Amido-Tiyoüre Bazlı p-tert-bütilkaliks[4]aren Bileşiğinin Sentezi, Karakterizasyonu ve Geçiş Metal Kompleks Özelliklerinin Araştırılması

Year 2024, , 858 - 868, 29.04.2024

Sevil Söyleyici

https://doi.org/10.29130/dubited.1198430

Abstract

Konak-konuk kompleks bileşiklerinde, konakçı boşluğunun ve konuk molekülün boyut ve şeklinin uyumluluğu, konak-konuk kompleksinin oluşumunda esastır. Üçüncü nesil makrosiklik konakçılar olarak kabul edilen kaliksarenler, biyokataliz, enzim analizi, farmasötikler ve biyoalgılama gibi alanlarda geniş bir uygulama yelpazesi sunmaları nedeniyle supramoleküler kimya araştırmacılarının ilgisini çekmektedir. Koordinasyon kimyasında anyonik ve katyonik misafir bileşikler için ev sahibi moleküllerin sentezi oldukça önemli yer tutmaktadır. Kaliksareneler supramoleküler bileşiklerin önemli türlerinden biri olarak bilinmekte ve katyon, anyon ve organik moleküller için uygun bir reseptör olarak görev alabilen ve kolay sentezlenebilen önemli bir bileşik sınıfıdır. Ev sahibi-konuk kimyasında önemli bir yeri olan kaliksaren bileşikleri uygun şekilde türevlendirildiklerinde, molekülün metal katyonlarına karşı koordinasyon yeteneği artmaktadır. Bu türevlendirmeler moleküllün sensör özelliği göstermesi ile önem kazanmış ve daha çok misafir molekülü için daha büyük kavite ve fonksiyonel grup gerektiği düşünülerek faklı çalışmalar başlamıştır. Bu çalışmada da katyon seçimliliği arttırılmış, yapısında amit grupları taşıyan 1,3-disübstitüe kaliks[4]aren türevi bileşik ve bu bileşiğin Co(II), Ni(II), Cu(II) ve Zn(II) kompleksleri sentezlenerek bileşiklerin yapıları UV-vis, FT-IR, 1H-NMR, 13C-NMR kütle spektrometresi ile aydınlatılmıştır.

Keywords

p-tert-butilkaliks[4]aren, Geçiş Metal Kompleksi, Amit, Tiyoüre

Project Number

2011BSP028

Synthesis and Characterization of Amido-Thiourea Based p-tert-butylcalix[4]arene Compound and Investigation of Transition Metal Complex Properties

Abstract

In host-guest complexes, the compatibility of the size and shape of the host cavity and the guest molecule is essential in the formation of the host-guest complex. Considered third-generation macrocyclic hosts, calixarenes attract the attention of researchers in supramolecular chemistry as they offer a wide range of applications in fields such as biocatalysis, enzyme analysis, pharmaceuticals, and biosensing. The synthesis of host molecules for anionic and cationic guest compounds has a very important place in coordination chemistry. Calixarenes are known as one of the important types of supramolecular compounds and are an important class of easily synthesized compounds that can act as a suitable receptors for cations, anions, and organic molecules. When calixarene compounds, which have an important place in host-guest chemistry, are derivatized appropriately, the coordination ability of the molecule against metal cations increases. These derivatizations gained importance due to the sensory properties of the molecule, and different studies were started considering that a larger cavity and functional group are required for more guest molecules. In this study, a new ligand of 1,3-disubstituted p-tert-butylcalix[4]arene derivative with increased donor atomic number with amide and thiourea groups in its structure was synthesized. Co(II), Ni(II), Cu(II), and Zn(II) complexes were synthesized with the compound and the structures of the compounds were characterized by UV-vis, FT-IR, 1H-NMR, 13C-NMR, and mass spectrometry.

Keywords

p-tert-butylcalix[4]arene, Transition Metal Complex, Amide, Thiourea

Supporting Institution

Pamukkale Üniversitesi

Project Number

2011BSP028

Thanks

This study was supported by Pamukkale University Scientific ResearchProjects (Project no: 2011BSP028).

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