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Preparation and Characterization of N-Type SnS2 Semiconductor Thin Films

Year 2016, Volume: 31 Issue: 1, 83 - 92, 15.06.2016
https://doi.org/10.21605/cukurovaummfd.317735

Abstract

SnS2 semiconductor thin films were prepared by the chemical bath deposition (CBD) technique onto glass substrates deposited at 50–80oC. X-ray diffraction spectra of the films have shown that the films are amorphous in structure. To determine the optical properties of the SnS2 films UV-vis spectrophotometer was used. Optical transmittance (%T) and optical absorption (A) values of the films were determined in the wavelength range 400-1100 nm at room temperature. The obtained data with optical parameters of the films absorption coefficient (α), refractive index (n), extinction coefficient (k), real, imaginary dielectric constants (Ԑ1, Ԑ2) and the energy band gap (Eg) values were calculated. From the Hall effect measurement, it was found that SnS2 thin films exhibits n-type conduction.

References

  • 1. Shi C, Yang P, Yao M, Dai X, Chen Zhu., 2013. Preparation of SnS2 Thin Films by Close-Spaced Sublimation at Different Source Temperatures. Thin Solid Films, 534, 28–31.
  • 2. Kiruthigaa G, Manoharan C, Raju C, Dhanapandian S, Thanikachalam V., 2014. Synthesis and Spectroscopic Analysis of Undoped and Zn doped SnS2 Nanostructure by Solid State Reaction Method. Materials Science in Semiconductor Processing, 26, 533–539.
  • 3. Khelia C, K. Boubaker, T. Ben Nasrallah, M. Amlouk, Belgacem S., 2009. Morphological and Thermal Properties of β-SnS2 Sprayed Thin Films Using Boubaker Polynomials Expansion. Journal of Alloys and Compounds, 477, 461–467.
  • 4. Schlaf R, Armstrong N. R, Parkinson B. A, Pettenkofer C, Jaegermann W., 1997. Van der Waals Epitaxy of the Layered Semiconductors SnSe2 and SnS2: Morphology and Growth Modes. Surface Science, 385, 1–14.
  • 5. Reddy, N. K, Reddy, K. T. R., 1998. Growth of Polycrystalline SnS Films by Spray Pyrolysis. Thin Solid Films, 325,4–6.
  • 6. Koteswara Reddy N, Ramakrishna Reddy K T, Fisher G, Best R, Dutta P K., 1999. The Structural Behaviour of Layers of SnS Grown by Spray Pyrolysis. J. Phys. D: Appl. Phys, 32, 988–990.
  • 7. Sokolov I. A., 2000. Adaptive Photodetectors: Novel Approach for Vibration Measurements. Measurement, 27, 13– 9.
  • 8. Shi W, Huo L, Wang H, Zhang H, Yang J, Wei P., 2006. Hydrothermal Growth and Gas Sensing Property of Flower Shaped SnS2 Nanostructures. Nanotechnology, 17, 2918–2924.
  • 9. Tan F, Qu S , Zeng X, Zhang C, Shi M, Wang Z, Jin L, Bi Y, Cao J, Wang Z, Hou Y, Teng F, Feng Z., 2010. Photovoltaic Effect of Tin Disulfide with Nanocrystalline/ Amorphous Blended Phases. Solid State Communications, 150, 58–61.
  • 10. Seo J-W, Jang J-T, Park S-W, Kim C, Park B, Cheon J., 2008. Two-Dimensional SnS2 Nanoplates with Extraordinary High Discharge Capacity for Lithium Ion Batteries. Advanced Materials, 20, 4269–4273.
  • 11. De D, Manongdo J, See S, Zhang V, Guloy A., 2013. Haibing Peng. High on/off Ratio Field Effect Transistors Based on Exfoliated Crystalline SnS2 Nano-membranes. Nanotechnology 24-025202 (6pp).
  • 12. Sanchez-Juareza A, Tiburcio-Silverb A, Ortiz A., 2005. Fabrication of SnS2/SnS Heterojunction Thin Film Diodes by Plasma-Enhanced Chemical Vapor Deposition. Thin Solid Films 480–481:452 – 456.
  • 13. Kutchinsky J, Taboryski R, Sorensen C. B, Hansen J. B, Lindelof P. E., 2001. Experimental Investigation of Supercurrent Enchancement in S-N-S Junctions by Non-Equilibrium Injection into Supercurrent-Carrying Bound Andreev States. Physica C, 352- 4–10.
