Fabrication and Characterization of Sugarcane Bagasse/Coconut Shell Particle-Reinforced Hybrid Polymer Biocomposites for Compostable Packaging
Year 2026,
Volume: 14 Issue: 2
,
629
-
640
,
19.04.2026
Stephen Idowu Durowaye
,
Olusola Emmanuel Ojo
Abstract
Reinforcement of polymers with natural fillers has gained significant attention due to growing environmental concerns, the need for sustainability, and the limited viability of synthetic materials. This study addressed these challenges by developing and characterizing epoxy-based hybrid biocomposites reinforced with sugarcane bagasse and coconut shell particles. The biocomposites were fabricated using the stir casting method, and their microstructural, mechanical, and biodegradability properties were systematically evaluated. Experimental results revealed that the biocomposite containing 12 wt. % hybrid fillers exhibited optimal performance, with a 32.2 % increase in hardness (24.87 HV), a 12.3 % improvement in compressive strength (67.99 MPa), and a 4.1 % enhancement in impact energy (6.16 J) compared to the control sample. Scanning Electron Microscopy (SEM) analysis confirmed uniform filler dispersion and strong matrix–particle interfacial bonding. Biodegradability tests showed the highest weight loss of 18.5 % after seven months, indicating effective compostability. The synergistic reinforcement from sugarcane bagasse and coconut shell significantly enhanced both mechanical and environmental performance, demonstrating the composite’s potential for sustainable packaging applications.
Ethical Statement
This study does not involve human or animal participants. All procedures followed scientific and ethical principles, and all referenced studies were appropriately cited.
Supporting Institution
This research received financial support from the Central Research Committee (CRC) of the University of Lagos, Nigeria, under Grant No. CRC-2025/014.
Thanks
This research received financial support from the Central Research Committee (CRC) of the University of Lagos, Nigeria, under Grant No. CRC-2025/014. The authors gratefully acknowledge this support, which was instrumental to the successful execution of the study. The authors also thank Mr. Jelili Tiamiyu of the Department of Metallurgical and Materials Engineering, University of Lagos, for his invaluable assistance with logistics.
References
-
Abdollahiparsa, H., Shahmirzaloo, A., Teuffel, P., & Blok, R. (2023). A review of recent developments in structural applications of natural fiber-reinforced composites (NFRCs). Composites and Advanced Materials, 32, 1-18. https://doi.org/10.1177/26349833221147540
-
Abdul-Khalil, H. P. S., Davoudpour, Y., Islam, M. N., Mustapha, A., Sudesh, K., Dungani, R., & Jawaid, M. (2014). Production and modification of nanofibrillated cellulose using various mechanical processes: A review. Carbohydrate Polymers, 99, 649-665. https://doi.org/10.1016/j.carbpol.2013.08.069
-
Akorede, A. O., Dauda, B., & Adeyemi, M. M. (2019). The influence of chemical treatment on mechanical properties and biodegradability of sugarcane fibre filler epoxy resin. American Journal of Engineering Research, 8(1), 233-242.
