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Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi

Year 2023, , 1349 - 1364, 31.07.2023

Özlem Altunordu Kalaycı , Hülya Arslan

https://doi.org/10.29130/dubited.1124484

Abstract

Bu çalışmada, AB tipi diblok (mPEG-b-PCL) ve BAB tipi triblok (PCL-b-PEG-b-PCL) kopolimerler sırasıyla makrobaşlatıcı olarak mPEG (monometoksi poli(etilen glikol)) ve PEG (poli etilen glikol) kullanılarak ve katalizör olarak kalay oktanoat (Sn(Oct)2) kullanılarak ε-kaprolakton (ε-CL)’nun halka açılması polimerizasyonu ile sentezlendi. Blok kopolimer içerisinde, gümüş nitrat (AgNO3) metal tuzlarının indirgenmesiyle gümüş nanoparçacıkları içeren Ag/PEG-b-PCL ve Ag/PCL-b-PEG-b-PCL kolloidal çözeltileri üretilmiştir. mPEG-b-PCL ve PCL-b-PEG-b-PCL blok kopolimerlerinin karakterizasyonu, GPC, FTIR ve 1HNMR teknikleri kullanılarak yapılmıştır. Hibrit yapı içerisindeki gümüş nanoparçacık formasyonu, yüzey plazmon rezonans (SPR) dalga boyu değişiminden ve floresans emisyon spektrumundan gözlenmiştir. İlaç taşıyıcı sistemlerde model ilaç olarak kullanılan metilen mavisinin, polimerde gümüş nanoparçacıkların varlığında, löko-metilene indirgenme hızı araştırılmıştır.

