Natural Dyeing of Cotton, Wool and Viscose Fabrics with Sodium Copper Chlorophyllin

Year 2024, Volume: 39 Issue: 2, 569 - 576, 11.07.2024

Gamze Gülşen Bakıcı Deniz Mutlu Ala

https://doi.org/10.21605/cukurovaumfd.1514667

Abstract

This study investigates the optimal dyeing concentrations of cotton, wool, and viscose fabrics with sodium copper chlorophyllin (SCC). Using SSC above the optimal concentration increases the amount of SCC in the wastewater, which is a disadvantage. Pre-finished 100% cotton, wool and viscose 1 x 1 rib knitted fabrics were dyed with varying SCC concentrations. Optimal dyeing concentrations were determined using UV-Vis spectrophotometry, showing dye absorption decreasing as SCC concentration increases. Equilibrium was reached at approximately 7 ml/L for cotton and viscose, and 3 ml/L for wool. Color measurement values and K/S values of the dyed samples were obtained according to the CIELab color system. The K/S values of dyed cotton, viscose, and wool fabrics rose as the concentration of SCC increased, reaching a peak at 9 ml/L for viscose and 12 ml/L for cotton and wool. Rubbing and perspiration fastness were rated good to excellent.

Keywords

Sodium copper chlorophyllin, Natural dyeing, UV-visible spectrophotometer, Color fastness

Pamuk, Yün ve Viskon Kumaşların Sodyum Bakır Klorofil ile Doğal Boyanması

Abstract

Bu çalışmanın amacı pamuk, yün ve viskon kumaşların sodyum bakır klorofil (SCC) ile optimum boyama konsatrasyonlarının araştırılmasıdır. Ön terbiyesi yapılmış %100 pamuk, yün ve viskon 1 x 1 ribana örme kumaşlar farklı SCC konsantrasyonlarıyla boyanmıştır. Optimal boyama konsantrasyonlarını belirlemek için UV-Vis spektrofotometre kullanılarak SCC konsantrasyonunun boya çekimine etkisi incelenmiştir. SSC’nin optimal konsantasyondan fazla kullanılması bir dezavantaj olarak atık suyun SCC miktarını artırır. SCC konsantrasyonunun artmasıyla boya çekiminin azaldığı ve pamuk ve viskon için yaklaşık 7 ml/L, yün için ise 3 ml/L civarında dengeye ulaştığı görülmüştür. Numunelerin K/S değerleri ve renk ölçümleri CIELab renk sistemi kullanılarak ölçülmüştür. K/S değerleri yün kumaşlarda 12 ml/L'ye kadar, pamuk ve viskon kumaşlarda ise 9 ml/L'ye kadar artmıştır. Sürtünme ve terlemeye karşı renk haslığı değerlendirilmiş olup boyalı kumaşların haslık değerleri iyi ile mükemmel arasındadır.

