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TALK VE EPDM MİKTARININ PP/TALK/EPDM KOMPOZİTİNİN MEKANİKSEL ÖZELLİKLERİNE ETKİSİNİN İNCELENMESİ

Year 2017, Volume: 19 Issue: 55, 295 - 303, 01.01.2017

Abstract

Bu çalışmada, talk ve EPDM miktarının PP/Talk/EPDM
kompozitlerinin çekme ve darbe dayanımı gibi mekanik özellikleri
üzerine etkileri incelenmiştir. Bu amaçla, PP polimerine %15 talk
ve % 5-20 oranlarında EPDM elastomeri ilave edilmiştir. Karışım
çift vidalı ekstruderde gerçekleştirilmiş olup, çekme ve darbe
numuneleri enjeksiyonla kalıpla tekniği kullanılarak
gerçekleştirilmiştir. Çalışma sonucunda, PP polimerine ilave
edilen talk minerali ile çekme dayanımı ve elastisite modülü
artarken darbe dayanımı azalmıştır. Bununla birlikte,
PP/Talk/EPDM polimer kompozitinde artan EPDM miktarı ile
çekme dayanımı ve elastisite modülü azalırken darbe dayanımı
artmıştır. Kırılma analizleri SEM analizi ile yapılmıştır

References

  • Iman, H., Javad, S., Gity, M.M.S., Seyed, M.D. 2011. Assessment of rheological properties materials based on thermoplastic olefin blend and organoclay,
  • Materials and Design, Cilt. 32, s. –655. mechanical of nanostructured Karger-Kocsis J. (Ed.). 1995,
  • Polypropylene; strucuture, blends and Chapman & Hall. Cambridge: Yang, Y., Chen, J., Yuan, Q., Misra, R.D.K. 2011. Structure–property relationship in impact modified nanoclay-reinforced polypropylene, Materials Science and Engineering A, Cilt. 528, s.1857–1863.
  • Xinqing, S., Youqing, H., Jinliang, Q., Yiqun, L., Xiaohong, Z., Jianming, G., Zhihai, S., Fan, H., Manli, Z. 2004. The Microstructure and Properties in
  • PP/Rubber Powder/nano-CaCO3 Ternary Blends, Macromolecular Materials and Engineering, Cilt. , s.275–280. between Sedigheh, B.K., Daniel, F., Yanhui, C., Luke, M.G., Alireza, K., Reza, B., Clement, L.H., Hongzhou, Z., Biqiong, C. 2012. Morphology, rheology properties polypropylene/ethylene–octene copolymer/clay nanocomposites:
  • Effects of the compatibilizer, Composites Science and Technology, Cilt. 72, s.1697–1704. mechanical of
  • Hong, Y., Qin, Z., Min, G., Cong, W., Rongni, D., Qiang, F. 2006. Study on the toughening PP/EPDM/SiO2 composites, Polymer, Cilt. 47, s. –2115. and in ternary
  • Bendjaouahdou, C., Bensaad, S. Properties of Polypropylene/(NaturalRubber)/ Organomontmorillonite Nanocomposites Prepared by Melt Blending, Journal Of Vınyl & Addıtıve Technology, s. 48-57. Joy, K.M., Keun-Joon, H., Chang-Sık, H. 2005. Preparation, mechanical and rheological properties of a thermoplastic polyolefin (TPO) / organoclay nanocomposite with reference to the effect of maleic anhydride modified polypropylene as a compatibilizer, Polymer, Cilt.46, s.1995–2002.
  • Yiqun, L., Marianna, K. 2006. The structure and physical properties of thermoplastic nanocomposites nanosilica, Polymer, Cilt.47, s.7731- and olefin containing Rajkiran, R.T., Paul, D.R. 2011.
  • Polypropylene-elastomer nanocomposites: 1. Morphology, Polymer, Cilt.52, s. 4955-4969.
  • Qiu, M., Xuming, S., Patricia, C.T., Xinmin, L., Zhongqin, L. 2010. Mechanical
