Elektrodepolanmış Nanokompozit Kaplamalarda Elektrolit Bileşenlerinin Etkisi

Year 2020, Volume: 35 Issue: 1, 159 - 172, 31.03.2020

Ersin Ünal Abdulkadir Yaşar İsmail Hakkı Karahan

https://doi.org/10.21605/cukurovaummfd.764753

Abstract

Bu çalışmada, nikel esaslı alaşım ve nanokompozit kaplamalar elektrokimyasal depolama metodu ile paslanmaz çelik altlık üzerine üretilmiştir. Watts tipi nikel banyosuna bor kaynağı olarak trimetilamin boran (TMAB) ilave edilerek Ni-B alaşım kaplama elde edilmiş, daha sonra buna ilave olarak banyoya titanyum diborür (TiB2) seramik nano parçacıkları ilave edilerek nanokompozit kaplama elde edilmiştir. Elektrolit bileşenlerinin kaplama özelliklerine etkilerini incelemek amacıyla elektrokimyasal, mikrosertlik, korozyon dayanımı ve yüzey morfolojileri açısından analizler yapılmıştır. Yapılan incelemeler sonucunda her banyo bileşeninin morfoloji, sertlik ve korozyon dayanımı gibi özellikleri ciddi miktarda etkilediği görülmektedir. Genel olarak yüzey morfolojiler pürüzsüz olmakla birlikte, nanokompozit kaplamanın yüzeyinin daha kaba olduğu optik resimlerden anlaşılmaktadır. Ana yapıya bor elementi ilavesi mikro sertliği yaklaşık %38 oranında artırırken, TiB2 takviyesiyle birlikte saf nikele göre %140, Ni-B alaşımına göre %75 oranında iyileşme olmasına sebep olmuştur. Bor takviyesi korozyon dayanımını azaltırken, TiB2 takviyesi korozyon dayanımında artışa neden olmuştur.

Keywords

Elektrodepolama, Nanokompozit kaplamalar, Ni-B alaşım, Elektrokimyasal kaplama

Effect of Electrolyte Components on Electrodeposited Nanocomposite Coatings

Abstract

In this study, nickel-based alloy and nanocomposite coatings were produced on a stainless steel base with the electrochemical deposition method. Ni-B alloy coating was obtained by adding trimethylamine borane (TMAB) as a boron source to the Watts type nickel bath, and in addition, titanium diboride (TiB2) ceramic nanoparticles were added to the bath in order to obtain a nanocomposite coating. In order to examine the effects of electrolyte components on coating properties, analyzes were carried out in terms of electrochemical, microhardness, corrosion resistance and surface morphology. As a result of the examinations, it was seen that each bath component has a serious effect on the coating properties such as morphology, hardness and corrosion resistance. In general, although surface morphologies were smooth, it was understood from the optical images that the surface of the nanocomposite coating was more coarser. While the addition of boron element to the main structure increased the microhardness by about 38%, with the TiB2 supplement, it caused 140% improvement over pure nickel and 75% improvement over Ni-B alloy. While boron reinforcement reduced corrosion resistance, TiB2 reinforcement caused an increase in corrosion resistance.