Keywords

Sodyum bakır klorofil, Doğal boyama, UV-vis spektrofotometre, Renk haslık

References

• 1. Ali, S., Nisar, N., Hussain, T., 2007. Dyeing Properties of Natural Dyes Extracted from Eucalyptus. The Journal of the Textile Institute, 98(6), 559-562.
• 2. Tayade, P.B., Adivarekar, R.V., 2013. Dyeing of Cotton Fabric with Cuminum cyminum L. as a Natural Dye and its Comparison with Synthetic Dye. The Journal of the Textile Institute, 104(10), 1080-1088.
• 3. Mansour, R., Ezzili, B., Farouk, M., 2017. The use of Response Surface Method to Optimize the Extraction of Natural Dye from Winery Waste in Textile Dyeing. The Journal of the Textile Institute, 108(4), 528-537.
• 4. Giacomini, F., Menegazzo, M.A.B., Santos, J.C.O., Arroyo, P.A., Barros, M.A.S.D., 2016. Ecofriendly Dyeing of Silk with Extract of Yerba Mate (Ilex Paraguariensis). Textile Research Journal, 87(7), 829-837.
• 5. Jiang, H., Hu, X., Meena, B.I., Khan, A., Hussain, M.T., Yao, J., Wang, J., 2019. Extraction of Natural Dyes from the Stem of Caulis Spatholobi and their Application on Wool. Textile Research Journal, 89(23-24), 5209- 5217.
• 6. Kumbasar, E.P.A., Atav, R., Bahtiyari, M.İ., 2009. Effects of Alkali Proteases on Dyeing Properties of Various Proteinous Materials with Natural Dyes. Textile Research Journal, 79(6), 517-525.
• 7. Safapour, S., Sadeghi-Kiakhani, M., Doustmohammadi, S., 2019. Chitosan-cyanuric Chloride Hybrid as an Efficient Novel Bio-mordant for Improvement of Cochineal Natural Dye Absorption on Wool Yarns. The Journal of the Textile Institute, 110(1), 81-88.
• 8. Li, K., Ding, Q., Zhang, H., 2022. Eco-friendly Dyeing of Cotton Fabric Using Natural Dye from Orange Peel. The Journal of the Textile Institute, 113(3), 360-366.
• 9. Bahtiyari, M.İ., Benli, H., Yavaş, A., Akça, C., 2017. Use of Different Natural Dye Sources for Printing of Cotton Fabrics. Textile and Apparel, 27(3), 259-265.
• 10. Davulcu, A., 2015. Investigation the Dyeability of Hyperbranched Polymer Modified Polypropylene Fibers with Natural Dyes. Textile and Apparel, 25(1), 73-79.
• 11. Tutak, M., Acar, G., Akman, O., 2014. Natural Dyeing Properties of Wool Fabrics by Pomegranate (Punica granatum) Peel. Textile and Apparel, 24(1), 81-85.
• 12. Deveoğlu, O., Karadağ, R., 2011. Genel Bir Bakış: Doğal Boyarmaddeler. Marmara Üniversitesi Fen Bilimleri Dergisi, 23(1), 21-32.
• 13. Yoo, H.J., Ahn, C., Narantuya, L., 2013. Extractions of Chlorophyll from Spinach and Mate Powders and their Dyeability on Fabrics. Journal of the Korean Society of Clothing and Textiles, 37(3), 413-423.
• 14. Usop, R., Abidin, Z.H.Z., Mazni, N.A., Hadi, A.N., 2016. The Colour Stability of Natural Dye Coating Films Consisting of Chlorophyll after Exposed to UV-A. Pigment & Resin Technology, 45(3), 149-157.
• 15. Hou, X., Yang, R., Xu, H., Yang, Y., 2012. Adsorption Kinetic and Thermodynamic Studies of Silk Dyed with Sodium Copper Chlorophyllin. Industrial & Engineering Chemistry Research, 51(25), 8341-8347.
• 16. Liu, Y., Guo, Y., Ren, Y., Wang, Y., Guo, X., Liu, X., 2020. Phosphorylation of Sodium Copper Chlorophyll Enables Color-fasten and Durable Flame Retardant Wool Fibers. Polymer Degradation and Stability, 179, 109286.
• 17. Park, S.J., Park, Y.M., 2010. Eco-dyeing and Antimicrobial Properties of Chlorophyllin Copper Complex Extracted from Sasa Veitchii. Fibers and Polymers, 11(3), 357-362.
• 18. Xiu-liang, H., Rui-ling, Y., Xin-zi, C., Yi-qi, Y., 2012. Dyeing Kinetics of Sodium Copper Chlorophyll on Silk. Natural Product Research & Development, 24, 312-315.
• 19. Zhang, J., Tao, R., 2014. Eco-friendly Dyeing of Silk Fabric with Sodium Copper Chlorophyll. Advanced Materials Research, 941, 1313-1316.
• 20. Zhao, Z., Zhang, M., Hurren, C., Zhou, L., Wu, J., Sun, L., 2020. Study on Photofading of Two Natural Dyes Sodium Copper Chlorophyllin and Gardenia Yellow on Cotton. Cellulose, 27(14), 8405-8427.
• 21. Yolacan, G., 2009. Effects of Alkali Pre-treatment on Dye Exhaustion, Color Values, Color Fastness, Tensile and Surface Properties of Lyocell Yarns. Fibers and Polymers, 10, 625-635.
• 22. Usop, R., Abidin, Z.H.Z., Mazni, N.A., Hadi, A.N., Halim, N.A., Taha, R.M., Arof, A.K., 2016. The Colour Stability of Natural Dye Coating Films Consisting of Chlorophyll After Exposed to UV-A. Pigment & Resin Technology, 45(3), 149-157.
• 23. Periyasamy, A.P., 2022. Natural Dyeing of Cellulose Fibers Using Syzygium Cumini Fruit Extracts and a Bio-mordant: A Step Toward Sustainable Dyeing. Sustainable Materials and Technologies, 33, e00472.