Keywords

Gümüş nanoparçacıklar blok kopolimer Yüzey plazmon rezonans Metilen Mavisi

Supporting Institution

Zonguldak Bülent Ecevit Üniversitesi

Project Number

2016-72118496-07

References

  • S.S. Eliçora, , D. Erdem, A.E. Dinc, O.A. Kalaycı, B. Hazer, G. Yurdakan, C. Külah, “Effects of polymer-based, silver nanoparticle-coated silicone splints on the nasal mucosa of rats” Eur Arch Otorhinolaryngol. 274 (2017) 1535–1541.
  • H. Koc, E. Kilicay, Z. Karahaliloglu, B. Hazer, E.B. Denkbas, E.B. “Prevention of catheter related infections via the urinary catheter modified with polystyrene-ricinoleic acid copolymers containing Ag nano particles”, J. Biomaterials Applications. 36(3) (2021) 385-405.
  • A. Akbarzadeh, S. Saghfi Synthesis, Preparation and Characterization of Nanoparticles for Biomedical Applications (2018) DOI: 10.13140/RG.2.2.27539.532
  • P. Makvandi, U. Josic, M. Delfi, F. Pinelli, V. Jahed, E. Kaya, M. Ashrafizadeh, A. Zarepour, F. Rossi, A. Zarrabi, T. Agarwal, E. N. Zare, M. Ghomi, T. K. Maiti, L. Breschi, F. R Tay, “Drug Delivery (Nano)Platforms for Oral and Dental Applications: Tissue Regeneration, Infection Control, and Cancer Management” Adv. Sci. 8 ( 2021) 2004014.
  • R. Begum, J. Najeeb, A. Sattar, K. Naseem, A. Irfan, A. G. Al-Sehemi, Z. H. Farooqi, “Chemical reduction of methylene blue in the presence of nanocatalysts: a critical review” Rev Chem Eng (2019) doi.org/10.1515/revce-2018-0047
  • X. Wei, C. Gong, M. Gou, S.Fu, Q. Guo, S. Shi, F. Luo, G. Guo, L. Qiu, Z. Qian. International Journal of Pharmaceutics 381 (2009) 1-18
  • B. Bogdanov, A. Vidts, A. Van Den Bulcke, R. Verbeeck, E. Schacht, “Synthesis and thermal properties of poly(ethylene glycol)-poly(ε-caprolactone) copolymers" Polymer 39 (1998) 1631-1636.
  • K. Jette, D. Law, E. Schmitt, G. Kwon, “Preparation and Drug Loading of Poly(Ethylene Glycol)-blok-Poly(ε-Caprolactone) Micelles Through the Evaporation of a Cosolvent Azeotrope” Pharmaceutical Research, 21, (2004), 7.
  • C. Shen, S. Guo, C. Lu, “Degradation behaviors of monomethoxy poly(ethylene glycol)-b-poly(Ɛ-caprolactone) nanoparticles in aqueous solution” Polym. Adv. Technol. 19 (2008) 66-72.
  • M. Gou, X. Zheng, K. Men, J. Zhang, L. Zheng, X. Wang, F. Luo, F, Y. Zhao, X. Zhao, Y. Wei, Z. Qian. “Poly(ε-caprolactone)/Poly(ethylene glycol)/Poly(ε-caprolactone)Nanoparticles : Preparation, Characterization, and Application in Doxorubicin Delivery” J. Phys. Chem. B 113 (2009) 12928-12933.
  • R. Diab, M. Hamoudeh, O. Boyron, A. Elaissari, H. Fessi, “Microencapsulation of cytarabine using poly(ethylene glycol)-poly (ε-caprolactone) diblock copolymers as surfactant agents” Drug Development and Industrial Pharmacy, 36 (4) (2010) 456-469.
  • J. Sun, C. He, X. Zhuang, X. Jing, X. Chen. “The crystallization behavior of poly(ethylene glycol)- poly(ε-caprolactone) diblock copolymers with asymmetric block compositions” J Polym Res. 18 (2011) 2161-2168.
  • S. Bhatt, J. Pulpytel, M. Mirshahi, F. Arefi-Khonsari. “Catalyst-Free Plasma-Assisted Copolymerization of Poly(ε-caprolactone)-poly(ethylene glycol) for Biomedical Applications” ACS Macro Lett. 1 (2012) 764-767.
  • B. Zhang, H. Zhang, Y. Li, J. N. Hoskins, S. M. Grayson “Exploring the Effect of Amphiphilic Polymer Architecture:Synthesis, Characterization, and Self-Assembly of Both Cyclic and Linear Poly(ethylene gylcol)-b-polycaprolactone” ACS Macro Lett. 2 (2013) 845-848.
