Decoloration and Detoxification of Astrazon Red FBL Solution Using Gamma Rays

Year 2023, , 358 - 368, 31.01.2023

Ömer Kantoğlu

https://doi.org/10.29130/dubited.1069909

Abstract

In this study, decoloration and detoxification of Astrazon Red FBL dye solutions using gamma rays have been examined at different environments (air, O2 saturated, 2.6 mM H2O2). In this context, the decoloration, mineralization, detoxification, pH, COD and BOD5 parameters were followed. Biodegradability ( 5 days of biological oxygen demand/ chemical oxygen demand -BOD5/COD-) ratio has been improved up on 2 kGy irradiation for all solutions. Optimum irradiation conditions were found to be 5 kGy pH 9 for air, 5 kGy pH 11 for O2 saturated, 7 kGy pH 11 for 2.6 mM H2O2 to provide mineralization and decoloration of Astrazon Red FBL solutions. Microtox bioluminescent test was conducted to measure the toxicity of Astrazon FBL solutions treated with high energetic rays. Toxicity reduction has been achieved at 5, 5 and 7 kGy in the range of 81.2, 86.7 and 56.3 % for air, O2 saturated and H2O2 solutions, respectively. As a result of study, it is found that Astrazon Red FBL dye could be treated by irradiation technology.

Keywords

radiation, decoloration, toxicity, mineralization, COD, BOD5

Supporting Institution

Turkish Energy, Nuclear and Mining Agency, International Atomic Energy Authority

Project Number

A2.H5.F8, CRP-16406

Thanks

The author wishs to express his gratitude to both Turkish Energy, Nuclear and Mining Agency (A2.H5.F8) and International Atomic Energy Agency (IAEA-TUR/8/017), which financially supported this work.

Astrazon Red FBL Çözeltisinin Gama Işınlarıyla Renk Giderimi ve Detoksifikasyonu

Abstract

Bu çalışmada, Astrazon Red FBL boyasının sulu çözeltilerinin yüksek enerji ile etkileşimi sonrası renk giderimi ve detoksifikasyonu farklı deneysel koşullar altında (hava, doygun O2, 2.6 mM H2O2) araştırılmıştır. Bu kapsamda renk giderme, mineralizasyon, detoksifikasyon, pH, KOİ ve BOİ5 parametreleri takip edilmiştir. Biyobozunurluk (5 günlük biyolojik oksijen ihtiyacı/kimyasal oksijen ihtiyacı -BOD5/COD-) oranı, tüm çözeltiler için 2 kGy ışınlamada artmıştır. Astrazon Red FBL çözeltilerinin mineralizasyonunu ve renk giderimini sağlamak üzere hava için 5 kGy ve pH 9, doygun O2 için 5 kGy ve pH 11, 2.6 mM H2O2 için 7 kGy ve pH 11, optimum ışınlama koşulları olarak bulunmuştur. Yüksek enerjili ışınlarla muamele edilen Astrazon FBL çözeltilerinin toksisitesini ölçmek için microtox bioassay testi gerçekleştirilmiştir. Hava, doygun O2 ve H2O2 çözeltileri için sırasıyla %81.2, %86.7 ve %56.3 oranlarında 5, 5 ve 7 kGy'de toksisite azalması sağlanmıştır. Çalışmanın sonucu olarak, Astrazon Red FBL tekstil boyasının ışınlama teknolojisi ile arıtımının gerçekleştirilebileceği tespit edilmiştir.

