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The Experimental Investigation of The Recycling Effect on The Low Strain Rate Behavior of HDPE and PP Materials Under Tensile Loading

Year 2025, Volume: 27 Issue: 81, 473 - 484, 29.09.2025
https://doi.org/10.21205/deufmd.2025278115

Abstract

Thermoplastics are widely used as engineering materials due to their advantages such as lightweight, corrosion resistance, and low cost. However, thermoplastic waste stands out as one of the major contributors to environmental pollution. This situation not only presents an economic disadvantage but also reduces the quality of life. The recyclability of thermoplastic materials is a crucial feature to address these disadvantages. Recycling not only conserves raw materials but also reduces environmental pollution. However, changes in the molecular structure of thermoplastics during the recycling process can lead to degradation in their rheological and mechanical properties. In this project, The impact of recycling via extrusion on tensile strength and the elasticity modulus of High-Density Polyethylene (HDPE) and Polypropylene (PP) materials at different strain rates was investigated. The raw HDPE material was recycled once and thrice, while the raw PP material was recycled once. The results indicated that the mechanical properties of HDPE material remain largely unaffected even after three recycling processes, while the PP material shows a slight reduction in elasticity after one recycling process. Additionally, an increase in mechanical properties was observed for all material types at high strain rates. While this increase was nearly the same for both raw and recycled HDPE materials, recycled PP materials exhibited a higher increase in mechanical properties compared to raw PP material. The results suggest that HDPE and PP materials subjected to a limited number of recycling processes can still be used as engineering materials.