  • G. Yin, G. Chen, Z. Zhou, Q. Lİ. “Modification of PEG-b-PCL block copolymer with high melting temperature by the enhancement of POSS crystal and ordered phase structure” RSC Adv. 5 (2015) 33356.
  • A. Mohanty, U. Jana, P. Manna, G. Mohanta “Synthesis and evaluation of MePEG-PCL diblock copolymers: surface properties and controlled release behavior” Prog Biomater 4 (2015) 89-100.
  • M. Hwang, J. Suh, Y. Bae, S. Kim, B. Jeong, “Caprolactonic Poloxamer Analog: PEG-PCL-PEG” Biomacromolecules 6 (2005) 885-890.
  • C. Gong, S. Shi, P. Dong, B. Kan, M. Gou, X. Wang, X. Li, F. Luo, X. Zhao, Y. Wei, Z. Qian. “Synthesis and characterization of PEG-PCL-PEG thermosensitive hydrogel” Internation Journal of Pharmaceutics 365 (2009) 89-99.
  • N. Cuong, J. Jiang, Y. Li, J. Chen, S. Jwo, M. Hsieh. “Doxorubicin-Loaded PEG-PCL-PEG Micelle Using Xenograft Model of Nude Mice: Effect of Multiple Administration of Micelle on the Suppression of Human Breast Cancer” Cancers 3 (2011) 61-78.
  • Z. Luo, L. Jin, L. Xu, Z. Zhang, J. Yu, S. Shi, X. Li, H. Chen, H. “Thermosensitive PEG-PCL-PEG (PECE) hydrogel as an in situ gelling system for ocular drug delivery of diclofenac sodium” Drug Deliv. 23 (1) (2016) 63-68.
  • T. Shiomi, K. Imai, K. Takenaka, H. Takeshita, H. Hayashi, Y. Tezuka “Appearance of double spherulites like concentric circles for poly(ε-caprolactone)-block-poly(ethylene glycol)-block-poly(ε-caprolactone)” Polymer 42 (2001) 3233-3239.
  • Y. Hu, L. Zhang, Y. Cao, H. Ge, X. Jiang, C. Yang, “Degradation Behavior of Poly(Ɛ-caprolactone)-b-poly(ethylene glycol)-b-poly(ε-caprolactone) Micelles in Aqueous Solution” Biomacromolecules. 5 (2004) 1756-1762.
  • S. Bae, M. Joo, Y. Jeong, S. Kim, W. Lee, Y. Sohn, B. Jeong. “Gelation Behavior of Poly(ethylene glycol) and Polycaprolactone Triblock and Multiblock Copolymer Aqueous Solutions” Macromolecules. 39 (2006) 4873-4879.
  • M. Huang, M. Gou, Z. Qian, M. Dai, X. Li, M. Cao, K. Wang, J. Zhao, J. Yang, Y. Lu, M. Tu, Y. Wei, “One-step preparation of poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone) nanoparticles for plasmid DNA delivery” 86 (4) (2008) 979-86.
  • Y. Zhang, S. Guo, C. Lu, L. Lıu, Z. Lı, J. Gu J. “Poly(ε-caprolactone)-b-Poly(ethylene glycol)-b-Poly(ε-caprolactone) Triblock Copolymers: Synthesis and Self-Assembly in Aqueonus Solutions” Journal of Polymer Science:Part A:Polymer Chemistry, 45 (2007) 605-613.
  • G. Ma, B. Miao, C. Song. “Thermosensitive PCL-PEG-PCL Hydrogels: Synthesis, Characterization, and Delivery of Proteins” Journal of Applied Polymer Science. 116 (2010) 1985-1993.
  • Y. Wang, C. Wang, S. Fu, Q. Liu, D. Dou, H. Lv, M. Fan, G. Guo, F. Luo, Z. Qian, “ Preparation of Tacrolimus loaded micelles based on poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone)” International Journal of Pharmaceutics 407 (2011) 184-189.
  • R. Feng, Z. Song, G. Zhai. “Preparation and in vivo pharmacokinetics of curcumin-loaded PCL-PEG-PCL triblock copolymeric nanoparticles” International Journal of Nanomedicine, 7 (2012) 4089-4098.
  • Y. Huang, L. Li, G. Li. “An enzyme-catalysed Access to amphiphilic triblock copolymer of PCL-b-PEG-b-PCL:synthesis, characterization and self-assembly properties” Designed Monomers and Polymers 18 (2015) 799-806.
  • L’H. Azouz, F. Dahmoune, F. Rezgui, C. G’Sell. “Full factorial design optimization of anti-inflammatory drug release by PCL-PEG-PCL microspheres” Materials Science and Engineering C 58 (2016) 412-419.