Keywords

Astrazon, radyasyon, renk giderimi, toksisite, mineralizasyon, KOİ, BOİ5, radiation, decoloration, toxicity, mineralization, COD, BOD5

Project Number

A2.H5.F8, CRP-16406

References

• [1]A. Aleboyed, H. Aleboyeh, and Y. Moussa, “Decolorisation of acid blue 74 by ultraviolet/ H2O2,” Environmental Chemistry Letters, vol. 1, no. 3, pp. 161–164, 2003.
• [2]S.F. Kang and H.M. Chang, “Coagulation of textile secondary effluents with Fenton’s Reagent,” Water Science and Technology, vol. 36, no. 12, pp. 215–222, 1997.
• [3]H.Y. Shu and M.C.J. Chang, “Pre-ozonization coupled with UV/H2O2 process for the decolorization and mineralization of cotton dyeing effluent and synthesized C.I. Direct Black 22 wastewater,” Journal of Hazardous Materials, vol. B121, no. 1-3, pp. 127–133, 2005.
• [4]F. Zidane, P. Drogui, B. Lekhlif, J. Bensaid, J. Blais, S. Belcadi and K.J. Kacemi,“Decolourization of dye-containing effluent using mineral coagulants produced by electro-coagulation,” Journal of Hazardous Materials, vol. 155, pp. 153–163, 2008.
• [5]J.H. Mo, Y.H. Lee, J. Kim, J.Y. Jeong and J. Jegal, “Treatment of dye aqueous solutions using nanofiltration polyamide composite membranes for the dye wastewater reuse,” Dyes and Pigments, vol. 76, pp. 429–434, 2008.
• [6]S. Souza, E. Forgiarini and A. Souza, “Toxicity of textile dyes and their degradation by the enzyme horse radish peroxidase (HRP),” Journal of Hazardous Materials, vol. 147, pp. 1073–1078, 2007.
• [7]C. Wu, “Decolorization of C.I. reactive red 2 in O3, Fenton-like and O3/Fenton like hybrid Systems,” Dyes and Pigments, vol. 77, pp. 24–30, 2008.
• [8]M. Panizza and G. Cerisola, “Removal of colour and COD from wastewater containing acid blue 22 by electrochemical oxidation,” Journal of Hazardous Materials, vol. 153, no. 1-2, pp. 83–88, 2008.
• [9]G.J. Brunner, “Near and supercritical water. Part II: oxidative processes, review,” Supercritical Fluids, vol. 47, pp. 382–390, 2009.
• [10]J.L. Morias and P.P. Zamora, “Use of advanced oxidation process to improve the biodegradability of mature landfill leachate,” Journal of Hazardous Materials, vol. B123, pp. 181–186, 2005.
• [11]T.H. Kim, C. Park, J. Lee, E.B. Shin and S. Kim, “Pilot scale treatment of textile wastewater by combined process (fluidized biofilm process-chemical coagulation-electrochemical oxidation),” Water Research, vol. 36, pp. 3979–3988, 2002.
• [12]M. Noorjahan, M. Pratap Reddy, V. Durga Kumari, B. Lave´ drine, P. Boule and M. Subrahmanyam, “Photocatalytic degradation of H-acid over a novel TiO2 thin film fixed bed reactor and in aqueous suspensions,” Journal of Photochemistry and Photobiology A: Chemistry, vol. 156, pp. 179–187, 2003.
• [13]I. Arslan and I.A. Balcioglu, “Degradation of commercial reactive dye stuffs by heterogenous and homogenous advanced oxidation processes: a comparative study,” Dyes and Pigments, vol. 43, pp. 95–108, 1999.
• [14]M. Koch, A. Yediler, D. Lienert, G. Insel and A. Kettrup, “Ozonation of hydrolyzed azo dye reactive yellow 84(CI),” Chemosphere, vol. 44, pp. 109–113, 2002.
• [15]G.M. Shaul, C.R. Dempsey and K.A. Dostal, “Fate of water soluble azo dyes in the Activated Sludge Process,” United State Environmental Protection Agency, Water Engineering Research Laboratory, USA, Project summary no. EPA/600/S2-88/30, 1988.