  • 14. Gajendiran J, Rajendran V., 2011. Synthesis of SnS2 Nanoparticles by a Surfactant-Mediated Hydrothermal Method and their Characterization. Nanosci. Nanotechnol. 2 - 015001 (4pp).
  • 15. Deshpande N.G, Sagade A. A, Gudage Y. G, Lokhande C. D., 2007. Ramphal Sharma. Growth and Characterization of Tin Disulfide (SnS2) Thin Film Deposited by Successive Ionic Layer Adsorption and Reaction (SILAR) technique. Journal of Alloys and Compounds, 436, 421–426.
  • 16. Cheng L. L, Liu M H , Wang S. C, Wang M. X, Wang G. D, Zhou Q. Y, Chen Z. Q., 2013. Nano-flower and Nano-wall SnS2 Films Fabricated with Controllable Shape and Size by the PECVD Method. Semicond. Sci. Technol. 28-015020 (8pp).
  • 17. Khelia C, Boubaker K, Ben Nasrallah T., Amlouk M, Belgacem S, Saadallah F, Yacoubi N., 2009. Morphological and Thermal Properties of b-SnS2 Crystals Grown by Spray Pyrolysis Technique. Journal of Crystal Growth, 311, 1032–1035.
  • 18. George J, Valsala Kumari C. K., 1983. Growth and Characterization of Tin Disulphide Crystals Grown by Physical Vapour Transport Method. Journal of Crystal Growth, 63, 233-238.
  • 19. Gupta R. K, Yakuphanoglu F., 2012. Photoconductive Schottky Diode Based on Al/p-Si/SnS2/Ag for Optical Sensör Applications. Solar Energy, 86, 1539–1545.
  • 20. Sreedevi G, Ramakrishna Reddy K. T., 2013. Dependence of Optical Properties of Chemical Bath Deposited SnS2 Films on Deposition Time. Solid State Physics, 1512, 688–689.
  • 21. Guneri E, Ulutas C, Kirmizigul F, Altindemir G, Gode F, Gumus C., 2010. Effect of Deposition Time on Structural, Electrical, and Optical Properties of Sns Thin Films Deposited by Chemical Bath Deposition. Applied Surface Science, 257, 1189–1195.
  • 22.Bar M, Ennaoui A, Klaer J, Saez-Araoz R, Kropp T, Weinhardt L, Heske C, Schock H. W, Fischer C. H, Lux-Steiner M. C., 2006. The Electronic Structure of the [Zn(S,O)/ZnS]/CuInS2 Heterointerface- Impact of Post-Annealing. Chemical Physics Letters, 433, 71–74.
  • 23.Panda A, Antonakos E, Liarokapis S, Bhattacharya S. Chaudhuri. S., 2007. Optical Properties of Nanocrystalline SnS2 Thin Films. S.K. Materials Research Bulletin, 42, 576–583.
  • 24.Ramakrishna Reddy K. T, Sreedevi G, Ramyaan K , Miles R.W., 2012. Physical Properties of Nano-Crystalline SnS2 Layers Grown by Chemical Bath Deposition. Energy Procedia, 15, 340 – 346.
  • 25.Kariper A, Güneri E, Göde F, Gümüs C, Özpozan T., 2011. The Structural, Electrical and Optical Properties of CdS Thin Films as a Function of pH. Materials Chemistry and Physics, 129, 183–188.
  • 26.Kırmızıgül F, Güneri E, Gümüş C., 2012. Effects of different deposition conditions on the Properties of Cu2S thin films, 93,511-523.
  • 27.Gümüş C, Ulutaş C, Esen R, Özkendir O. M, Ufuktepe Y., 2005. Preparation and Characterization of Crystalline Mns thin Films by Chemical Bath Deposition. Thin Solid Films, 492, 1–5.
  • 28.Schlaf R, Armstrong N. R, Parkinson B. A, Pettenkofer C, Jaegermann W., 2007. Vander Waals Epitaxy of the Layered Semiconductors SnSe2 and SnS2: Morphology and Growth Modes. Journal of Alloys and Compounds, 436, 421–426.
  • 29.Zhang Y. C, Du Z. N, Li S. Y, Zhang M., 2010. Novel Synthesis and High Visible Light Photocatalytic Activity of SnS2 Nanoflakes from SnCl2-2H2O and S powders. Applied Catalysis B: Environmental, 95, 153–159.
  • 30. Geng H, Su Y, Wei H, Xu M, Wei L, Yang Z, Zhang Y., 2013. Controllable Synthesis and Photoelectric Property of Hexagonal SnS2 Nanoflakes by Triton X–100 Assisted Hydrothermal Method. Materials Letters, 111, 204-207.

N-Tipi SnS2 Yarıiletken İnce Filmlerin Hazırlanması ve Karakterizasyonu

Year 2016, Volume: 31 Issue: 1, 83 - 92, 15.06.2016
https://doi.org/10.21605/cukurovaummfd.317735

Abstract

SnS2 yarıiletken ince filmleri, kimyasal depolama yöntemi (KDY) kullanılarak 50-80oC’de cam alttabanlar üzerine elde edildi. X-ışını kırınım spektrumu filmlerin amorf yapıda olduklarını göstermiştir. SnS2 filmlerin optik özelliklerini belirlemek için UV-vis spektrofotometresi kullanılmıştır. Filmlerin oda sıcaklığındaki optik geçirgenlik (%T) ve optik soğurma (A) değerleri 400-1100 nm dalga boyu aralığında belirlenmiştir. Elde edilen veriler ile filmlerin optik parametreleri olan soğurma katsayısı (α), kırılma indisi (n), sönüm katsayısı (k), reel, imajiner dielektrik sabitleri (Ԑ1, Ԑ2) ve enerji bant aralığı (Eg) değerleri hesaplandı. Hall etkisi ölçümlerinden SnS2 filmleri n-tipi iletkenliğe sahip olduğu bulunmuştur.

References

  • 1. Shi C, Yang P, Yao M, Dai X, Chen Zhu., 2013. Preparation of SnS2 Thin Films by Close-Spaced Sublimation at Different Source Temperatures. Thin Solid Films, 534, 28–31.
  • 2. Kiruthigaa G, Manoharan C, Raju C, Dhanapandian S, Thanikachalam V., 2014. Synthesis and Spectroscopic Analysis of Undoped and Zn doped SnS2 Nanostructure by Solid State Reaction Method. Materials Science in Semiconductor Processing, 26, 533–539.
  • 3. Khelia C, K. Boubaker, T. Ben Nasrallah, M. Amlouk, Belgacem S., 2009. Morphological and Thermal Properties of β-SnS2 Sprayed Thin Films Using Boubaker Polynomials Expansion. Journal of Alloys and Compounds, 477, 461–467.
  • 4. Schlaf R, Armstrong N. R, Parkinson B. A, Pettenkofer C, Jaegermann W., 1997. Van der Waals Epitaxy of the Layered Semiconductors SnSe2 and SnS2: Morphology and Growth Modes. Surface Science, 385, 1–14.
  • 5. Reddy, N. K, Reddy, K. T. R., 1998. Growth of Polycrystalline SnS Films by Spray Pyrolysis. Thin Solid Films, 325,4–6.
  • 6. Koteswara Reddy N, Ramakrishna Reddy K T, Fisher G, Best R, Dutta P K., 1999. The Structural Behaviour of Layers of SnS Grown by Spray Pyrolysis. J. Phys. D: Appl. Phys, 32, 988–990.
  • 7. Sokolov I. A., 2000. Adaptive Photodetectors: Novel Approach for Vibration Measurements. Measurement, 27, 13– 9.
  • 8. Shi W, Huo L, Wang H, Zhang H, Yang J, Wei P., 2006. Hydrothermal Growth and Gas Sensing Property of Flower Shaped SnS2 Nanostructures. Nanotechnology, 17, 2918–2924.
  • 9. Tan F, Qu S , Zeng X, Zhang C, Shi M, Wang Z, Jin L, Bi Y, Cao J, Wang Z, Hou Y, Teng F, Feng Z., 2010. Photovoltaic Effect of Tin Disulfide with Nanocrystalline/ Amorphous Blended Phases. Solid State Communications, 150, 58–61.
  • 10. Seo J-W, Jang J-T, Park S-W, Kim C, Park B, Cheon J., 2008. Two-Dimensional SnS2 Nanoplates with Extraordinary High Discharge Capacity for Lithium Ion Batteries. Advanced Materials, 20, 4269–4273.
  • 11. De D, Manongdo J, See S, Zhang V, Guloy A., 2013. Haibing Peng. High on/off Ratio Field Effect Transistors Based on Exfoliated Crystalline SnS2 Nano-membranes. Nanotechnology 24-025202 (6pp).
  • 12. Sanchez-Juareza A, Tiburcio-Silverb A, Ortiz A., 2005. Fabrication of SnS2/SnS Heterojunction Thin Film Diodes by Plasma-Enhanced Chemical Vapor Deposition. Thin Solid Films 480–481:452 – 456.
  • 13. Kutchinsky J, Taboryski R, Sorensen C. B, Hansen J. B, Lindelof P. E., 2001. Experimental Investigation of Supercurrent Enchancement in S-N-S Junctions by Non-Equilibrium Injection into Supercurrent-Carrying Bound Andreev States. Physica C, 352- 4–10.