  • N. Mohamed, H. Salama, M. Sabaa, G. Saad. “Synthesis and characterization of biodegradable copoly(ether-ester-urethane)s and their chitin whisker nanocomposites” J Therm Anal Calorim, 125 (2016) 163–173.
  • C. Lagunas, X. Fernández-Francos, F. Ferrando, M. Flores, A. Serra, J. Morancho, J. Salla, X. Ramis. “New epoxy thermosets modified with amphiphilic multiarm star polymers as toughness enhancer” Reactive & Functional Polymers 83 (2014) 132-143.
  • Y. Zhang, Q. Zhao, H. Shao, S. Zhang, X. Han. “ Synthesis and Characterization of Star-Shaped Block Copolymer s PCL-b-PEG-GA” Hindawi Publishing Corporation Advances in Materials Science and Engineering. (2014) 107375.
  • F. Bahadori, A. Dag, H. Durmaz, N. Cakir, H. Onyuksel, U. Tunca, G. Topcu, G. Hizal. “Synthesis and Characterization of Biodegradable Amphiphilic Star and Y-Shaped Block Copolymers as Potential Carriers for Vinorelbine” Polymers 6 (2014) 214-242.
  • M. Zhang, H. Liu, W. Shao, K. Miao, Y. Zhao. “Synthesis and properties of Multicleavable Amphiphilic Dendritic Comblike and Toothbrushlike Copolymers Comprising Alternating PEG and PCL grafts” Macromolecules 46 (2013) 1325-1336.
  • Y. Liu, J. Nguyen, T. Steele, O. Merkel, T. Kissel. “A new synthesis method and degradation of hyper-branched polyethylenimine grafted polycaprolactone block mono-methoxyl poly(ethylene glycol) copolymers (hy-PEI-g-PCL-b-m PEG) as potential DNA delivery vectors” Polymer 50 (2009) 3895-3904.
  • B.H. Vilsinski, P.R. Souza, A. C. Oliveira, C. M.C. Filho, A. J. M. Valente, E. C. Muniz, O. Borges, A. P. Gerola, Wilker Caetano, A. F. Martins. “Photophysics and drug delivery behavior of methylene blue into Arabic-gum based hydrogel matrices” Materials Today Communications 26 (2021) 101889.
  • C. Saldias, A. Leiva, S. Bonardd, C. Quezada, S. Saldias, M. Pino, D. Radic “A facile one-step synthesis of noble metal nanoparticles in DMSO using poly(ethylene glycol)-poly(ε-caprolactone) block copolymers” Reactive and Functional Polymers 96 (2015) 78–88.
  • K.T. Shalumon, C. Sheu, C.H. Chen, S.H. Heng Chen, G. Jose, C.Y. Kuo, J.P. Chen. “Multi-functional electrospun antibacterial core-shell nanofibrous membranes for prolonged prevention of post-surgical tendon adhesion and inflammation” Acta Biomaterialia 72 (2018) 121–136
  • R.V. M. Madhavan, M.J. Rosemary, M. A. Nandkumar, K. V. Krishnan, L. K. Krishnan. “Silver Nanoparticle Impregnated Poly (e-Caprolactone) Scaffolds: Optimization of Antimicrobial and Noncytotoxic Concentrations” Tissue Engineering: Part A 00 ( 2010) 00.
  • O.A. Kalaycı, F.B. Cömert, B. Hazer, B., Atalay, T., Cavicchi, K.A., Cakmak, M, “Synthesis, characterization, and antibacterial activity of metal nanoparticles embedded into amphiphilic comb-type graft copolymers” 65 (2010) Polym. Bulletin. 215–226.
  • M. Vanaja, K. Paulkumar, M. Baburaja, S. Rajeshkumar, G. Gnanajobitha, C. Malarkodi, M. Sivakavinesan, G. Annadurai, “Degradation of Methylene Blue Using Biologically Synthesized Silver Nanoparticles” Bioinorganic Chemistry and Applications (2014), Article ID 742346.
  • J. Krstić, J. Spasojević, A. Radosavljević, M. Šiljegovć, Z. K. Popović, “Optical and structural properties of radiolytically in situ synthesized silver nanoparticles stabilized by chitosan/poly (vinyl alcohol)” blends Radiation Physics and Chemistry 96 (2014) 158–166.
  • H.S. Samanta, C. Battacharjee “5th International Conference on Chemical, Agricultural, Biological and Environmental Sciences (CAFES-17)” Kyoto (Japan) April 18-19, (2017) ISBN 978-81 933894-1-6