-
Asim, M., Abdan, K., Jawaid, M., Nasir, M., Dashtizadeh, Z., Ishak, M. R., & Hoque, M. E. (2015). A review on pineapple leaves and its composites. International Journal of Polymer Science, 2015, Article 950567. https://doi.org/10.1155/2015/950567
-
ASTM International. (2018a). Standard test methods for determining the Izod pendulum impact strength of plastics (ASTM D256-10). https://doi.org/10.1520/D0256-10R18
-
ASTM International. (2018b). Standard test method for determining aerobic biodegradation of plastic materials in soil (ASTM D5988-18). https://doi.org/10.1520/D5988-18
-
ASTM International. (2024). Standard test method for compressive properties of polymer matrix composite materials with unsupported gage section by shear loading (ASTM D3410/D3410M-16). https://doi.org/10.1520/D3410_D3410M-16R24
-
ASTM International. (2022). Standard test method for micro indentation hardness of materials (ASTM E384-22). https://doi.org/10.1520/E0384-22
-
Babu, R. D., Kumar, S., & Raju, J. S. (2021). Review on mechanical investigation on sugarcane and glass fibre composite material. Journal of Critical Reviews, 8(1), 385-389. https://jcreview.com/archives/volume-8/issue-1/6535
-
Balaji, A., Karthikeyan, B., & Swaminathan, J. (2019). Comparative mechanical, thermal, and morphological study of untreated and NaOH-treated bagasse fiber-reinforced cardanol green composites. Advanced Composites and Hybrid Materials, 2, 125-132. https://doi.org/10.1007/s42114-019-00079-7
-
Bam, S. A., Gundu, D. T., & Onu, F. A. (2019). The effect of chemical treatments on the mechanical and physical properties of bagasse filler reinforced low-density polyethylene composite. American Journal of Engineering Research, 8(4), 95-98.
-
Bolasodun, B., Durowaye, S., & Akano, T. (2022). Synthesis and characterization of sugarcane bagasse and pineapple leaf particulate reinforced polyester resin matrix composites. Gazi University Journal of Science, 35(3), 1091-1100. https://doi.org/10.35378/gujs.787964
-
Cerqueira, E. F., Baptista, C. A. R. P., & Mulinari, D. R. (2011). Mechanical behaviour of polypropylene reinforced sugarcane bagasse fibers composites. Procedia Engineering, 10, 2046-2051. https://doi.org/10.1016/j.proeng.2011.04.339
-
Dehury, J., Mohanty, J. R., Biswas, S., & Bhagat, V. (2017). Physical, mechanical and water absorption behavior of bi-directional jute/glass fiber reinforced epoxy composites. International Journal of Engineering Research, 6(1), 1-6.
-
Durowaye, S., Kanu, D., Awotunde, O., & Alao, S. (2022). Effect of particulate of mild steel and aluminium dross on the physical and mechanical properties of epoxy-resin matrix composites. Scientific Journal of Mehmet Akif Ersoy University, Techno-Science, 5(1), 1-8.
-
Fadare, O. B., Adewuyi, B. O., Oladele, I. O., & Ukoba, K. (2021). A review on waste-wood reinforced polymer matrix composites for sustainable development. IOP Conference Series: Materials Science and Engineering, 1107, Article 012057. https://doi.org/10.1088/1757-899x/1107/1/012057
-
Fekiač, J. J., Krbata, M., Kohutiar, M., Janík, R., Kakošová, L., Breznická, A., Eckert, M., & Mikuš, P. (2025). Comprehensive review: Optimization of epoxy composites, mechanical properties, & technological trends. Polymers, 17(3), Article 271. https://doi.org/10.3390/polym17030271
-
Fong, A. L., Khandoker, N. A. N., & Debnath, S. (2018). Development and characterization of sugarcane bagasse fiber and nano-silica reinforced epoxy hybrid composites. IOP Conference Series: Materials Science and Engineering, 344, Article 012029. https://doi.org/10.1088/1757-899X/344/1/012029
-
Furgier, V., Root, A., Heinmaa, I., Zamani, A., & Åkesson, D. (2024). Development and characterisation of composites prepared from PHBV compounded with organic waste reinforcements, and their soil biodegradation. Materials, 17(3), Article 768. https://doi.org/10.3390/ma17030768
-
Future Market Insights, Inc. (2026). Global sustainable packaging market to reach USD 421.6 billion by 2036 [Market forecast]. AccessNewswire. https://www.accessnewswire.com/newsroom/en/business-and-professional-services/global-sustainable-packaging-market-to-reach-usd-421.6-billion-b-1135489
-
Haque, S., Karim, F. E., Islam, M. R., & Siddique, A. B. (2023). Mechanical characterization of luffa-bagasse fiber reinforced polymer-based hybrid composite. Textile & Leather Review, 6(1), 252-270. https://doi.org/10.31881/tlr.2022.111
-
Husseinsyah, S., & Mostapha, M. (2011). The effect of filler content on properties of coconut shell filled polyester composites. Malaysian Polymer Journal, 6(1), 87-97.