Keywords

Electrodeposition, Nanocomposite coatings, Ni-B alloys, Electrochemical coatings

References

• 1. Tozar, A., Karahan, İ.H., 2020. Effect of Octylphenyl Ether Group Nonionic Surfactant on the Electrodepositon of the Hexagonal Boron Nitride Reinforced Ni-B Matrix Composite Coatings, Surface & Coatings Technology, 381, 125131.
• 2. Baosong, L., Xiao, L., Yuxing, H., Wenzhe, X., Weiwei, Z., 2018. Influence of Alumina Nanoparticles on Microstructure and Properties of Ni-B Composite Coating, Journals of Alloys and Compounds, 762, 133-142.
• 3. Dandan, L., Baosong, L., Shengsong, D., Weiwei, Z., 2019. Synthesis of a Novel Ni– B/YSZ Metal-ceramic Composite Coating Via Singlestep Electrodeposition at Different Current Density, Ceramics International, 45, 24884–24893.
• 4. García-Aguirre, C.A., Domínguez-Ríos, C., Torres-Sánchez, R., Román-Aguirre, M., Holguín-Momaca, J.T., Aguilar-Elguézabal, A., 2015. Microstructure and Transmission Electron Microscopy Characterization of Electroless Ni-B Thin Films Deposited on MWCNTs, Surface & Coatings Technology, 282, 107–114.
• 5. Shakoor, R.A., Kahraman, R., Waware, U., Wang, Y., Gao, W., 2014. Properties of Electrodeposited Ni-B-Al2O3 Composite Coatings, Materials & Design, 64, 127–135.
• 6. Shakoor, R.A., Kahraman, R., Waware, U.S., Wang, Y., Gao, W., 2014. Synthesis and Properties of Electrodeposited Ni-B-CeO2 Composite Coatings Materials & Design, 59, 421–429.
• 7. Kanani, N., 2004. Electroplating: Basic Principles, Processes and Practice, Elsevier Advanced Technology, Oxford, U.K.
• 8. Srivastava, M., William, G.V., Rajam, K.S., 2007. Electrochemical Deposition and Tribological Behaviour of Ni and Ni-Co Metal Matrix Composites with SiC Nano-particles. Applied Surface Science, 253, 3814.
• 9. Singh, V.B., Singh, D.K., 2014. An Overview on the Preparation, Characterization and Properties of Electrodeposited-Metal Matrix Nanocomposites, Nano sci Technol 1 (3), 1-20.
• 10. Koch, C.C., 2007. Structural Nanocrystalline Materials: An Overwiew, J. Mater. Sci. 42, 1403.
• 11. Shakoor, R.A., Kahraman, R., Waware, U.S., Wang, Y., Gao, W., 2014. Synthesis and Properties of Electrodeposited Ni-B-Zn Ternary Alloy Coatings, Int. J. Electrochem. Sci., 9, 5520.
• 12. Ünal, E., Yaşar, A., Karahan, İ.H., 2019. A Review of Electrodeposited Composite Coatings with Ni-B Alloy Matrix, Maretials Research Express, 6, 092004.
• 13. Ünal, E., Karahan, İ.H., 2018. Production and Characterization of Electrodeposited Ni-B/hBN Composite Coatings, Surface & Coatings Technology, 333, 125-137.
• 14. Ünal, E., Karahan, İ.H., 2018. Investigation of Effect of the Bath Components on Coating Properties in Electrodeposition of Ni, Ni-B and Ni-B/hBN Coatings, Sakarya University Journal of Science, 22 (2), 663-672.
• 15. Ünal, E., Karahan, İ.H., 2018. Effects of Ultrasonic Agitation Prior to Deposition and Additives in the Bath on Electrodeposited Ni- B/hBN Composite Coatings, Journal of Alloys and Compounds, 763, 329-341.
• 16. Tozar, A., Karahan, İ.H., 2019. Investigation of the Mechanical Properties of Ni-B/hBN Composite Coatings Electrodeposited in Presence of CTAB as the Surfactant, Materials Research Express, Volume 6, Number 12.
• 17. Baosong, L., Weiwei, Z., 2020. Facile Synthesis and Electrochemical Properties of a Novel Ni-B/TiC Composite Coating Via Ultrasonic-assisted Electrodeposition, Ultrasonics-Sonochemistry 61, 104837.
• 18. Hosseini, M.G., Ahmadiyeh, S., Rasooli, A., 2019. Pulse Plating of Ni–B/WC Nanocomposite Coating and Study of its Corrosion and Wear Resistance, Materials Science and Technology, 35(10), 1248-1256.
• 19. Ahmadiyeh, S., Rasooli, A., Hosseini, M.G., 2019. Ni–B/SiC Nanocomposite Coating Obtained by Pulse Plating and Evaluation of its Electrochemistry and Mechanical Properties, Surface Engineering, 35(10), 861-872.
• 20. Li, B.S., Huan, Y.X., Luo, H., Zhang, W.W., 2019. Electrodeposition and Properties of Ni–B/SiC Nanocomposite Coatings, Surface Engineering, 35(2), 109-119.
• 21. Mehr, M.S., Akbari, A., Damerchi, E., 2019. Electrodeposited Ni-B/SiC Micro- and Nano-composite Coatings: A Comparative Study, Journal of Alloys and Compounds, 782, 477-487.