Year 2023, , 1349 - 1364, 31.07.2023

Özlem Altunordu Kalaycı , Hülya Arslan

https://doi.org/10.29130/dubited.1124484

Abstract

Project Number

2016-72118496-07

References

  • S.S. Eliçora, , D. Erdem, A.E. Dinc, O.A. Kalaycı, B. Hazer, G. Yurdakan, C. Külah, “Effects of polymer-based, silver nanoparticle-coated silicone splints on the nasal mucosa of rats” Eur Arch Otorhinolaryngol. 274 (2017) 1535–1541.
  • H. Koc, E. Kilicay, Z. Karahaliloglu, B. Hazer, E.B. Denkbas, E.B. “Prevention of catheter related infections via the urinary catheter modified with polystyrene-ricinoleic acid copolymers containing Ag nano particles”, J. Biomaterials Applications. 36(3) (2021) 385-405.
  • A. Akbarzadeh, S. Saghfi Synthesis, Preparation and Characterization of Nanoparticles for Biomedical Applications (2018) DOI: 10.13140/RG.2.2.27539.532
  • P. Makvandi, U. Josic, M. Delfi, F. Pinelli, V. Jahed, E. Kaya, M. Ashrafizadeh, A. Zarepour, F. Rossi, A. Zarrabi, T. Agarwal, E. N. Zare, M. Ghomi, T. K. Maiti, L. Breschi, F. R Tay, “Drug Delivery (Nano)Platforms for Oral and Dental Applications: Tissue Regeneration, Infection Control, and Cancer Management” Adv. Sci. 8 ( 2021) 2004014.
  • R. Begum, J. Najeeb, A. Sattar, K. Naseem, A. Irfan, A. G. Al-Sehemi, Z. H. Farooqi, “Chemical reduction of methylene blue in the presence of nanocatalysts: a critical review” Rev Chem Eng (2019) doi.org/10.1515/revce-2018-0047
  • X. Wei, C. Gong, M. Gou, S.Fu, Q. Guo, S. Shi, F. Luo, G. Guo, L. Qiu, Z. Qian. International Journal of Pharmaceutics 381 (2009) 1-18
  • B. Bogdanov, A. Vidts, A. Van Den Bulcke, R. Verbeeck, E. Schacht, “Synthesis and thermal properties of poly(ethylene glycol)-poly(ε-caprolactone) copolymers" Polymer 39 (1998) 1631-1636.
  • K. Jette, D. Law, E. Schmitt, G. Kwon, “Preparation and Drug Loading of Poly(Ethylene Glycol)-blok-Poly(ε-Caprolactone) Micelles Through the Evaporation of a Cosolvent Azeotrope” Pharmaceutical Research, 21, (2004), 7.
  • C. Shen, S. Guo, C. Lu, “Degradation behaviors of monomethoxy poly(ethylene glycol)-b-poly(Ɛ-caprolactone) nanoparticles in aqueous solution” Polym. Adv. Technol. 19 (2008) 66-72.
  • M. Gou, X. Zheng, K. Men, J. Zhang, L. Zheng, X. Wang, F. Luo, F, Y. Zhao, X. Zhao, Y. Wei, Z. Qian. “Poly(ε-caprolactone)/Poly(ethylene glycol)/Poly(ε-caprolactone)Nanoparticles : Preparation, Characterization, and Application in Doxorubicin Delivery” J. Phys. Chem. B 113 (2009) 12928-12933.
  • R. Diab, M. Hamoudeh, O. Boyron, A. Elaissari, H. Fessi, “Microencapsulation of cytarabine using poly(ethylene glycol)-poly (ε-caprolactone) diblock copolymers as surfactant agents” Drug Development and Industrial Pharmacy, 36 (4) (2010) 456-469.
  • J. Sun, C. He, X. Zhuang, X. Jing, X. Chen. “The crystallization behavior of poly(ethylene glycol)- poly(ε-caprolactone) diblock copolymers with asymmetric block compositions” J Polym Res. 18 (2011) 2161-2168.
  • S. Bhatt, J. Pulpytel, M. Mirshahi, F. Arefi-Khonsari. “Catalyst-Free Plasma-Assisted Copolymerization of Poly(ε-caprolactone)-poly(ethylene glycol) for Biomedical Applications” ACS Macro Lett. 1 (2012) 764-767.
  • B. Zhang, H. Zhang, Y. Li, J. N. Hoskins, S. M. Grayson “Exploring the Effect of Amphiphilic Polymer Architecture:Synthesis, Characterization, and Self-Assembly of Both Cyclic and Linear Poly(ethylene gylcol)-b-polycaprolactone” ACS Macro Lett. 2 (2013) 845-848.