  • Thermoplastic Olefin Composites: Effect of Fillers Content, Strain Rate and Temperature, Polymer- Plastics Engineering, Cilt. 49, s.121–127. Hugo, M.T., Daiane, T., Fabrício, C., Vanda, F.R., Sônia, M.B.N. 2013. Use of wollastonite in a thermoplastic elastomer composition, Polymer Testing, Cilt.32, s.1373–1378.
  • Matonis, V.A., Small, N.C. 1969. A macroscopic composites containing layered spherical
  • Engineering Science, Cilt.9, s.99- of inclusion, Polymer Matonis, V.A., Small, N.C. 1969. The interfacial streses in particulate composite
  • Engineering Science, Cilt.9, s.100- Polymer mechanical-properties of of composites wıthınorganıc Cheng, T.W., Keskkula. H., PAUL, D.R. Morphology Ternary Blends of Polycarbonate, Brittle Polymers And an İmpact Modifier, Polymer, CİLT. 33, S. 606- and for Lubomır, L.J., Pavlına, J., Barbora, L., Rıchard, T., Rıchard, G., Neıl, R. Effect of the talc filler content properties composites, Journal of Applied Polymer Science, Cilt.110, s. 2742– mechanical of polypropylene
  • Leong, Y.W., Bakar, A.M.B., Ishak, Z.A.M., Ariffin, A., Pukanszky, B. mechanical interfacial interactions between talc, kaolin, and calcium carbonate filled polypropylene composites, Journal of Applied Polymer Science, Cilt.91, s. 3315–3326. of the and properties
  • Öksüz, M., Eroglu, M., Yıldırım, H. Effect of talc on the properties of Polypropylene / Ethylene / Propylene / Diene terpolymer blends, Journal of Applied Polymer Science, Cilt.101, s. –3039.
  • Tara, J.M. 2007. Properties and Foaming thermoplastic olefin blends based on polypropylene, Degree of Master of
  • Science (Engineering), Queen’s University, Canada. of linear and branched Kingston, Ontario, Qıu, M., Xumıng, S., Patrıcıa, C.T., Xınmın, L., Zhongqın, L. 2010. Mechanical thermoplastic olefin composites: of
  • Effect of fillers content, strain rate and temperature, Polymer-Plastics Technology Cilt.49, s.121–127. Krıstıına, O., Craıg, C. 1998. Mechanical polypropylene-wood morphology of impact modified flour composites, Journal of Applied
  • Polymer Science, Cilt. 67, s. 1503- properties and Chandra, A., Gong, S., Mıngjun, Y.,
  • Lıh-Sheng, T., Paul, G., Holger, C. crystallography in microcellular injection-molded nanocomposite and neat resın, Polymer Engineering and Science, s. 61. and Polyamide-6 Marerı, P., Bastıde, S., Bında, N., Crespy, 1998. A. Mechanical behaviour composites containing fine mineral filler: effect of filler surface treatment, Composites Science and Technology, Cilt. 58, s. 747-752. Suresha, B., Ravı, B.N.K.,
  • Venkataramareddy, M., Jayaraju, T. Role of micro/nano fillers on mechanical properties of Polyamide66 / Polypropylene Materials and Design, Cilt. 31, s. –2000. tribological composites,
  • Gafur, M.A., Rahıma, N., Forhad, M.M., Abu, M.H.B., Yukıhıro, T., Tsutomu, A. 2010. Structures and properties of the compression- molded istactic-polypropylene/talc composites: Effect of cooling and rolling, Polymer Degradation and Stability, Cilt. 95, s. 1818-1825.

