Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi

Özlem Altunordu Kalaycı; Hülya Arslan

doi:10.29130/dubited.1124484

Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi

Abstract

Bu çalışmada, AB tipi diblok (mPEG-b-PCL) ve BAB tipi triblok (PCL-b-PEG-b-PCL) kopolimerler sırasıyla makrobaşlatıcı olarak mPEG (monometoksi poli(etilen glikol)) ve PEG (poli etilen glikol) kullanılarak ve katalizör olarak kalay oktanoat (Sn(Oct)2) kullanılarak ε-kaprolakton (ε-CL)’nun halka açılması polimerizasyonu ile sentezlendi. Blok kopolimer içerisinde, gümüş nitrat (AgNO3) metal tuzlarının indirgenmesiyle gümüş nanoparçacıkları içeren Ag/PEG-b-PCL ve Ag/PCL-b-PEG-b-PCL kolloidal çözeltileri üretilmiştir. mPEG-b-PCL ve PCL-b-PEG-b-PCL blok kopolimerlerinin karakterizasyonu, GPC, FTIR ve 1HNMR teknikleri kullanılarak yapılmıştır. Hibrit yapı içerisindeki gümüş nanoparçacık formasyonu, yüzey plazmon rezonans (SPR) dalga boyu değişiminden ve floresans emisyon spektrumundan gözlenmiştir. İlaç taşıyıcı sistemlerde model ilaç olarak kullanılan metilen mavisinin, polimerde gümüş nanoparçacıkların varlığında, löko-metilene indirgenme hızı araştırılmıştır.

Keywords

Supporting Institution

Zonguldak Bülent Ecevit Üniversitesi

Project Number

2016-72118496-07

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Details

Primary Language

Turkish

Subjects

Engineering

Journal Section

Research Article

Authors

Özlem Altunordu Kalaycı
0000-0001-6563-9145
Türkiye

Hülya Arslan ^*
0000-0002-6891-2212
Türkiye

Publication Date

July 31, 2023

Submission Date

June 1, 2022

Acceptance Date

September 27, 2022

Published in Issue

Year 2023 Volume: 11 Number: 3

DOI

https://doi.org/10.29130/dubited.1124484

IZ

https://izlik.org/JA78TU64HJ

Cite

RIS / Bibtex

APA

Altunordu Kalaycı, Ö., & Arslan, H. (2023). Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi. Duzce University Journal of Science and Technology, 11(3), 1349-1364. https://doi.org/10.29130/dubited.1124484

AMA

1.Altunordu Kalaycı Ö, Arslan H. Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi. DUBİTED. 2023;11(3):1349-1364. doi:10.29130/dubited.1124484

Chicago

Altunordu Kalaycı, Özlem, and Hülya Arslan. 2023. “Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi Ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi”. Duzce University Journal of Science and Technology 11 (3): 1349-64. https://doi.org/10.29130/dubited.1124484.

EndNote

Altunordu Kalaycı Ö, Arslan H (July 1, 2023) Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi. Duzce University Journal of Science and Technology 11 3 1349–1364.

IEEE

[1]Ö. Altunordu Kalaycı and H. Arslan, “Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi”, DUBİTED, vol. 11, no. 3, pp. 1349–1364, July 2023, doi: 10.29130/dubited.1124484.

ISNAD

Altunordu Kalaycı, Özlem - Arslan, Hülya. “Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi Ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi”. Duzce University Journal of Science and Technology 11/3 (July 1, 2023): 1349-1364. https://doi.org/10.29130/dubited.1124484.

JAMA

1.Altunordu Kalaycı Ö, Arslan H. Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi. DUBİTED. 2023;11:1349–1364.

MLA

Altunordu Kalaycı, Özlem, and Hülya Arslan. “Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi Ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi”. Duzce University Journal of Science and Technology, vol. 11, no. 3, July 2023, pp. 1349-64, doi:10.29130/dubited.1124484.

Vancouver

1.Özlem Altunordu Kalaycı, Hülya Arslan. Gümüş Nanoparçacık İçeren Polimer Hibrit Nanomalzemelerin Sentezi ve Metilen Mavisi İndirgenmesine Nanoparçacık Etkisi. DUBİTED. 2023 Jul. 1;11(3):1349-64. doi:10.29130/dubited.1124484