  • G. Yin, G. Chen, Z. Zhou, Q. Lİ. “Modification of PEG-b-PCL block copolymer with high melting temperature by the enhancement of POSS crystal and ordered phase structure” RSC Adv. 5 (2015) 33356.
  • A. Mohanty, U. Jana, P. Manna, G. Mohanta “Synthesis and evaluation of MePEG-PCL diblock copolymers: surface properties and controlled release behavior” Prog Biomater 4 (2015) 89-100.
  • M. Hwang, J. Suh, Y. Bae, S. Kim, B. Jeong, “Caprolactonic Poloxamer Analog: PEG-PCL-PEG” Biomacromolecules 6 (2005) 885-890.
  • C. Gong, S. Shi, P. Dong, B. Kan, M. Gou, X. Wang, X. Li, F. Luo, X. Zhao, Y. Wei, Z. Qian. “Synthesis and characterization of PEG-PCL-PEG thermosensitive hydrogel” Internation Journal of Pharmaceutics 365 (2009) 89-99.
  • N. Cuong, J. Jiang, Y. Li, J. Chen, S. Jwo, M. Hsieh. “Doxorubicin-Loaded PEG-PCL-PEG Micelle Using Xenograft Model of Nude Mice: Effect of Multiple Administration of Micelle on the Suppression of Human Breast Cancer” Cancers 3 (2011) 61-78.
  • Z. Luo, L. Jin, L. Xu, Z. Zhang, J. Yu, S. Shi, X. Li, H. Chen, H. “Thermosensitive PEG-PCL-PEG (PECE) hydrogel as an in situ gelling system for ocular drug delivery of diclofenac sodium” Drug Deliv. 23 (1) (2016) 63-68.
  • T. Shiomi, K. Imai, K. Takenaka, H. Takeshita, H. Hayashi, Y. Tezuka “Appearance of double spherulites like concentric circles for poly(ε-caprolactone)-block-poly(ethylene glycol)-block-poly(ε-caprolactone)” Polymer 42 (2001) 3233-3239.
  • Y. Hu, L. Zhang, Y. Cao, H. Ge, X. Jiang, C. Yang, “Degradation Behavior of Poly(Ɛ-caprolactone)-b-poly(ethylene glycol)-b-poly(ε-caprolactone) Micelles in Aqueous Solution” Biomacromolecules. 5 (2004) 1756-1762.
  • S. Bae, M. Joo, Y. Jeong, S. Kim, W. Lee, Y. Sohn, B. Jeong. “Gelation Behavior of Poly(ethylene glycol) and Polycaprolactone Triblock and Multiblock Copolymer Aqueous Solutions” Macromolecules. 39 (2006) 4873-4879.
  • M. Huang, M. Gou, Z. Qian, M. Dai, X. Li, M. Cao, K. Wang, J. Zhao, J. Yang, Y. Lu, M. Tu, Y. Wei, “One-step preparation of poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone) nanoparticles for plasmid DNA delivery” 86 (4) (2008) 979-86.
  • Y. Zhang, S. Guo, C. Lu, L. Lıu, Z. Lı, J. Gu J. “Poly(ε-caprolactone)-b-Poly(ethylene glycol)-b-Poly(ε-caprolactone) Triblock Copolymers: Synthesis and Self-Assembly in Aqueonus Solutions” Journal of Polymer Science:Part A:Polymer Chemistry, 45 (2007) 605-613.
  • G. Ma, B. Miao, C. Song. “Thermosensitive PCL-PEG-PCL Hydrogels: Synthesis, Characterization, and Delivery of Proteins” Journal of Applied Polymer Science. 116 (2010) 1985-1993.
  • Y. Wang, C. Wang, S. Fu, Q. Liu, D. Dou, H. Lv, M. Fan, G. Guo, F. Luo, Z. Qian, “ Preparation of Tacrolimus loaded micelles based on poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone)” International Journal of Pharmaceutics 407 (2011) 184-189.
  • R. Feng, Z. Song, G. Zhai. “Preparation and in vivo pharmacokinetics of curcumin-loaded PCL-PEG-PCL triblock copolymeric nanoparticles” International Journal of Nanomedicine, 7 (2012) 4089-4098.
  • Y. Huang, L. Li, G. Li. “An enzyme-catalysed Access to amphiphilic triblock copolymer of PCL-b-PEG-b-PCL:synthesis, characterization and self-assembly properties” Designed Monomers and Polymers 18 (2015) 799-806.
  • L’H. Azouz, F. Dahmoune, F. Rezgui, C. G’Sell. “Full factorial design optimization of anti-inflammatory drug release by PCL-PEG-PCL microspheres” Materials Science and Engineering C 58 (2016) 412-419.
  • N. Mohamed, H. Salama, M. Sabaa, G. Saad. “Synthesis and characterization of biodegradable copoly(ether-ester-urethane)s and their chitin whisker nanocomposites” J Therm Anal Calorim, 125 (2016) 163–173.