Investigation of The Effect of The Amount of Talk and EPDM onMechanical Properties of PP/Talc/EPDM Composites

Year 2017, Volume: 19 Issue: 55, 295 - 303, 01.01.2017

Abstract

In this study, the effect of talc and EPDM content on mechanical properties such as tensile and impact of PP/Talc/EPDM composite samples were examined. For this purpose, 15% talc and 5-20% EPDM was added to PP polymer. The mixture has taken placed in a twin screw extruder, and tensile and impact specimens were performed using the injection molding technique. As a result of, the tensile strength and modulus of elasticity increased while impact strength increased with talc added to PP polymer. Furthermore, tensile strength and modulus of elasticity decreased while impact strength increased with increase amount of the EPDM in the PP/Talk/EPDM polymer composite. Fracture surface analyzes were performed by SEM analysis

References

  • Iman, H., Javad, S., Gity, M.M.S., Seyed, M.D. 2011. Assessment of rheological properties materials based on thermoplastic olefin blend and organoclay,
  • Materials and Design, Cilt. 32, s. –655. mechanical of nanostructured Karger-Kocsis J. (Ed.). 1995,
  • Polypropylene; strucuture, blends and Chapman & Hall. Cambridge: Yang, Y., Chen, J., Yuan, Q., Misra, R.D.K. 2011. Structure–property relationship in impact modified nanoclay-reinforced polypropylene, Materials Science and Engineering A, Cilt. 528, s.1857–1863.
  • Xinqing, S., Youqing, H., Jinliang, Q., Yiqun, L., Xiaohong, Z., Jianming, G., Zhihai, S., Fan, H., Manli, Z. 2004. The Microstructure and Properties in
  • PP/Rubber Powder/nano-CaCO3 Ternary Blends, Macromolecular Materials and Engineering, Cilt. , s.275–280. between Sedigheh, B.K., Daniel, F., Yanhui, C., Luke, M.G., Alireza, K., Reza, B., Clement, L.H., Hongzhou, Z., Biqiong, C. 2012. Morphology, rheology properties polypropylene/ethylene–octene copolymer/clay nanocomposites:
  • Effects of the compatibilizer, Composites Science and Technology, Cilt. 72, s.1697–1704. mechanical of
  • Hong, Y., Qin, Z., Min, G., Cong, W., Rongni, D., Qiang, F. 2006. Study on the toughening PP/EPDM/SiO2 composites, Polymer, Cilt. 47, s. –2115. and in ternary
  • Bendjaouahdou, C., Bensaad, S. Properties of Polypropylene/(NaturalRubber)/ Organomontmorillonite Nanocomposites Prepared by Melt Blending, Journal Of Vınyl & Addıtıve Technology, s. 48-57. Joy, K.M., Keun-Joon, H., Chang-Sık, H. 2005. Preparation, mechanical and rheological properties of a thermoplastic polyolefin (TPO) / organoclay nanocomposite with reference to the effect of maleic anhydride modified polypropylene as a compatibilizer, Polymer, Cilt.46, s.1995–2002.
  • Yiqun, L., Marianna, K. 2006. The structure and physical properties of thermoplastic nanocomposites nanosilica, Polymer, Cilt.47, s.7731- and olefin containing Rajkiran, R.T., Paul, D.R. 2011.
  • Polypropylene-elastomer nanocomposites: 1. Morphology, Polymer, Cilt.52, s. 4955-4969.
  • Qiu, M., Xuming, S., Patricia, C.T., Xinmin, L., Zhongqin, L. 2010. Mechanical
  • Thermoplastic Olefin Composites: Effect of Fillers Content, Strain Rate and Temperature, Polymer- Plastics Engineering, Cilt. 49, s.121–127. Hugo, M.T., Daiane, T., Fabrício, C., Vanda, F.R., Sônia, M.B.N. 2013. Use of wollastonite in a thermoplastic elastomer composition, Polymer Testing, Cilt.32, s.1373–1378.
  • Matonis, V.A., Small, N.C. 1969. A macroscopic composites containing layered spherical
  • Engineering Science, Cilt.9, s.99- of inclusion, Polymer Matonis, V.A., Small, N.C. 1969. The interfacial streses in particulate composite
  • Engineering Science, Cilt.9, s.100- Polymer mechanical-properties of of composites wıthınorganıc Cheng, T.W., Keskkula. H., PAUL, D.R. Morphology Ternary Blends of Polycarbonate, Brittle Polymers And an İmpact Modifier, Polymer, CİLT. 33, S. 606- and for Lubomır, L.J., Pavlına, J., Barbora, L., Rıchard, T., Rıchard, G., Neıl, R. Effect of the talc filler content properties composites, Journal of Applied Polymer Science, Cilt.110, s. 2742– mechanical of polypropylene
  • Leong, Y.W., Bakar, A.M.B., Ishak, Z.A.M., Ariffin, A., Pukanszky, B. mechanical interfacial interactions between talc, kaolin, and calcium carbonate filled polypropylene composites, Journal of Applied Polymer Science, Cilt.91, s. 3315–3326. of the and properties
  • Öksüz, M., Eroglu, M., Yıldırım, H. Effect of talc on the properties of Polypropylene / Ethylene / Propylene / Diene terpolymer blends, Journal of Applied Polymer Science, Cilt.101, s. –3039.
  • Tara, J.M. 2007. Properties and Foaming thermoplastic olefin blends based on polypropylene, Degree of Master of
  • Science (Engineering), Queen’s University, Canada. of linear and branched Kingston, Ontario, Qıu, M., Xumıng, S., Patrıcıa, C.T., Xınmın, L., Zhongqın, L. 2010. Mechanical thermoplastic olefin composites: of
  • Effect of fillers content, strain rate and temperature, Polymer-Plastics Technology Cilt.49, s.121–127. Krıstıına, O., Craıg, C. 1998. Mechanical polypropylene-wood morphology of impact modified flour composites, Journal of Applied
  • Polymer Science, Cilt. 67, s. 1503- properties and Chandra, A., Gong, S., Mıngjun, Y.,
  • Lıh-Sheng, T., Paul, G., Holger, C. crystallography in microcellular injection-molded nanocomposite and neat resın, Polymer Engineering and Science, s. 61. and Polyamide-6 Marerı, P., Bastıde, S., Bında, N., Crespy, 1998. A. Mechanical behaviour composites containing fine mineral filler: effect of filler surface treatment, Composites Science and Technology, Cilt. 58, s. 747-752. Suresha, B., Ravı, B.N.K.,
  • Venkataramareddy, M., Jayaraju, T. Role of micro/nano fillers on mechanical properties of Polyamide66 / Polypropylene Materials and Design, Cilt. 31, s. –2000. tribological composites,
  • Gafur, M.A., Rahıma, N., Forhad, M.M., Abu, M.H.B., Yukıhıro, T., Tsutomu, A. 2010. Structures and properties of the compression- molded istactic-polypropylene/talc composites: Effect of cooling and rolling, Polymer Degradation and Stability, Cilt. 95, s. 1818-1825.
There are 24 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Other ID JA55TH79SF
Journal Section Research Article
Authors