• 22. Krishnaveni, K., Narayanan, T.S.N.S., Seshadri, S.K., 2008. Electrodeposited Ni-B-Si3N4 Composite Coating: Preparation and Evaluation of its Characteristic Properties, J. of Alloys and Compounds, 466, 412-420.
• 23. Monteiro, O.R., Murugesan, S., Khabashesku, V., 2015. Electroplated Ni–B Films and Ni–B Metal Matrix Diamond Nanocomposite Coatings, Surface & Coatings Technology, 272, 291–297.
• 24. Ogihara, H., Safuan, M., Saji, T., 2012. Effect of Electrodeposition Conditions on Hardness of Ni–B/diamond Composite Films, Surface & Coatings Technology, 212, 180-184.
• 25. Shakoor, R.A., Waware, U.S., Ali, K., Kahraman, R., Popelka, A., Yusuf, M.M., Hasan, A., 2017. Novel Electrodeposited Ni-B/Y2O3 Composite Coatings with Improved Properties, Coatings, 7, 161.
• 26. Waware, S., Wasekar, N.P., 2017. Manufacture and Properties of Ni-B-Fe2O3 Composite Nano- Coatings by Electrodeposition, Journal of Material Sciences & Engineering, 6, 6.
• 27. Waware, U.S., Hamoudaa, A.M.S., Wasekar, N.P., 2018. Mechanical Properties, Thermal Stability and Corrosion Behavior of Electrodeposited Ni-B/AlN Nanocomposite Coating, Surface & Coatings Technology, 337, 335-341.
• 28. Waware, U.S., Hamouda, A.M.S., Bajaj, B., Borkar, T., Pradhan, A.K., 2018. Synthesis and Characterization of Electrodeposited Ni-B-Tl2O3 Composite Coatings, Journal of Alloys and Compounds, 769, 353-359.
• 29. Ett, G., Pessine, E.J., 1999. Pulse Current Plating of TiB2 in Molten Fluoride, Electrochimica Acta, 44, 2859-2870.
• 30. Gyawali, G., Cho, S.H., Lee, S.W., 2013. Electrodeposition and Characterization of Ni-TiB2 Composite Coatings, Metals and Materials International, 19(1), 113-118.
• 31. Gyawali, G., Tripathi, K., Joshi, B., Lee, S.W., 2017. Mechanical and Tribological Properties of Ni-W-TiB2 Composite Coatings, Journal of Alloys and Compounds, 721, 757-763.
• 32. Xiaozhen, L., Yifan, L., Lingling, S., Xiaowen, S., 2010. Preparation and Performance of Electrodeposited Ni-TiB2-Sm2O3 Composite Coatings, Journal of Rare Earths, 28, 97.
• 33. Xiaozhen, L., Xin, L., Aibing, Y., Weijue, H., 2009. Preparation and Tribological Performance of Electrodeposited Ni-TiB2-Dy2O3 Composite Coatings, Journal of Rare Earths, 27(3), 480.
• 34. Sheu, H.H., Tzeng, Y.C., Syu, J.H., 2019. Study of the Strengthening Mechanism of Electrodeposited Ni-B Thin Films with Ultra-low Boron Content, Materials Letters, 238, 275-277.
• 35. Tozar, A., 2012. Düşük Karbonlu Çeliğin Çevreci ZnNi/Polianilin İletken Polimer ile Kaplanması ve Kaplanan Çeliğin Korozyon Davranışının İncelenmesi, Mustafa Kemal Üniversitesi, Fen Bilimleri Enstitüsü. Yüksek Lisans Lisans Tezi, Hatay.
• 36. Lee, K.H., Chang, D., Kwon, S.C., 2005. Properties of Electrodeposited Nanocrystalline Ni-B Alloy Films, Electrochimica Acta, 50, 4538-4543.
• 37. Lekka, M., Offoiach, R., Lanzutti, A., Mughal, M.Z., Sebastiani, M., Bemporad, E., Fedrizzi, L., 2018. Ni-B Electrodeposits with Low B Content: Effect of DMAB Concentration on the Internal Stresses and the Electrochemical Behaviour, Surface & Coatings Technology, 344, 190–196.
• 38. Matsui, I., Omura, N., Yamamoto, T., Takigawa, Y., 2018. Electrodeposition with Intermittent Addition of Trimethylamine Borane to Produce Ductile Bulk Nanocrystalline Ni–B Alloys, Surface & Coatings Technology, 337, 411–417.
• 39. Guglielmi, N., 1972. Kinetics of the Deposition of Inert Particles from Electrolytic Baths, Journal of The Electrochemical Society, 119 (8), 1009-1012.
• 40. Öztekin, K., 2014. Çinko Kaplanmış Karbon Çeliğinin Na-okzalat ve Na-tartarat Ortamlarında Polianilin ve Poli-o-anisidin ile Kaplanarak Korozyon Direncinin Geliştirilmesi, Mustafa Kemal Üniversitesi, Fen Bilimleri Enstitüsü. Yüksek Lisans Lisans Tezi, Hatay.
• 41. Tozar, A., Karahan, İ.H., 2014. Structural and Corrosion Protection Properties of Electrochemically Deposited Nano-sized Zn-Ni Alloy Coatings, Appl. Surf. Sci. 318, 15-23.
• 42. Kasturibai, S., Kalaignan, G.P., 2014, Characterizations of Electrodeposited Ni–CeO2 Nanocomposite Coatings, Materials Chemistry and Physics, 147, 1042-1048.
• 43. Wang, Y., Wang, S., Shu, X., Gao, W., Lu, W., Yan, B., 2014. Preparation and Property of Sol- Enhanced Ni–B–TiO2 Nano-composite Coatings, J. of Alloys and Compounds, 617, 472-478.