properties, excessive use can increase viscosity and reduce printing performance. Although SiO2 nanoparticles increase transparency and durability, their tendency to clump negatively affects mechanical properties. By coating the surface of these particles with the silanization method, they are better bonded with the resin, thus improving the integrity and mechanical strength of the structure. In this study, the aim is to investigate the effects of the silanization process on the mechanical properties and conversion degree of particles in epoxy composite materials reinforced with SiO2 nanoparticles. For this purpose, nanoparticles synthesized by the sol-gel method and subjected to the silane coating process were added to the epoxy resin at different rates and produced with a DLP type 3D printer. In the study, critical parameters such as the compatibility of coated and uncoated nanoparticles with the resin matrix, the viscosity properties of the material, mechanical strength and conversion degree were evaluated with detailed analyses. The obtained results aimed to reveal the effect of silane coating on increasing the performance of the material and to show the potential of this technology in application areas such as medicine, dentistry and tissue engineering.

Keywords

Additive manufacturing, nanocomposite, silanization, mechanical properties, conversion degree

Eklemeli Üretimle Üretilen SiO2 Nanopartikül Takviyeli Epoksi Kompozitlerin İncelenmesi: Silanizasyonun Dönüşüm Derecesi ve Mekanik Özellikler Üzerindeki Etkisi

Abstract

3D yazıcılar, eklemeli üretim teknolojisinin temelini oluşturarak havacılık, diş hekimliği, sağlık, inşaat, gıda, eczacılık ve doku mühendisliği gibi birçok alanda devrim yaratmıştır. Malzemeyi katman katman ekleyerek çalışan bu cihazlar, CAD yazılımlarıyla birleşerek karmaşık tasarımların hızlı ve verimli bir şekilde üretilmesini sağlamaktadır. Fotokimyasal kategorideki DLP yazıcılar, fotosensitizör reçinelerini UV ışığıyla polimerize ederek tıbbi uygulamalarda öne çıkmaktadır. Bu reçinelerdeki inorganik dolgular mekanik özellikleri artırırken, aşırı kullanımı viskoziteyi artırarak baskı performansını düşürebilmektedir. SiO2 nanopartikülleri şeffaflığı ve dayanıklılığı artırmasına rağmen, topaklanma eğilimleri mekanik özellikleri olumsuz etkilemektedir. Bu partiküllerin yüzeyinin silanizasyon yöntemi ile kaplanmasıyla reçineyle daha iyi bağlanmaları sağlanmakta, böylece yapının bütünlüğü ve mekanik mukavemeti artmaktadır. Bu çalışmada, SiO2 nanopartikülleri ile takviye edilmiş epoksi kompozit malzemelerde silanizasyon işleminin partiküllerin mekanik özellikleri ve dönüşüm derecesi üzerindeki etkilerinin incelenmesi amaçlanmıştır. Bu amaçla sol-jel yöntemi ile sentezlenen ve silan kaplama işlemine tabi tutulan nanopartiküller farklı oranlarda epoksi reçinesine eklenerek DLP tipi 3D yazıcı ile üretilmiştir. Çalışmada, kaplanmış ve kaplanmamış nanopartiküllerin reçine matrisi ile uyumluluğu, malzemenin viskozite özellikleri, mekanik mukavemet ve dönüşüm derecesi gibi kritik parametreler detaylı analizlerle değerlendirilmiştir. Elde edilen sonuçlar, silan kaplamanın malzemenin performansını artırma etkisini ortaya koymayı ve bu teknolojinin tıp, diş hekimliği ve doku mühendisliği gibi uygulama alanlarındaki potansiyelini göstermeyi amaçlamaktadır.

Keywords

Eklemeli imalat, nanokompozit, silanizasyon, mekanik özellikler, dönüşüm derecesi

Supporting Institution

Dokuz Eylul University, Scientific Research Projects Coordinatorship with the project code 2021.KB.FEN.046.

Project Number

2021.KB.FEN.046

Ethical Statement

The study is complied with research and publication ethics.

Thanks

This study was financially supported by Dokuz Eylul University, Scientific Research Projects Coordinatorship with the project code 2021.KB.FEN.046.

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Details

Primary Language

English

Subjects

Composite and Hybrid Materials, Material Characterization, Polymers and Plastics, Nanomaterials

Journal Section

Research Article

Authors

Berk Özler ^*
0000-0003-1819-6032
Türkiye

Serdar Yıldırım
0000-0002-3730-3473
Türkiye

Early Pub Date

June 26, 2025

Publication Date

June 27, 2025

Submission Date

January 9, 2025

Acceptance Date

March 1, 2025

Published in Issue

Year 2025 Volume: 4 Number: 1

DOI

https://doi.org/10.69560/cujast.1616786

IZ

https://izlik.org/JA62UM76PG

APA

Özler, B., & Yıldırım, S. (2025). Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties. Sivas Cumhuriyet Üniversitesi Bilim Ve Teknoloji Dergisi, 4(1), 12-20. https://doi.org/10.69560/cujast.1616786

AMA

1.Özler B, Yıldırım S. Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties. CUJAST. 2025;4(1):12-20. doi:10.69560/cujast.1616786

Chicago

Özler, Berk, and Serdar Yıldırım. 2025. “Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties”. Sivas Cumhuriyet Üniversitesi Bilim Ve Teknoloji Dergisi 4 (1): 12-20. https://doi.org/10.69560/cujast.1616786.

EndNote

Özler B, Yıldırım S (June 1, 2025) Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties. Sivas Cumhuriyet Üniversitesi Bilim ve Teknoloji Dergisi 4 1 12–20.

IEEE

[1]B. Özler and S. Yıldırım, “Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties”, CUJAST, vol. 4, no. 1, pp. 12–20, June 2025, doi: 10.69560/cujast.1616786.

ISNAD

Özler, Berk - Yıldırım, Serdar. “Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties”. Sivas Cumhuriyet Üniversitesi Bilim ve Teknoloji Dergisi 4/1 (June 1, 2025): 12-20. https://doi.org/10.69560/cujast.1616786.

JAMA

1.Özler B, Yıldırım S. Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties. CUJAST. 2025;4:12–20.

MLA

Özler, Berk, and Serdar Yıldırım. “Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties”. Sivas Cumhuriyet Üniversitesi Bilim Ve Teknoloji Dergisi, vol. 4, no. 1, June 2025, pp. 12-20, doi:10.69560/cujast.1616786.

Vancouver

1.Berk Özler, Serdar Yıldırım. Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties. CUJAST. 2025 Jun. 1;4(1):12-20. doi:10.69560/cujast.1616786

Investigation of SiO2 Nanoparticle Reinforced Epoxy Composites Produced by Additive Manufacturing: Effect of Silanization on Conversion Degree and Mechanical Properties

Abstract

Keywords

Eklemeli Üretimle Üretilen SiO2 Nanopartikül Takviyeli Epoksi Kompozitlerin İncelenmesi: Silanizasyonun Dönüşüm Derecesi ve Mekanik Özellikler Üzerindeki Etkisi

Abstract

Keywords

Supporting Institution

Project Number

Ethical Statement

Thanks

References

Details

Primary Language

Subjects

Journal Section

Authors

Early Pub Date

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

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