-
Jaramillo, A. F., Medina, C., Flores, P., Canales, C., Maldonado, C., Castaño Rivera, P., Rojas, D., & Meléndrez, M. F. (2020). Improvement of thermomechanical properties of composite based on hydroxyapatite functionalized with alkylsilanes in epoxy matrix. Ceramic International, 46(6), 8368-8378. https://doi.org/10.1016/j.ceramint.2019.12.069
-
Jawaid, M., & Khalil, H. P. S. A. (2011). Cellulosic/synthetic fibre reinforced polymer hybrid composites: A review. Carbohydrate Polymers, 86(1), 1-18. https://doi.org/10.1016/j.carbpol.2011.04.043
-
Kaewpirom, S., & Worrarat, C. (2014). Preparation and properties of pineapple leaf fiber reinforced poly(lactic acid) green composites. Fibers and Polymers, 15(7), 1469-1477. https://doi.org/10.1007/s12221-014-1469-0
-
Kalia, S., Dufresne, A., Cherian, B. M., Kaith, B. S., Avérous, L., Njuguna, J., & Nassiopoulos, E. (2011). Cellulose-based bio-and nanocomposites: A review. International Journal of Polymer Science, 2011, Article 837875. https://doi.org/10.1155/2011/837875
-
Kamaruddin, S. H., Rayung, M., Abu, F., Ahmad, S., Fadil, F., Karim, A. A., Norizan, M. N., Sarifuddin, N., Mat-Desa, M. S. Z., Mohd-Basri, M. S., Samsudin, H., & Abdullah, L. C. (2022). A review on antimicrobial packaging from biodegradable polymer composites. Polymers, 14(1), Article 174. https://doi.org/10.3390/polym14010174
-
Kuciel, S., Rusin-Żurek, K., & Kurańska, M. (2024). The influence of filler particle size on the strength properties and mechanical energy dissipation capacity of biopoly (ethylene terephthalate) BioPET/eggshell biocomposites. Recycling, 9(5), Article 88. https://doi.org/10.3390/recycling9050088
-
Kuforiji, C., Durowaye, S., Odunitan, O., Kassim, K., & Lawal, G. (2023). Influence of sawdust particles reinforcement on physical and mechanical properties of high-density polyethylene (HDPE) matrix composites. Kathmandu University Journal of Science, Engineering and Technology, 17(1), 1-7. https://doi.org/10.3126/kuset.v17i1.62382
-
Makinde-Isola, B. A., Taiwo, A. S., Oladele, I. O., Akinwekomi, A. D., Adelani, S. O., & Onuh, L. N. (2023). Development of sustainable and biodegradable materials: A review on banana and sisal fibre based polymer composites. Journal of Thermoplastic Composite Materials, 37(4), 1-21. https://doi.org/10.1177/08927057231186324
-
Mustapha, K., Sogoye, M., Ottan, A. S., Danyuo, Y., Azeko, S. T., & Annan, E. (2021). Strength and fracture resistance of cellulose fiber reinforced cement composite. Technoscience Journal for Community Development in Africa, 2(1), 29-37.