• [16]B. Han, J. Kim, Y. Kim, J.S. Choi, I.E. Makarov and A.V. Ponomarev, “Electron beam treatment of textile dyeing wastewater: Operation of pilot plant and industrial plant construction,” Water Science and Technology, vol. 52, no. 10-11, pp. 317-324, 2005.
• [17]N. Getoff, “Radiation chemistry and the environment,” Radiation Physics and Chemistry, vol. 54, pp. 377–384, 1999.
• [18]N.M. Mahmoodi, N.Y. Limaee, M. Arami, S. Borhany and M.J. Mohammad-Taheri, “Nanophotocatalysis using nanoparticles of titania. mineralization and finite element modelling of solophenyldyede colorization,” Journal of Photochemistry and Photobiology A: Chemistry, vol. 189, pp. 1–6, 2007.
• [19]A. Doubla, L.B. Bello, M. Fotso and J.L. Brisset, “Plasmochemical decolourisation of bromothymol blue by gliding electric discharge at atmospheric pressure,” Dyes and Pigments, vol. 77, pp. 118–124, 2008.
• [20]M. Wang, R. Yang, W. Wang, Z. Shen, S. Bian and Z. Zhu, “Radiation-induced decomposition and decoloration of reactive dyes in the presence of H2O2,” Radiation Physics and Chemistry, vol. 75, pp. 286–291, 2006.
• [21]T. Ting and N. Jamaludin, “Decolorization and decomposition of organic pollutants for reactive and disperse dyes using electron beam technology: effect of the concentrations of pollutants and irradiation dose,” Chemosphere, vol. 73, pp. 76–80, 2008.
• [22] Ö. Kantoğlu, “Decoloration and mineralization of aqueous solution of cationic (basic) dye Astrazon Black FDL by using gamma rays,” Radiochimica Acta, vol. 105, no. 3, pp. 241-248, 2017.
• [23]D. De Zwart and A.J. Folkerts, “Monitoring the toxicity of organic compounds dissolved in Rhine water,” Hydrobiology Bulleetine, vol. 24, no. 1, pp. 5-12, 1990.
• [24]M.E. Lebsack, A.D. Anderson, C.M. Degraeve, and H.L. Bergman, “Comparison of Bacterial luminescence and fish bioassay result for fossil –fuel process waters and phenolic constituents,” Aquatic Toxicology and Hazard Assessment: Fourth Conference, 1981, pp 348-356.
• [25]Basic Test, Azur Environmental Ltd, Microtox User Manual, pp. 23-33, 1998.
• [26]L. Wojnarovits, T. Palfi, E. Takacs, and S.S. “Emmi, Reactivity differences of hydroxyl radicals and hydrated electrons in destructing azo dyes,” Radiation Physics and Chemistry, vol. 74, pp. 239–246, 2005.
• [27]S. Hammami, N. Bellakhal, N. Oturan, M.A. Oturan, and M. Dachraoui, “Degradation of acid orange 7 by electrochemically generated OH radicals in acidic aqueous medium using a boron-doped diamond or platinum anode: a mechanistic study,” Chemosphere, vol. 73, pp. 678–684, 2008.
• [28]J. Yang, J. Dai, C. Chen, and J. Zhao, “Effects of hydroxyl radicals and oxygen species on the 4-chlorophenol degradation by photoelectrocatalytic reactions with TiO2-film electrodes,” Journal of Photochemistry and Photobiology A: Chemistry, vol. 208, pp. 66–77, 2009.
• [29]J. Paul, K.P. Rawat, KS.S. Sarma, and S. Sabharwal, “Decoloration and degradation of Reactive Red-120 dye by electron beam irradiation in aqueous solution,” Applied Radiation and Isotopes, vol. 69, pp. 982-987, 2011.
• [30]J. Garcia-Montano, F. Torrades, J.A. Garcia-Hortal, X. Domenech, and J. Peral, “Combining photo-Fenton process with aerobic sequencing batch reactor for commercial hetero-bireactive dye removal,” Applied Catalysis B: Environmental, vol. 67, pp. 86–92, 2006.
• [31]Ö. Kantoğlu, “Effects of high energitic radiation on the removal and detoxification of cationic dye Astrazon Blue FGRL,” Turkish Journal of Nuclear Sciences, vol. 33, no. 1, pp. 1-14, 2021.