BTCA ve CA Çapraz Bağlayıcılar Kullanılarak Pamuklu Kumaşın Kopma ve Yırtılma Mukavemetinin Geliştirilmesi

Year 2021, Volume: 36 Issue: 4, 1061 - 1072, 29.12.2021

Aslıhan Koruyucu

https://doi.org/10.21605/cukurovaumfd.1048353

Cited By: 3

Abstract

Polikarboksilik asitler, sodyum hipofosfit ile formaldehit içermeyen çapraz bağlayıcı maddeleri olarak kullanılmaktadır. Bu çalışmada, %100 pamuk dimi yapısında kumaşlar kullanılarak altı farklı kaplama reçetesi ile kumaşın kopma, uzama ve yırtılma mukavemetleri belirlenmiştir. Kullanılan kumaş cinsine, kaplama reçetesine ve çapraz bağlayıcı yapısına göre elde edilen sonuçlar karşılaştırılmış ve istatiksel olarak değerlendirilmiştir. 1 g Cu2 O<5 μm, CuO<5 μm, ZnO<5 μm ve 5 g 1,2,3,4-BTCA ile kaplamadan sonra kopma mukavemetinde önemli bir artış gözlenmiştir. Pamuklu dokuma kumaşta birim uzunluktaki çözgü iplik sayısının fazla olması, çekme mukavemetinin artışına yol açmaktadır. Kopma mukavemeti ve kopma uzamasında en iyi sonuç; poliakrilat binderin BTCA ve ZnO mikro partikülü ile reaksiyonu sonrasında elde edilmiştir.

Keywords

Dokuma kumaş, Kopma ve Yırtılma mukavemeti, Kopma uzaması, Kaplama reçetesi, Çapraz bağlayıcı yapısı

Improving the Breaking and Tear Strength of Cotton Fabric Using BTCA and CA Crosslinkers

Abstract

Polycarboxylic acids are used as crosslinking agents with sodium hypophosphite which do not contain formaldehyde. In this study, breaking strength, breaking elongation and tear strength of cotton(twill weave)fabric samples were determined by using twill fabrics, six different coating recipes, produced with 100% cotton yarns. The results of breaking strength, breaking elongation and tear strength testing were compared according to the fabric structure, coating recipes and crosslinker structure statistically. A significant increase in tensile strength was observed after coating with 1g Cu2O|<5 μm, CuO<5 μm, ZnO<5 μm and 5 g 1,2,3,4-BTCA. The high number of warp threads per unit length in cotton woven fabric leads to an increase in tensile strength. The best results in tensile strength and elongation at break experiments were obtained after the reaction of polyacrylate binder with BTCA and ZnO microparticles.

Keywords

Woven fabric, Breaking and Tearing strength, Breaking elongation, Coating recipes, Crosslinker structure

References

• 1. Soljačić, I., 1993. Textile Coating. Tekstil, 42(12), 673-686.
• 2. Mogahzy, Y.E., 2009. Engineering Textiles. Integrating the Design and Manufacture of Textile Products. The Textile Institute, Woodhead Publishing Limited, Cambridge, England.
• 3. Fung, W., Hardcastle, M., 2001. Textiles Automotive Engineering. The Textile Institute, Woodhead Publishing Limited, Cambridge, England.
• 4. Brandrup, J., Immergut, E.H., Grulke, E.A., 1999. Polymer Handbook. 4th ed. New York: John Wiley & Sons.
• 5. Fenichell, S., 1996. Plastic: The Making of a Synthetic Century. New York: Harper Collins.
• 6. Seymour, R.B., Giant, C.E., 1990. Molecules. New York: John Wiley and Sons, Inc.
• 7. Ulrich, H., 1982. Introduction to Industrial Polymers. Munich: Hanser.
• 8. Skoko, M., 1998. Investigations of Properties and Multiaxial Strength and Degenerations of Coated Textile Fabrics. Tekstil, 47(7), 339-344.
• 9. Kong, I., Yang, C.Q., Wei, W., Lickfield, G.C., 1998. Mechanical Strength of Durable Press Finished Cotton Fabrics: Part I: Effects of Acid Degradation and Crosslinking of Cellulose by Polycarboxylic Acids. Textile Research.Journal., Nov. 1, 68, 865-870.
• 10. Yang, C.Q., Qian, L., Lickfield, G.C., 2001. Mechanical Strength of Durable Press Finished Cotton Fabric. Part IV: Abrasion Resistance. Textile Research Journal, June 1(71), 543-548.
• 11. Harper, R.J., Little, H.W., Blanchard, E.J., 1972. Cotton Yarn and Fabric Treatments Using Polymers with Various Glass-transition Temperatures. Textile Research Journal, Oct 1(42), 569-575. 12.Yamamato, K., 1982. Crease-resistance Finishing of Cotton Fabrics with Acrylate Copolymers and Dihydroxy Dimethylethylene Urea. Textile Research Journal, Jun 1(52), 363-369. 13. Harper, R.J., Blanchard, E.J., Donoghue, M.J., 1970. Effect of Polyvinyl Alcohol on Textile Finishes. American Dyestuff Reporter, 59(12), 15.
• 14. Abo-Shosha, M.H., Ibrahim, N.A., 1992. Water Soluble Polyether Polyurethanes as Finishing Additives in Easy Care Finishing of Cotton Fabrics. Science International Lahour, 4(2), 163. 15. Hebeish, A., Amin, S.A., Nassar, F., Ibrahim, N.A., Hanna, H.L., 1982. Cellulose Chemistry and Technology, 16, 405.
• 16. Yang, C.Q., 2013. Crosslinking: a Rout to Improve Cotton Performance. AATCC Review,13,43-52.
• 17. Yang, C.Q., Wei, W., 2000. Mechanical Strength of Durable Press Finished Cotton Fabric. Textile Research Journal, 70(2), 143-147.
• 18. Refaie, R., 2005. Polymeric Additives for Improving Performance Properties of Cotton Fabric Crosslinked with 1,2,3,4-Butanetetracarboxylic Acid. 8th Arab International Conference on Polymer Science & Technology, 27-30 Nov, Egypt.
• 19. Chen,W., Gary, C., Lickfield & Others, 2001. Abrasion Resistance of Durable Press Finish Cotton,.National Textile Center Annual Report: November, C00-C01: 1-8.
• 20. Xu, W., Li, Y., 2000. Cotton Fabric Strength Loss from Treatment with Polycarboxylic Acids for Durable Press Performance. Textile Research Journal, 70(11), 957-961.
• 21. Sauperl, O., Stana-Kleinschek, K., 2009. Cotton Cellulose 1,2,3,4 (BTCA) Buthanetetracarboxylic Acid Crosslinking Monitored by Some Physical–chemical Methods. Textile Research Journal, 79(9), 780-791.
• 22. Sauperl, O., Stana-Kleinschek, K., 2009. Differences Between Cotton and Viscose Fibers Crosslinked with BTCA. Textile Research. Journal, 80(4), 383-392.
• 23. Xu, W., 2003. Effect of Cross-linking Treatment on the Crystallinity, Crystallite Size, and Strength of Cotton Fibers. Textile Research Journal, 73(5), 433-436.
• 24. Spencer, T.P., Hauser, P.B., Smith, B., 2006. Optimization of Ionic Cross-linking. North Carolina State University, 98.
• 25. Hashem, M., Elshakankery, M.H., El-Aziz, S.M.A., Fouda, M.G., Fahmy, H.M., 2011. Improving Easy Care Properties of Cotton Fabric via Dual Effect of Ester and Ionic Crosslinking. Carbohydrate Polymers, 86, 1692-1698.
• 26. Taylor, M., 1999. Technology of Textile Properties. Forbes Publications Ltd, London, 204.
• 27. Yao, W., Wang, B., Ye, T., Yang, Y., 2013. Durable Press Finishing of Cotton Fabrics with Citric Acid: Improvement of Whiteness and Engineering Chemistry Research, 52, 16118–16127.
• 28. Schramm, C., Rinderer, B., 1999. Influence of Additives on the Generation of Unsaturated PCAs Generated During Durable-press Curing with Citric Acid. Color Technology ,115, 306–311.
• 29. Morris, C.E., Morris, N.M., Trask-Morrell, B. J., 1996. Interaction of meso-1,2,3,4-Butanetetra Carboxylic Acid with Phosphorus-Including Catalysts for Esterification Cross-linking of Cellulose. Industrial & Engineering Chemistry Research, 35, 950–953.
• 30. Yang, C.Q., Wang, X., 1996. Generation of Cyclic Anhydride Intermediates and Esterification of Cotton Cellulose by Multifunctional Carboxylic Acids: An Infrared Spectroscopy Study. Textile Research Journal, 66, 595–603.
• 31. Ibrahim, N.A., Abo-Shosha, M.H., Gaffar, M.A., 2001. Eco-friendly Durable Press Finishing of Cellulose-including Fabrics. Journal of Applied Polymer Science, 84, 2243–2253.
• 32. Welch, C.M., 1988. Tetra Carboxylic Acids as Generalaldehyde-free Durable Press Finishing Agents Part I: Catalyst, Additive, and Durability Studies 1. Textile Research Journal, 58, 480–486.
• 33. Choi, H.M., Welch, C.M., Morris, N.M., 1994. Nonphosphorus Catalysts for Generatealdehyde-free DP Finishing of Cotton with 1,2,3,4-Butanetetracarboxylic Acid: Part II: Sodium Salts of Fumaric, Maleic, and Itaconic Acids. Textile Research Journal, 64, 501–507.
• 34. Hashem, M., Elshakankery, M.H., El-Aziz, S.M.A., Fouda, M.M.G., Fahmy, H.M., 2011. Improving Easy Care Properties of Cotton Fabric via Dual Effect of Ester and Ionic Crosslinking. Carbohydrate Polymers, 86, 1692–1698.
• 35. Sungur, E.G., 2020. Dokuma Kumaşların Yapısal ve Mekanik Özellikleri ile Dökümlülüğü Arasındaki İlişkinin İncelenmesi. Yüksek Lisans Tezi, Uludağ Üniversitesi, Fen Bilimleri Enstitüsü, Bursa, 115.