-
Nguyen, D. D., Vadivel, M., Shobana, S., Arvindnarayan, S., Dharmaraja, J., Priya, R. K., Nguyen-Tri, P., Kumar, G., & Chang, S. W. (2020). Fabrication and modeling of prototype bike silencer using hybrid glass and chicken feather fiber/hydroxyapatite reinforced epoxy composites. Progress in Organic Coatings, 148, Article 105871. https://doi.org/10.1016/j.porgcoat.2020.105871
-
Ni, Z., Shi, J., Li, M., Lei, W., & Yu, W. (2023). FDM 3D printing and soil-burial-degradation behaviors of residue of Astragalus particles/thermoplastic starch/poly(lactic acid) biocomposites. Polymers, 15(10), Article 2382. https://doi.org/10.3390/polym15102382
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Nourbakhsh, A., & Ashori, A. (2010). Wood plastic composites from agro-waste materials: Analysis of mechanical properties. Bioresource Technology, 101(7), 2525-2528. https://doi.org/10.1016/j.biortech.2009.11.040
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Oladele, I. O., Akinwekomi, A. D., Akinseye, J. G., Falana, S. O., & Oke, S. R. (2024). Evolution of bamboo derivative fiber-mollusk shell based calcite particulate hybrid reinforced epoxy bio-composites for sustainable applications. Journal of Composite Materials, 58(24), 2597-2622. https://doi.org/10.1177/00219983241270966
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Fabrication and Characterization of Sugarcane Bagasse/Coconut Shell Particle-Reinforced Hybrid Polymer Biocomposites for Compostable Packaging
Year 2026,
Volume: 14 Issue: 2
,
629
-
640
,
19.04.2026
Stephen Idowu Durowaye
,
Olusola Emmanuel Ojo
Abstract
Reinforcement of polymers with natural fillers has gained significant attention due to growing environmental concerns, the need for sustainability, and the limited viability of synthetic materials. This study addressed these challenges by developing and characterizing epoxy-based hybrid biocomposites reinforced with sugarcane bagasse and coconut shell particles. The biocomposites were fabricated using the stir casting method, and their microstructural, physical, mechanical, and biodegradability properties were systematically evaluated. Experimental results revealed that the biocomposite containing 12 wt. % hybrid fillers exhibited optimal performance, with a 32.2 % increase in hardness (24.87 HV), a 12.3 % improvement in compressive strength (67.99 MPa), and a 4.1 % enhancement in impact energy (6.16 J) compared to the control sample. Scanning Electron Microscopy (SEM) analysis confirmed uniform filler dispersion and strong matrix–particle interfacial bonding. Biodegradability tests showed the highest weight loss of 18.5 % after seven months, indicating effective compostability. The synergistic reinforcement from sugarcane bagasse and coconut shell significantly enhanced both mechanical and environmental performance, demonstrating the composite’s potential for sustainable packaging applications.
Ethical Statement
This study does not involve human or animal participants. All procedures followed scientific and ethical principles, and all referenced studies were appropriately cited.
Supporting Institution
This research received financial support from the Central Research Committee (CRC) of the University of Lagos, Nigeria, under Grant No. CRC-2025/014. The authors gratefully acknowledge this support, which was instrumental to the successful execution of the study. The authors also thank Mr. Jelili Tiamiyu of the Department of Metallurgical and Materials Engineering, University of Lagos, for his invaluable assistance with logistics.
Thanks
This research received financial support from the Central Research Committee (CRC) of the University of Lagos, Nigeria, under Grant No. CRC-2025/014. The authors gratefully acknowledge this support, which was instrumental to the successful execution of the study. The authors also thank Mr. Jelili Tiamiyu of the Department of Metallurgical and Materials Engineering, University of Lagos, for his invaluable assistance with logistics.
References
-
Abdollahiparsa, H., Shahmirzaloo, A., Teuffel, P., & Blok, R. (2023). A review of recent developments in structural applications of natural fiber-reinforced composites (NFRCs). Composites and Advanced Materials, 32, 1-18. https://doi.org/10.1177/26349833221147540
-
Abdul-Khalil, H. P. S., Davoudpour, Y., Islam, M. N., Mustapha, A., Sudesh, K., Dungani, R., & Jawaid, M. (2014). Production and modification of nanofibrillated cellulose using various mechanical processes: A review. Carbohydrate Polymers, 99, 649-665. https://doi.org/10.1016/j.carbpol.2013.08.069
-
Akorede, A. O., Dauda, B., & Adeyemi, M. M. (2019). The influence of chemical treatment on mechanical properties and biodegradability of sugarcane fibre filler epoxy resin. American Journal of Engineering Research, 8(1), 233-242.