References

  • Ibeh, C.C. 2011. Thermoplastic Materials: Properties, Manufacturing Methods, and Applications. CRC Press.
  • Coulier, L., Orbons, H.G.M., Rijk, R. 2007. Analytical protocol to study the food safety of (multiple-)recycled high-density polyethylene (HDPE) and polypropylene (PP) crates: Influence of recycling on the migration and formation of degradation products, Polymer Degradation and Stability, Vol. 92, no. 11, pp. 2016-2025, DOI: 10.1016/j.polymdegradstab.2007.07.022.
  • Simões, C.L., Costa Pinto, L.M., Bernardo, C.A. 2013. Environmental and economic assessment of a road safety product made with virgin and recycled HDPE: A comparative study, Journal of Environmental Management, Vol. 114, pp. 209-215, DOI: 10.1016/j.jenvman.2012.10.001.
  • Achilias, D.S., Roupakias, C., Megalokonomos, P., Lappas, A.A., Antonakou, E.V. 2007. Chemical recycling of plastic wastes made from polyethylene (LDPE and HDPE) and polypropylene (PP), Journal of Hazardous Materials, Vol. 149, no. 3, pp. 536-542, DOI: 10.1016/j.jhazmat.2007.06.076.
  • Özyurt, H. 2020. Design and properties of composite sustainable building material by using waste HDPE, Mühendislik Bilimleri ve Tasarım Dergisi, Vol. 8, no. 3, pp. 777-782, DOI: 10.21923/jesd.741478.
  • Ragaert, K., Delva, L., Van Geem, K. 2017. Mechanical and chemical recycling of solid plastic waste, Waste Management, Vol. 69, pp. 24-58, DOI: 10.1016/j.wasman.2017.07.044.
  • PlasticsEurope. 2015. Plastics - the Facts 2015. An Analysis of European Plastics Production, Demand and Recovery for 2015.
  • COP26. 2022. COP26 Presidency Outcomes The Climate Pact. https://ukcop26.org/wp-content/uploads/2021/11/COP26-Presidency-Outcomes-The-Climate-Pact.pdf (Accessed: Sep. 20, 2025).
  • Zheng, J., Suh, S. 2019. Strategies to reduce the global carbon footprint of plastics, Nature Climate Change, Vol. 9, no. 5, pp. 374-378, DOI: 10.1038/s41558-019-0459-z.
  • Turner, D.A., Williams, I.D., Kemp, S. 2015. Greenhouse gas emission factors for recycling of source-segregated waste materials, Resources, Conservation and Recycling, Vol. 105, pp. 186-197, DOI: 10.1016/j.resconrec.2015.10.026.
  • Jin, H., Gonzalez-Gutierrez, J., Oblak, P., Zupančič, B., Emri, I. 2012. The effect of extensive mechanical recycling on the properties of low density polyethylene, Polymer Degradation and Stability, Vol. 97, no. 11, pp. 2262-2272, DOI: 10.1016/j.polymdegradstab.2012.07.039.
  • Raquez, J.-M., Bourgeois, A., Jacobs, H., Degée, P., Alexandre, M., Dubois, P. 2011. Oxidative degradations of oxodegradable LDPE enhanced with thermoplastic pea starch: Thermo-mechanical properties, morphology, and UV-ageing studies, Journal of Applied Polymer Science, Vol. 122, no. 1, pp. 489-496, DOI: 10.1002/app.34190.
  • Andersson, T., Holmgren, M.H., Nielsen, T., Wesslén, B. 2005. Degradation of low density polyethylene during extrusion. IV. Off-flavor compounds in extruded films of stabilized LDPE, Journal of Applied Polymer Science, Vol. 95, no. 3, pp. 583-595, DOI: 10.1002/app.21264.
  • Hamad, K., Kaseem, M., Deri, F. 2011. Effect of recycling on rheological and mechanical properties of poly(lactic acid)/polystyrene polymer blend, Journal of Materials Science, Vol. 46, no. 9, pp. 3013-3019, DOI: 10.1007/s10853-010-5179-8.
  • Abad, M.J. et al. 2004. Effects of a mixture of stabilizers on the structure and mechanical properties of polyethylene during reprocessing, Journal of Applied Polymer Science, Vol. 92, no. 6, pp. 3910-3916, DOI: 10.1002/app.20420.
  • Vidakis, N., Petousis, M., Maniadi, A. 2021. Sustainable Additive Manufacturing: Mechanical Response of High-Density Polyethylene over Multiple Recycling Processes, Recycling, Vol. 6, no. 1, p. 4, DOI: 10.3390/recycling6010004.
  • Zhang, J., Hirschberg, V., Rodrigue, D. 2023. Mechanical fatigue of recycled and virgin high-/low-density polyethylene, Journal of Applied Polymer Science, Vol. 140, no. 2, DOI: 10.1002/app.53312.
  • Vidakis, N., Petousis, M., Maniadi, A., Koudoumas, E., Vairis, A., Kechagias, J. 2020. Sustainable Additive Manufacturing: Mechanical Response of Acrylonitrile-Butadiene-Styrene over Multiple Recycling Processes, Sustainability, Vol. 12, no. 9, p. 3568, DOI: 10.3390/su12093568.
  • Strangl, M., Ortner, E., Buettner, A. 2019. Evaluation of the efficiency of odor removal from recycled HDPE using a modified recycling process, Resources, Conservation and Recycling, Vol. 146, pp. 89-97, DOI: 10.1016/j.resconrec.2019.03.009.
  • Yıldız Zeyrek, B., Aydoğan, B., Dilekcan, E., Öztürk, F. 2023. Recycle potential of thermoplastic composites, Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, DOI: 10.28948/ngumuh.1258388.
  • Oblak, P., Gonzalez-Gutierrez, J., Zupančič, B., Aulova, A., Emri, I. 2015. Processability and mechanical properties of extensively recycled high density polyethylene, Polymer Degradation and Stability, Vol. 114, pp. 133-145, DOI: 10.1016/j.polymdegradstab.2015.01.012.
  • Nor Arman, N.S., Chen, R.S., Ahmad, S., Shahdan, D. 2022. Mechanical and physical characterizations of compatibilizer‐free recycled plastics blend composites modified with carbon nanotube and clay nanofiller, Journal of Applied Polymer Science, Vol. 139, no. 32, DOI: 10.1002/app.52768.
  • Stark, N.M., Matuana, L.M. 2006. Influence of photostabilizers on wood flour–HDPE composites exposed to xenon-arc radiation with and without water spray, Polymer Degradation and Stability, Vol. 91, no. 12, pp. 3048-3056, DOI: 10.1016/j.polymdegradstab.2006.08.003.
  • Abedini, H., Yousefi, S., Khonakdar, H.A. 2017. A simplified moment model for prediction of long-chain branching during peroxide modification of HDPE, Materials & Design, Vol. 130, pp. 16-25, DOI: 10.1016/j.matdes.2017.05.043.
  • Handayani, S.U., Fahrudin, M., Mangestiyono, W., Hadi Muhamad, A.F. 2021. Mechanical Properties of Commercial Recycled Polypropylene from Plastic Waste, Journal of Vocational Studies on Applied Research, Vol. 3, no. 1, pp. 1-4, DOI: 10.14710/jvsar.v3i1.10868.
  • Chiou, A.H., Lin, C.H. 2023. Material and mechanical characterization of recycled polypropylene reinforced with different weight percentages of short glass fiber developed by injection molding, Heliyon, Vol. 9, no. 9, DOI: 10.1016/j.heliyon.2023.e19403.
  • Kartal, İ., Selimoğlu, H. 2023. Investigation of the mechanical behavior of recycled polypropylene-based composite materials filled with waste cotton and pine sawdust, International Journal of Computational and Experimental Science and Engineering, Vol. 9, no. 4, pp. 412-418, DOI: 10.22399/ijcesen.1332982.
  • Mihelčič, M., Oseli, A., Huskić, M., Slemenik Perše, L. 2022. Influence of Stabilization Additive on Rheological, Thermal and Mechanical Properties of Recycled Polypropylene, Polymers, Vol. 14, no. 24, DOI: 10.3390/polym14245438.

Geri Dönüştürmenin HDPE ve PP Malzemelerinin Düşük Gerinme Hızı Altındaki Mekanik Davranışlarına Olan Etkisinin Deneysel Olarak İncelenmesi

Year 2025, Volume: 27 Issue: 81, 473 - 484, 29.09.2025
https://doi.org/10.21205/deufmd.2025278115

Abstract

Termoplastikler hafiflik, korozyona dayanıklılık ve düşük maliyetli olmaları gibi avantajları sayesinde yaygın bir şekilde mühendislik malzemesi olarak kullanılmaktadır. Ancak, termoplastik atıklar çevre kirliliğindeki en önemli sebeplerden bir tanesi olarak göze çarpmaktadır. Bu durum ekonomik olarak bir dezavantaj oluştururken hayat kalitesini de düşürmektedir. Termoplastik malzemelerin geri dönüştürülme kabiliyeti bu dezavantajları elimine etmek için çok önemli bir özelliktir. Geri dönüştürme yöntemi ile bir yandan hammadde tasarrufu sağlanırken bir yandan da çevre kirliliği azaltılmaktadır. Ancak, geri dönüştürme işlemi sırasında termoplastik malzemelerin moleküler yapısında meydana gelen değişiklikler reolojik ve mekanik özelliklerinde bozunmalara yol açabilmektedir. Bu projede ekstrüzyon ile geri dönüştürme işleminin Yüksek Yoğunluklu Polietilen (HDPE) ve Polietilen (PP) malzemelerinin farklı gerinim hızlarındaki çekme mukavemetine ve elastisite modülüne etkisi incelenmiştir. Ham HDPE malzemesi bir ve üç defa ekstrüzyona tabi tutularak, ham PP malzemesi ise bir defa ekstrüzyona tabi tutularak geri dönüştürme işlemi gerçekleştirilmiştir. Elde edilen sonuçlar HDPE malzemesinin üç defa geri dönüştürülse bile mekanik özelliklerini kaybetmediğini ancak PP malzemesinin bir defa geri dönüştürme sonucunda az da olsa elastikiyetini kaybettiği göstermiştir. Ayrıca, yüksek gerinim hızlarında tüm malzeme tiplerinin mekanik özelliklerinde bir artış olduğu görülmüştür. Bu artış oranı ham HDPE ve geri dönüştürülmüş HDPE malzemeleri için hemen hemen aynı seviyede iken geri dönüştürülmüş PP malzemelerinin yüksek gerinim hızlarındaki mekanik özelliklerindeki artış oranı ham PP malzemesine göre daha yüksek seviyede meydana gelmiştir. Sonuçlar, az sayıda geri dönüştürme işlemine maruz kalmış HDPE ve PP malzemelerinin mühendislik malzemesi olarak kullanılabileceğini göstermektedir.