  • 14. Gajendiran J, Rajendran V., 2011. Synthesis of SnS2 Nanoparticles by a Surfactant-Mediated Hydrothermal Method and their Characterization. Nanosci. Nanotechnol. 2 - 015001 (4pp).
  • 15. Deshpande N.G, Sagade A. A, Gudage Y. G, Lokhande C. D., 2007. Ramphal Sharma. Growth and Characterization of Tin Disulfide (SnS2) Thin Film Deposited by Successive Ionic Layer Adsorption and Reaction (SILAR) technique. Journal of Alloys and Compounds, 436, 421–426.
  • 16. Cheng L. L, Liu M H , Wang S. C, Wang M. X, Wang G. D, Zhou Q. Y, Chen Z. Q., 2013. Nano-flower and Nano-wall SnS2 Films Fabricated with Controllable Shape and Size by the PECVD Method. Semicond. Sci. Technol. 28-015020 (8pp).
  • 17. Khelia C, Boubaker K, Ben Nasrallah T., Amlouk M, Belgacem S, Saadallah F, Yacoubi N., 2009. Morphological and Thermal Properties of b-SnS2 Crystals Grown by Spray Pyrolysis Technique. Journal of Crystal Growth, 311, 1032–1035.
  • 18. George J, Valsala Kumari C. K., 1983. Growth and Characterization of Tin Disulphide Crystals Grown by Physical Vapour Transport Method. Journal of Crystal Growth, 63, 233-238.
  • 19. Gupta R. K, Yakuphanoglu F., 2012. Photoconductive Schottky Diode Based on Al/p-Si/SnS2/Ag for Optical Sensör Applications. Solar Energy, 86, 1539–1545.
  • 20. Sreedevi G, Ramakrishna Reddy K. T., 2013. Dependence of Optical Properties of Chemical Bath Deposited SnS2 Films on Deposition Time. Solid State Physics, 1512, 688–689.
  • 21. Guneri E, Ulutas C, Kirmizigul F, Altindemir G, Gode F, Gumus C., 2010. Effect of Deposition Time on Structural, Electrical, and Optical Properties of Sns Thin Films Deposited by Chemical Bath Deposition. Applied Surface Science, 257, 1189–1195.
  • 22.Bar M, Ennaoui A, Klaer J, Saez-Araoz R, Kropp T, Weinhardt L, Heske C, Schock H. W, Fischer C. H, Lux-Steiner M. C., 2006. The Electronic Structure of the [Zn(S,O)/ZnS]/CuInS2 Heterointerface- Impact of Post-Annealing. Chemical Physics Letters, 433, 71–74.
  • 23.Panda A, Antonakos E, Liarokapis S, Bhattacharya S. Chaudhuri. S., 2007. Optical Properties of Nanocrystalline SnS2 Thin Films. S.K. Materials Research Bulletin, 42, 576–583.
  • 24.Ramakrishna Reddy K. T, Sreedevi G, Ramyaan K , Miles R.W., 2012. Physical Properties of Nano-Crystalline SnS2 Layers Grown by Chemical Bath Deposition. Energy Procedia, 15, 340 – 346.
  • 25.Kariper A, Güneri E, Göde F, Gümüs C, Özpozan T., 2011. The Structural, Electrical and Optical Properties of CdS Thin Films as a Function of pH. Materials Chemistry and Physics, 129, 183–188.
  • 26.Kırmızıgül F, Güneri E, Gümüş C., 2012. Effects of different deposition conditions on the Properties of Cu2S thin films, 93,511-523.
  • 27.Gümüş C, Ulutaş C, Esen R, Özkendir O. M, Ufuktepe Y., 2005. Preparation and Characterization of Crystalline Mns thin Films by Chemical Bath Deposition. Thin Solid Films, 492, 1–5.
  • 28.Schlaf R, Armstrong N. R, Parkinson B. A, Pettenkofer C, Jaegermann W., 2007. Vander Waals Epitaxy of the Layered Semiconductors SnSe2 and SnS2: Morphology and Growth Modes. Journal of Alloys and Compounds, 436, 421–426.
  • 29.Zhang Y. C, Du Z. N, Li S. Y, Zhang M., 2010. Novel Synthesis and High Visible Light Photocatalytic Activity of SnS2 Nanoflakes from SnCl2-2H2O and S powders. Applied Catalysis B: Environmental, 95, 153–159.
  • 30. Geng H, Su Y, Wei H, Xu M, Wei L, Yang Z, Zhang Y., 2013. Controllable Synthesis and Photoelectric Property of Hexagonal SnS2 Nanoflakes by Triton X–100 Assisted Hydrothermal Method. Materials Letters, 111, 204-207.
There are 30 citations in total.