-
Asim, M., Abdan, K., Jawaid, M., Nasir, M., Dashtizadeh, Z., Ishak, M. R., & Hoque, M. E. (2015). A review on pineapple leaves and its composites. International Journal of Polymer Science, 2015, Article 950567. https://doi.org/10.1155/2015/950567
-
ASTM International. (2018a). Standard test methods for determining the Izod pendulum impact strength of plastics (ASTM D256-10). https://doi.org/10.1520/D0256-10R18
-
ASTM International. (2018b). Standard test method for determining aerobic biodegradation of plastic materials in soil (ASTM D5988-18). https://doi.org/10.1520/D5988-18
-
ASTM International. (2024). Standard test method for compressive properties of polymer matrix composite materials with unsupported gage section by shear loading (ASTM D3410/D3410M-16). https://doi.org/10.1520/D3410_D3410M-16R24
-
ASTM International. (2022). Standard test method for micro indentation hardness of materials (ASTM E384-22). https://doi.org/10.1520/E0384-22
-
Babu, R. D., Kumar, S., & Raju, J. S. (2021). Review on mechanical investigation on sugarcane and glass fibre composite material. Journal of Critical Reviews, 8(1), 385-389. https://jcreview.com/archives/volume-8/issue-1/6535
-
Balaji, A., Karthikeyan, B., & Swaminathan, J. (2019). Comparative mechanical, thermal, and morphological study of untreated and NaOH-treated bagasse fiber-reinforced cardanol green composites. Advanced Composites and Hybrid Materials, 2, 125-132. https://doi.org/10.1007/s42114-019-00079-7
-
Bam, S. A., Gundu, D. T., & Onu, F. A. (2019). The effect of chemical treatments on the mechanical and physical properties of bagasse filler reinforced low-density polyethylene composite. American Journal of Engineering Research, 8(4), 95-98.
-
Bolasodun, B., Durowaye, S., & Akano, T. (2022). Synthesis and characterization of sugarcane bagasse and pineapple leaf particulate reinforced polyester resin matrix composites. Gazi University Journal of Science, 35(3), 1091-1100. https://doi.org/10.35378/gujs.787964
-
Cerqueira, E. F., Baptista, C. A. R. P., & Mulinari, D. R. (2011). Mechanical behaviour of polypropylene reinforced sugarcane bagasse fibers composites. Procedia Engineering, 10, 2046-2051. https://doi.org/10.1016/j.proeng.2011.04.339
-
Dehury, J., Mohanty, J. R., Biswas, S., & Bhagat, V. (2017). Physical, mechanical and water absorption behavior of bi-directional jute/glass fiber reinforced epoxy composites. International Journal of Engineering Research, 6(1), 1-6.
-
Durowaye, S., Kanu, D., Awotunde, O., & Alao, S. (2022). Effect of particulate of mild steel and aluminium dross on the physical and mechanical properties of epoxy-resin matrix composites. Scientific Journal of Mehmet Akif Ersoy University, Techno-Science, 5(1), 1-8.