References

  • Ibeh, C.C. 2011. Thermoplastic Materials: Properties, Manufacturing Methods, and Applications. CRC Press.
  • Coulier, L., Orbons, H.G.M., Rijk, R. 2007. Analytical protocol to study the food safety of (multiple-)recycled high-density polyethylene (HDPE) and polypropylene (PP) crates: Influence of recycling on the migration and formation of degradation products, Polymer Degradation and Stability, Vol. 92, no. 11, pp. 2016-2025, DOI: 10.1016/j.polymdegradstab.2007.07.022.
  • Simões, C.L., Costa Pinto, L.M., Bernardo, C.A. 2013. Environmental and economic assessment of a road safety product made with virgin and recycled HDPE: A comparative study, Journal of Environmental Management, Vol. 114, pp. 209-215, DOI: 10.1016/j.jenvman.2012.10.001.
  • Achilias, D.S., Roupakias, C., Megalokonomos, P., Lappas, A.A., Antonakou, E.V. 2007. Chemical recycling of plastic wastes made from polyethylene (LDPE and HDPE) and polypropylene (PP), Journal of Hazardous Materials, Vol. 149, no. 3, pp. 536-542, DOI: 10.1016/j.jhazmat.2007.06.076.
  • Özyurt, H. 2020. Design and properties of composite sustainable building material by using waste HDPE, Mühendislik Bilimleri ve Tasarım Dergisi, Vol. 8, no. 3, pp. 777-782, DOI: 10.21923/jesd.741478.
  • Ragaert, K., Delva, L., Van Geem, K. 2017. Mechanical and chemical recycling of solid plastic waste, Waste Management, Vol. 69, pp. 24-58, DOI: 10.1016/j.wasman.2017.07.044.
  • PlasticsEurope. 2015. Plastics - the Facts 2015. An Analysis of European Plastics Production, Demand and Recovery for 2015.
  • COP26. 2022. COP26 Presidency Outcomes The Climate Pact. https://ukcop26.org/wp-content/uploads/2021/11/COP26-Presidency-Outcomes-The-Climate-Pact.pdf (Accessed: Sep. 20, 2025).
  • Zheng, J., Suh, S. 2019. Strategies to reduce the global carbon footprint of plastics, Nature Climate Change, Vol. 9, no. 5, pp. 374-378, DOI: 10.1038/s41558-019-0459-z.
  • Turner, D.A., Williams, I.D., Kemp, S. 2015. Greenhouse gas emission factors for recycling of source-segregated waste materials, Resources, Conservation and Recycling, Vol. 105, pp. 186-197, DOI: 10.1016/j.resconrec.2015.10.026.
  • Jin, H., Gonzalez-Gutierrez, J., Oblak, P., Zupančič, B., Emri, I. 2012. The effect of extensive mechanical recycling on the properties of low density polyethylene, Polymer Degradation and Stability, Vol. 97, no. 11, pp. 2262-2272, DOI: 10.1016/j.polymdegradstab.2012.07.039.
  • Raquez, J.-M., Bourgeois, A., Jacobs, H., Degée, P., Alexandre, M., Dubois, P. 2011. Oxidative degradations of oxodegradable LDPE enhanced with thermoplastic pea starch: Thermo-mechanical properties, morphology, and UV-ageing studies, Journal of Applied Polymer Science, Vol. 122, no. 1, pp. 489-496, DOI: 10.1002/app.34190.
  • Andersson, T., Holmgren, M.H., Nielsen, T., Wesslén, B. 2005. Degradation of low density polyethylene during extrusion. IV. Off-flavor compounds in extruded films of stabilized LDPE, Journal of Applied Polymer Science, Vol. 95, no. 3, pp. 583-595, DOI: 10.1002/app.21264.
  • Hamad, K., Kaseem, M., Deri, F. 2011. Effect of recycling on rheological and mechanical properties of poly(lactic acid)/polystyrene polymer blend, Journal of Materials Science, Vol. 46, no. 9, pp. 3013-3019, DOI: 10.1007/s10853-010-5179-8.
  • Abad, M.J. et al. 2004. Effects of a mixture of stabilizers on the structure and mechanical properties of polyethylene during reprocessing, Journal of Applied Polymer Science, Vol. 92, no. 6, pp. 3910-3916, DOI: 10.1002/app.20420.