  • C. Lagunas, X. Fernández-Francos, F. Ferrando, M. Flores, A. Serra, J. Morancho, J. Salla, X. Ramis. “New epoxy thermosets modified with amphiphilic multiarm star polymers as toughness enhancer” Reactive & Functional Polymers 83 (2014) 132-143.
  • Y. Zhang, Q. Zhao, H. Shao, S. Zhang, X. Han. “ Synthesis and Characterization of Star-Shaped Block Copolymer s PCL-b-PEG-GA” Hindawi Publishing Corporation Advances in Materials Science and Engineering. (2014) 107375.
  • F. Bahadori, A. Dag, H. Durmaz, N. Cakir, H. Onyuksel, U. Tunca, G. Topcu, G. Hizal. “Synthesis and Characterization of Biodegradable Amphiphilic Star and Y-Shaped Block Copolymers as Potential Carriers for Vinorelbine” Polymers 6 (2014) 214-242.
  • M. Zhang, H. Liu, W. Shao, K. Miao, Y. Zhao. “Synthesis and properties of Multicleavable Amphiphilic Dendritic Comblike and Toothbrushlike Copolymers Comprising Alternating PEG and PCL grafts” Macromolecules 46 (2013) 1325-1336.
  • Y. Liu, J. Nguyen, T. Steele, O. Merkel, T. Kissel. “A new synthesis method and degradation of hyper-branched polyethylenimine grafted polycaprolactone block mono-methoxyl poly(ethylene glycol) copolymers (hy-PEI-g-PCL-b-m PEG) as potential DNA delivery vectors” Polymer 50 (2009) 3895-3904.
  • B.H. Vilsinski, P.R. Souza, A. C. Oliveira, C. M.C. Filho, A. J. M. Valente, E. C. Muniz, O. Borges, A. P. Gerola, Wilker Caetano, A. F. Martins. “Photophysics and drug delivery behavior of methylene blue into Arabic-gum based hydrogel matrices” Materials Today Communications 26 (2021) 101889.
  • C. Saldias, A. Leiva, S. Bonardd, C. Quezada, S. Saldias, M. Pino, D. Radic “A facile one-step synthesis of noble metal nanoparticles in DMSO using poly(ethylene glycol)-poly(ε-caprolactone) block copolymers” Reactive and Functional Polymers 96 (2015) 78–88.
  • K.T. Shalumon, C. Sheu, C.H. Chen, S.H. Heng Chen, G. Jose, C.Y. Kuo, J.P. Chen. “Multi-functional electrospun antibacterial core-shell nanofibrous membranes for prolonged prevention of post-surgical tendon adhesion and inflammation” Acta Biomaterialia 72 (2018) 121–136
  • R.V. M. Madhavan, M.J. Rosemary, M. A. Nandkumar, K. V. Krishnan, L. K. Krishnan. “Silver Nanoparticle Impregnated Poly (e-Caprolactone) Scaffolds: Optimization of Antimicrobial and Noncytotoxic Concentrations” Tissue Engineering: Part A 00 ( 2010) 00.
  • O.A. Kalaycı, F.B. Cömert, B. Hazer, B., Atalay, T., Cavicchi, K.A., Cakmak, M, “Synthesis, characterization, and antibacterial activity of metal nanoparticles embedded into amphiphilic comb-type graft copolymers” 65 (2010) Polym. Bulletin. 215–226.
  • M. Vanaja, K. Paulkumar, M. Baburaja, S. Rajeshkumar, G. Gnanajobitha, C. Malarkodi, M. Sivakavinesan, G. Annadurai, “Degradation of Methylene Blue Using Biologically Synthesized Silver Nanoparticles” Bioinorganic Chemistry and Applications (2014), Article ID 742346.
  • J. Krstić, J. Spasojević, A. Radosavljević, M. Šiljegovć, Z. K. Popović, “Optical and structural properties of radiolytically in situ synthesized silver nanoparticles stabilized by chitosan/poly (vinyl alcohol)” blends Radiation Physics and Chemistry 96 (2014) 158–166.
  • H.S. Samanta, C. Battacharjee “5th International Conference on Chemical, Agricultural, Biological and Environmental Sciences (CAFES-17)” Kyoto (Japan) April 18-19, (2017) ISBN 978-81 933894-1-6
There are 44 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Articles
Authors