Details

Journal Section Articles
Authors

Cebrail Gümüş

Gülay Altındemir This is me

Publication Date June 15, 2016
Published in Issue Year 2016 Volume: 31 Issue: 1

Cite

APA Gümüş, C., & Altındemir, G. (2016). N-Tipi SnS2 Yarıiletken İnce Filmlerin Hazırlanması ve Karakterizasyonu. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 31(1), 83-92. https://doi.org/10.21605/cukurovaummfd.317735
AMA Gümüş C, Altındemir G. N-Tipi SnS2 Yarıiletken İnce Filmlerin Hazırlanması ve Karakterizasyonu. cukurovaummfd. June 2016;31(1):83-92. doi:10.21605/cukurovaummfd.317735
Chicago Gümüş, Cebrail, and Gülay Altındemir. “N-Tipi SnS2 Yarıiletken İnce Filmlerin Hazırlanması Ve Karakterizasyonu”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 31, no. 1 (June 2016): 83-92. https://doi.org/10.21605/cukurovaummfd.317735.
EndNote Gümüş C, Altındemir G (June 1, 2016) N-Tipi SnS2 Yarıiletken İnce Filmlerin Hazırlanması ve Karakterizasyonu. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 31 1 83–92.
IEEE C. Gümüş and G. Altındemir, “N-Tipi SnS2 Yarıiletken İnce Filmlerin Hazırlanması ve Karakterizasyonu”, cukurovaummfd, vol. 31, no. 1, pp. 83–92, 2016, doi: 10.21605/cukurovaummfd.317735.
ISNAD Gümüş, Cebrail - Altındemir, Gülay. “N-Tipi SnS2 Yarıiletken İnce Filmlerin Hazırlanması Ve Karakterizasyonu”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 31/1 (June 2016), 83-92. https://doi.org/10.21605/cukurovaummfd.317735.
JAMA Gümüş C, Altındemir G. N-Tipi SnS2 Yarıiletken İnce Filmlerin Hazırlanması ve Karakterizasyonu. cukurovaummfd. 2016;31:83–92.
MLA Gümüş, Cebrail and Gülay Altındemir. “N-Tipi SnS2 Yarıiletken İnce Filmlerin Hazırlanması Ve Karakterizasyonu”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, vol. 31, no. 1, 2016, pp. 83-92, doi:10.21605/cukurovaummfd.317735.
Vancouver Gümüş C, Altındemir G. N-Tipi SnS2 Yarıiletken İnce Filmlerin Hazırlanması ve Karakterizasyonu. cukurovaummfd. 2016;31(1):83-92.