  • Vidakis, N., Petousis, M., Maniadi, A. 2021. Sustainable Additive Manufacturing: Mechanical Response of High-Density Polyethylene over Multiple Recycling Processes, Recycling, Vol. 6, no. 1, p. 4, DOI: 10.3390/recycling6010004.
  • Zhang, J., Hirschberg, V., Rodrigue, D. 2023. Mechanical fatigue of recycled and virgin high-/low-density polyethylene, Journal of Applied Polymer Science, Vol. 140, no. 2, DOI: 10.1002/app.53312.
  • Vidakis, N., Petousis, M., Maniadi, A., Koudoumas, E., Vairis, A., Kechagias, J. 2020. Sustainable Additive Manufacturing: Mechanical Response of Acrylonitrile-Butadiene-Styrene over Multiple Recycling Processes, Sustainability, Vol. 12, no. 9, p. 3568, DOI: 10.3390/su12093568.
  • Strangl, M., Ortner, E., Buettner, A. 2019. Evaluation of the efficiency of odor removal from recycled HDPE using a modified recycling process, Resources, Conservation and Recycling, Vol. 146, pp. 89-97, DOI: 10.1016/j.resconrec.2019.03.009.
  • Yıldız Zeyrek, B., Aydoğan, B., Dilekcan, E., Öztürk, F. 2023. Recycle potential of thermoplastic composites, Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, DOI: 10.28948/ngumuh.1258388.
  • Oblak, P., Gonzalez-Gutierrez, J., Zupančič, B., Aulova, A., Emri, I. 2015. Processability and mechanical properties of extensively recycled high density polyethylene, Polymer Degradation and Stability, Vol. 114, pp. 133-145, DOI: 10.1016/j.polymdegradstab.2015.01.012.
  • Nor Arman, N.S., Chen, R.S., Ahmad, S., Shahdan, D. 2022. Mechanical and physical characterizations of compatibilizer‐free recycled plastics blend composites modified with carbon nanotube and clay nanofiller, Journal of Applied Polymer Science, Vol. 139, no. 32, DOI: 10.1002/app.52768.
  • Stark, N.M., Matuana, L.M. 2006. Influence of photostabilizers on wood flour–HDPE composites exposed to xenon-arc radiation with and without water spray, Polymer Degradation and Stability, Vol. 91, no. 12, pp. 3048-3056, DOI: 10.1016/j.polymdegradstab.2006.08.003.
  • Abedini, H., Yousefi, S., Khonakdar, H.A. 2017. A simplified moment model for prediction of long-chain branching during peroxide modification of HDPE, Materials & Design, Vol. 130, pp. 16-25, DOI: 10.1016/j.matdes.2017.05.043.
  • Handayani, S.U., Fahrudin, M., Mangestiyono, W., Hadi Muhamad, A.F. 2021. Mechanical Properties of Commercial Recycled Polypropylene from Plastic Waste, Journal of Vocational Studies on Applied Research, Vol. 3, no. 1, pp. 1-4, DOI: 10.14710/jvsar.v3i1.10868.
  • Chiou, A.H., Lin, C.H. 2023. Material and mechanical characterization of recycled polypropylene reinforced with different weight percentages of short glass fiber developed by injection molding, Heliyon, Vol. 9, no. 9, DOI: 10.1016/j.heliyon.2023.e19403.
  • Kartal, İ., Selimoğlu, H. 2023. Investigation of the mechanical behavior of recycled polypropylene-based composite materials filled with waste cotton and pine sawdust, International Journal of Computational and Experimental Science and Engineering, Vol. 9, no. 4, pp. 412-418, DOI: 10.22399/ijcesen.1332982.
  • Mihelčič, M., Oseli, A., Huskić, M., Slemenik Perše, L. 2022. Influence of Stabilization Additive on Rheological, Thermal and Mechanical Properties of Recycled Polypropylene, Polymers, Vol. 14, no. 24, DOI: 10.3390/polym14245438.
There are 28 citations in total.

Details

Primary Language English
Subjects Material Design and Behaviors
Journal Section Research Article
Authors

Mehmet Sait Karanfil 0009-0000-7312-8177

Arif Ergin 0009-0004-0000-4615

Mehmet Güçlü 0000-0001-6611-1203

Beyza Sarıcaoğlu 0000-0001-6305-1399

Fatih Turan 0000-0002-7197-3892

Hande Çelebi 0000-0003-0652-2048

Early Pub Date September 25, 2025
Publication Date September 29, 2025
Submission Date December 3, 2024
Acceptance Date February 6, 2025
Published in Issue Year 2025 Volume: 27 Issue: 81

Cite

APA Karanfil, M. S., Ergin, A., Güçlü, M., … Sarıcaoğlu, B. (2025). The Experimental Investigation of The Recycling Effect on The Low Strain Rate Behavior of HDPE and PP Materials Under Tensile Loading. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi, 27(81), 473-484. https://doi.org/10.21205/deufmd.2025278115
AMA Karanfil MS, Ergin A, Güçlü M, Sarıcaoğlu B, Turan F, Çelebi H. The Experimental Investigation of The Recycling Effect on The Low Strain Rate Behavior of HDPE and PP Materials Under Tensile Loading. DEUFMD. September 2025;27(81):473-484. doi:10.21205/deufmd.2025278115
Chicago Karanfil, Mehmet Sait, Arif Ergin, Mehmet Güçlü, Beyza Sarıcaoğlu, Fatih Turan, and Hande Çelebi. “The Experimental Investigation of The Recycling Effect on The Low Strain Rate Behavior of HDPE and PP Materials Under Tensile Loading”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi 27, no. 81 (September 2025): 473-84. https://doi.org/10.21205/deufmd.2025278115.
EndNote Karanfil MS, Ergin A, Güçlü M, Sarıcaoğlu B, Turan F, Çelebi H (September 1, 2025) The Experimental Investigation of The Recycling Effect on The Low Strain Rate Behavior of HDPE and PP Materials Under Tensile Loading. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen ve Mühendislik Dergisi 27 81 473–484.
IEEE M. S. Karanfil, A. Ergin, M. Güçlü, B. Sarıcaoğlu, F. Turan, and H. Çelebi, “The Experimental Investigation of The Recycling Effect on The Low Strain Rate Behavior of HDPE and PP Materials Under Tensile Loading”, DEUFMD, vol. 27, no. 81, pp. 473–484, 2025, doi: 10.21205/deufmd.2025278115.
ISNAD Karanfil, Mehmet Sait et al. “The Experimental Investigation of The Recycling Effect on The Low Strain Rate Behavior of HDPE and PP Materials Under Tensile Loading”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen ve Mühendislik Dergisi 27/81 (September2025), 473-484. https://doi.org/10.21205/deufmd.2025278115.
JAMA Karanfil MS, Ergin A, Güçlü M, Sarıcaoğlu B, Turan F, Çelebi H. The Experimental Investigation of The Recycling Effect on The Low Strain Rate Behavior of HDPE and PP Materials Under Tensile Loading. DEUFMD. 2025;27:473–484.
MLA Karanfil, Mehmet Sait et al. “The Experimental Investigation of The Recycling Effect on The Low Strain Rate Behavior of HDPE and PP Materials Under Tensile Loading”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi, vol. 27, no. 81, 2025, pp. 473-84, doi:10.21205/deufmd.2025278115.
Vancouver Karanfil MS, Ergin A, Güçlü M, Sarıcaoğlu B, Turan F, Çelebi H. The Experimental Investigation of The Recycling Effect on The Low Strain Rate Behavior of HDPE and PP Materials Under Tensile Loading. DEUFMD. 2025;27(81):473-84.