Salih Hakan Yetgin This is me

Publication Date January 1, 2017
Published in Issue Year 2017 Volume: 19 Issue: 55

Cite

APA Yetgin, S. H. (2017). TALK VE EPDM MİKTARININ PP/TALK/EPDM KOMPOZİTİNİN MEKANİKSEL ÖZELLİKLERİNE ETKİSİNİN İNCELENMESİ. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi, 19(55), 295-303.
AMA Yetgin SH. TALK VE EPDM MİKTARININ PP/TALK/EPDM KOMPOZİTİNİN MEKANİKSEL ÖZELLİKLERİNE ETKİSİNİN İNCELENMESİ. DEUFMD. January 2017;19(55):295-303.
Chicago Yetgin, Salih Hakan. “TALK VE EPDM MİKTARININ PP/TALK/EPDM KOMPOZİTİNİN MEKANİKSEL ÖZELLİKLERİNE ETKİSİNİN İNCELENMESİ”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi 19, no. 55 (January 2017): 295-303.
EndNote Yetgin SH (January 1, 2017) TALK VE EPDM MİKTARININ PP/TALK/EPDM KOMPOZİTİNİN MEKANİKSEL ÖZELLİKLERİNE ETKİSİNİN İNCELENMESİ. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen ve Mühendislik Dergisi 19 55 295–303.
IEEE S. H. Yetgin, “TALK VE EPDM MİKTARININ PP/TALK/EPDM KOMPOZİTİNİN MEKANİKSEL ÖZELLİKLERİNE ETKİSİNİN İNCELENMESİ”, DEUFMD, vol. 19, no. 55, pp. 295–303, 2017.
ISNAD Yetgin, Salih Hakan. “TALK VE EPDM MİKTARININ PP/TALK/EPDM KOMPOZİTİNİN MEKANİKSEL ÖZELLİKLERİNE ETKİSİNİN İNCELENMESİ”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen ve Mühendislik Dergisi 19/55 (January 2017), 295-303.
JAMA Yetgin SH. TALK VE EPDM MİKTARININ PP/TALK/EPDM KOMPOZİTİNİN MEKANİKSEL ÖZELLİKLERİNE ETKİSİNİN İNCELENMESİ. DEUFMD. 2017;19:295–303.
MLA Yetgin, Salih Hakan. “TALK VE EPDM MİKTARININ PP/TALK/EPDM KOMPOZİTİNİN MEKANİKSEL ÖZELLİKLERİNE ETKİSİNİN İNCELENMESİ”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi, vol. 19, no. 55, 2017, pp. 295-03.
Vancouver Yetgin SH. TALK VE EPDM MİKTARININ PP/TALK/EPDM KOMPOZİTİNİN MEKANİKSEL ÖZELLİKLERİNE ETKİSİNİN İNCELENMESİ. DEUFMD. 2017;19(55):295-303.

Dokuz Eylül Üniversitesi, Mühendislik Fakültesi Dekanlığı Tınaztepe Yerleşkesi, Adatepe Mah. Doğuş Cad. No: 207-I / 35390 Buca-İZMİR.