Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine

İrem Okman Koçoğlu

doi:10.29130/dubited.1463687

EN TR

Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine

Abstract

In this study, the use of three different crown ether-modified electrodes prepared by electropolymerization of different crown ether compounds (CE1, CE2 and CE3) on multi-walled carbon nanotube (MWCNT) modified glassy carbon electrode (GCE) surfaces was investigated for electrochemical dopamine determination. The number of cycles during the electropolymerization of crown ethers and the pH of the buffer solution were optimized. Under optimum conditions, the sensitivities of MWCNT-modified GCE and crown ether-MWCNT-modified electrodes were determined in the range of 4.0×10-6 – 5.7×10-4 M dopamine. The sensitivity of MWCNT/GCE was found to be 6.71 µA mM-1, while the sensitivities of CE1/MWCNT/GCE, CE2/MWCNT/GCE and CE3/MWCNT/GCE were 19.53, 16.32 and 20.80 µA mM-1, respectively. The performance characteristics of the crown ether-MWCNT-modified electrodes such as detection limit, quantification limit, reusability and reproducibility were also investigated. The study showed that crown ether compounds significantly enhanced the electrochemical response in dopamine determination.

Keywords

Crown ether, Electrochemical sensor, Dopamine, Modified electrode, Multi-walled carbon nanotube

Supporting Institution

Karabük University Scientific Research Projects Coordination Unit

Project Number

KBÜBAP-24-DS-039

Thanks

This study is supported by Karabük University Scientific Research Projects Coordination Unit. Project Number: KBÜBAP-24-DS-039

Dopaminin Elektrokimyasal Tayini için Bazı Taç Eter Bileşiklerinin Kullanımının Araştırılması

Abstract

Bu çalışmada çok duvarlı karbon nanotüp (MWCNT) modifiye edilmiş camsı karbon elektrot (GCE) yüzeylerine farklı taç eter bileşiklerinin (CE1, CE2 ve CE3) elektropolimerizasyonu ile hazırlanan üç farklı taç eter-modifiye elektrodun elektrokimyasal dopamin tayininde kullanımı araştırıldı. Taç eterlerin elektropolimerizasyonu sırasındaki döngü sayısı ve çalışılan tampon çözelti pH’sı optimize edildi. Optimum koşullarda, MWCNT modifiye edilmiş GCE ile taç eter-MWCNT-modifiye elektrotların 4,0×10-6 − 5,7×10-4 M dopamin derişimi aralığında duyarlılıkları belirlendi. MWCNT/GCE’nin duyarlılığı 6,71 µA mM-1 olarak bulunurken, CE1/MWCNT/GCE, CE2/MWCNT/GCE ve CE3/MWCNT/GCE’nin duyarlılıkları sırasıyla 19,53; 16,32 ve 20,80 µA mM-1 olarak belirlendi. Taç eter-modifiye elektrotların gözlenebilme sınırı, tayin sınırı, tekrar kullanılabilirlik ve tekrar üretilebilirlik gibi performans özellikleri de incelendi. Çalışma, taç eter bileşiklerinin dopamin tayininde elektrokimyasal cevabı önemli ölçüde arttırdığını ve dopamin tayinine olumlu yönde etki ettiğini gösterdi.

Keywords

Taç eter, Elektrokimyasal sensör, Dopamin, Modifiye elektrot, Çok duvarlı karbon nanotüp

Supporting Institution

Karabük Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi

Project Number

KBÜBAP-24-DS-039

Thanks

Bu çalışma Karabük Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi tarafından desteklenmiştir. Proje Numarası: KBÜBAP-24-DS-039

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Details

Primary Language

English

Subjects

Electroanalytical Chemistry, Sensor Technology

Journal Section

Research Article

Authors

İrem Okman Koçoğlu ^*
0000-0001-6071-9795
Türkiye

Publication Date

October 23, 2024

Submission Date

April 2, 2024

Acceptance Date

July 19, 2024

Published in Issue

Year 2024 Volume: 12 Number: 4

DOI

https://doi.org/10.29130/dubited.1463687

IZ

https://izlik.org/JA55ZF73GY

APA

Okman Koçoğlu, İ. (2024). Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine. Duzce University Journal of Science and Technology, 12(4), 2185-2199. https://doi.org/10.29130/dubited.1463687

AMA

1.Okman Koçoğlu İ. Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine. DUBİTED. 2024;12(4):2185-2199. doi:10.29130/dubited.1463687

Chicago

Okman Koçoğlu, İrem. 2024. “Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine”. Duzce University Journal of Science and Technology 12 (4): 2185-99. https://doi.org/10.29130/dubited.1463687.

EndNote

Okman Koçoğlu İ (October 1, 2024) Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine. Duzce University Journal of Science and Technology 12 4 2185–2199.

IEEE

[1]İ. Okman Koçoğlu, “Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine”, DUBİTED, vol. 12, no. 4, pp. 2185–2199, Oct. 2024, doi: 10.29130/dubited.1463687.

ISNAD

Okman Koçoğlu, İrem. “Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine”. Duzce University Journal of Science and Technology 12/4 (October 1, 2024): 2185-2199. https://doi.org/10.29130/dubited.1463687.

JAMA

1.Okman Koçoğlu İ. Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine. DUBİTED. 2024;12:2185–2199.

MLA

Okman Koçoğlu, İrem. “Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine”. Duzce University Journal of Science and Technology, vol. 12, no. 4, Oct. 2024, pp. 2185-99, doi:10.29130/dubited.1463687.

Vancouver

1.İrem Okman Koçoğlu. Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine. DUBİTED. 2024 Oct. 1;12(4):2185-99. doi:10.29130/dubited.1463687

Investigation of Some Crown Ether Compounds for Electrochemical Determination of Dopamine

Abstract

Keywords

Supporting Institution

Project Number

Thanks

Dopaminin Elektrokimyasal Tayini için Bazı Taç Eter Bileşiklerinin Kullanımının Araştırılması

Abstract

Keywords

Supporting Institution

Project Number

Thanks

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite