Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez ve Yapılarının Aydınlatılması

Ertuğrul Gazi Sağlam; Elif Bulat; Mustafa Saçmacı; Servet Yıldız

doi:10.29130/dubited.1104231

EN TR

Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez ve Yapılarının Aydınlatılması

Abstract

Bu çalışmada, 2,4-bis-(3-metoksitolil)-1,3-ditiya-2,4-difosfetan 2,4-disülfür ([((CH3)C6H3(OCH3)-P(S)S)2]) bileşiği yeniden sentezlendi. Bu bileşiğin alkollerle reaksiyonundan literatürde bilinen iki ditiyofosfonik asiti ([HS2P(R’)(ORn)], HLn; R’=(CH3)C6H3(OCH3); R1= Etil-, L1, R2= 2-propil-, L2) sentezlendi. Ham ditiyofosfonik asitler kuru amonyak gazıyla ligandlarına ([NH4][S2P(R’)(ORn)]) dönüştürüldü. Etil alkol ortamında bu ligandların kadmiyum tuzlarıyla reaksiyonlarından çift çekirdekli yeni ditiyofosfonato Cd(II) kompleksleri sentezlendi ([Cd(μ-Ln)2(Ln)2]). Komplekslerin yapıları; elementel analizi, kütle spektrometresi (ESI), FT-IR, Raman, NMR (1H, 13C, 31P) spektroskopisiyle aydınlatıldı.

Keywords

Fosfor 1,1-Ditiyolatlar, Ditiyadifosfetanlar, Ditiyofosfonik Asit, Cd(II) Ditiyofosfonato Kompleksleri

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Details

Primary Language

Turkish

Subjects

Engineering

Journal Section

Research Article

Authors

Ertuğrul Gazi Sağlam ^*
0000-0002-7719-3934
Türkiye

Elif Bulat
0000-0002-2164-3641
Türkiye

Mustafa Saçmacı
0000-0001-8265-8233
Türkiye

Servet Yıldız
0000-0002-6033-3419
Türkiye

Publication Date

April 30, 2023

Submission Date

April 15, 2022

Acceptance Date

June 28, 2022

Published in Issue

Year 2023 Volume: 11 Number: 2

DOI

https://doi.org/10.29130/dubited.1104231

IZ

https://izlik.org/JA48LY24AK

APA

Sağlam, E. G., Bulat, E., Saçmacı, M., & Yıldız, S. (2023). Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez ve Yapılarının Aydınlatılması. Duzce University Journal of Science and Technology, 11(2), 759-774. https://doi.org/10.29130/dubited.1104231

AMA

1.Sağlam EG, Bulat E, Saçmacı M, Yıldız S. Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez ve Yapılarının Aydınlatılması. DUBİTED. 2023;11(2):759-774. doi:10.29130/dubited.1104231

Chicago

Sağlam, Ertuğrul Gazi, Elif Bulat, Mustafa Saçmacı, and Servet Yıldız. 2023. “Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez Ve Yapılarının Aydınlatılması”. Duzce University Journal of Science and Technology 11 (2): 759-74. https://doi.org/10.29130/dubited.1104231.

EndNote

Sağlam EG, Bulat E, Saçmacı M, Yıldız S (April 1, 2023) Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez ve Yapılarının Aydınlatılması. Duzce University Journal of Science and Technology 11 2 759–774.

IEEE

[1]E. G. Sağlam, E. Bulat, M. Saçmacı, and S. Yıldız, “Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez ve Yapılarının Aydınlatılması”, DUBİTED, vol. 11, no. 2, pp. 759–774, Apr. 2023, doi: 10.29130/dubited.1104231.

ISNAD

Sağlam, Ertuğrul Gazi - Bulat, Elif - Saçmacı, Mustafa - Yıldız, Servet. “Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez Ve Yapılarının Aydınlatılması”. Duzce University Journal of Science and Technology 11/2 (April 1, 2023): 759-774. https://doi.org/10.29130/dubited.1104231.

JAMA

1.Sağlam EG, Bulat E, Saçmacı M, Yıldız S. Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez ve Yapılarının Aydınlatılması. DUBİTED. 2023;11:759–774.

MLA

Sağlam, Ertuğrul Gazi, et al. “Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez Ve Yapılarının Aydınlatılması”. Duzce University Journal of Science and Technology, vol. 11, no. 2, Apr. 2023, pp. 759-74, doi:10.29130/dubited.1104231.

Vancouver

1.Ertuğrul Gazi Sağlam, Elif Bulat, Mustafa Saçmacı, Servet Yıldız. Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez ve Yapılarının Aydınlatılması. DUBİTED. 2023 Apr. 1;11(2):759-74. doi:10.29130/dubited.1104231

Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez ve Yapılarının Aydınlatılması

Synthesis and Structural Characterization of Homo Dinuclear Phosphorus 1,1-Dithiolate Cd(II) Complexes

Abstract

Keywords

Çift Metal Merkezli Fosfor 1,1-Ditiyolat Cd(II) Komplekslerinin Sentez ve Yapılarının Aydınlatılması

Abstract

Keywords

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