Özlem Altunordu Kalaycı 0000-0001-6563-9145

Hülya Arslan 0000-0002-6891-2212

Project Number 2016-72118496-07
Publication Date July 31, 2023
Published in Issue Year 2023

Cite

APA Altunordu Kalaycı, Ö., & Arslan, H. (2023). Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi. Duzce University Journal of Science and Technology, 11(3), 1349-1364. https://doi.org/10.29130/dubited.1124484
AMA Altunordu Kalaycı Ö, Arslan H. Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi. DÜBİTED. July 2023;11(3):1349-1364. doi:10.29130/dubited.1124484
Chicago Altunordu Kalaycı, Özlem, and Hülya Arslan. “Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi Ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi”. Duzce University Journal of Science and Technology 11, no. 3 (July 2023): 1349-64. https://doi.org/10.29130/dubited.1124484.
EndNote Altunordu Kalaycı Ö, Arslan H (July 1, 2023) Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi. Duzce University Journal of Science and Technology 11 3 1349–1364.
IEEE Ö. Altunordu Kalaycı and H. Arslan, “Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi”, DÜBİTED, vol. 11, no. 3, pp. 1349–1364, 2023, doi: 10.29130/dubited.1124484.
ISNAD Altunordu Kalaycı, Özlem - Arslan, Hülya. “Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi Ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi”. Duzce University Journal of Science and Technology 11/3 (July 2023), 1349-1364. https://doi.org/10.29130/dubited.1124484.
JAMA Altunordu Kalaycı Ö, Arslan H. Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi. DÜBİTED. 2023;11:1349–1364.
MLA Altunordu Kalaycı, Özlem and Hülya Arslan. “Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi Ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi”. Duzce University Journal of Science and Technology, vol. 11, no. 3, 2023, pp. 1349-64, doi:10.29130/dubited.1124484.
Vancouver Altunordu Kalaycı Ö, Arslan H. Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi. DÜBİTED. 2023;11(3):1349-64.