-
Fadare, O. B., Adewuyi, B. O., Oladele, I. O., & Ukoba, K. (2021). A review on waste-wood reinforced polymer matrix composites for sustainable development. IOP Conference Series: Materials Science and Engineering, 1107, Article 012057. https://doi.org/10.1088/1757-899x/1107/1/012057
-
Fekiač, J. J., Krbata, M., Kohutiar, M., Janík, R., Kakošová, L., Breznická, A., Eckert, M., & Mikuš, P. (2025). Comprehensive review: Optimization of epoxy composites, mechanical properties, & technological trends. Polymers, 17(3), Article 271. https://doi.org/10.3390/polym17030271
-
Fong, A. L., Khandoker, N. A. N., & Debnath, S. (2018). Development and characterization of sugarcane bagasse fiber and nano-silica reinforced epoxy hybrid composites. IOP Conference Series: Materials Science and Engineering, 344, Article 012029. https://doi.org/10.1088/1757-899X/344/1/012029
-
Furgier, V., Root, A., Heinmaa, I., Zamani, A., & Åkesson, D. (2024). Development and characterisation of composites prepared from PHBV compounded with organic waste reinforcements, and their soil biodegradation. Materials, 17(3), Article 768. https://doi.org/10.3390/ma17030768
-
Future Market Insights, Inc. (2026). Global sustainable packaging market to reach USD 421.6 billion by 2036 [Market forecast]. AccessNewswire. https://www.accessnewswire.com/newsroom/en/business-and-professional-services/global-sustainable-packaging-market-to-reach-usd-421.6-billion-b-1135489
-
Haque, S., Karim, F. E., Islam, M. R., & Siddique, A. B. (2023). Mechanical characterization of luffa-bagasse fiber reinforced polymer-based hybrid composite. Textile & Leather Review, 6(1), 252-270. https://doi.org/10.31881/tlr.2022.111
-
Husseinsyah, S., & Mostapha, M. (2011). The effect of filler content on properties of coconut shell filled polyester composites. Malaysian Polymer Journal, 6(1), 87-97.
-
Jaramillo, A. F., Medina, C., Flores, P., Canales, C., Maldonado, C., Castaño Rivera, P., Rojas, D., & Meléndrez, M. F. (2020). Improvement of thermomechanical properties of composite based on hydroxyapatite functionalized with alkylsilanes in epoxy matrix. Ceramic International, 46(6), 8368-8378. https://doi.org/10.1016/j.ceramint.2019.12.069
-
Jawaid, M., & Khalil, H. P. S. A. (2011). Cellulosic/synthetic fibre reinforced polymer hybrid composites: A review. Carbohydrate Polymers, 86(1), 1-18. https://doi.org/10.1016/j.carbpol.2011.04.043
-
Kaewpirom, S., & Worrarat, C. (2014). Preparation and properties of pineapple leaf fiber reinforced poly(lactic acid) green composites. Fibers and Polymers, 15(7), 1469-1477. https://doi.org/10.1007/s12221-014-1469-0
-
Kalia, S., Dufresne, A., Cherian, B. M., Kaith, B. S., Avérous, L., Njuguna, J., & Nassiopoulos, E. (2011). Cellulose-based bio-and nanocomposites: A review. International Journal of Polymer Science, 2011, Article 837875. https://doi.org/10.1155/2011/837875
-
Kamaruddin, S. H., Rayung, M., Abu, F., Ahmad, S., Fadil, F., Karim, A. A., Norizan, M. N., Sarifuddin, N., Mat-Desa, M. S. Z., Mohd-Basri, M. S., Samsudin, H., & Abdullah, L. C. (2022). A review on antimicrobial packaging from biodegradable polymer composites. Polymers, 14(1), Article 174. https://doi.org/10.3390/polym14010174
-
Kuciel, S., Rusin-Żurek, K., & Kurańska, M. (2024). The influence of filler particle size on the strength properties and mechanical energy dissipation capacity of biopoly (ethylene terephthalate) BioPET/eggshell biocomposites. Recycling, 9(5), Article 88. https://doi.org/10.3390/recycling9050088
-
Kuforiji, C., Durowaye, S., Odunitan, O., Kassim, K., & Lawal, G. (2023). Influence of sawdust particles reinforcement on physical and mechanical properties of high-density polyethylene (HDPE) matrix composites. Kathmandu University Journal of Science, Engineering and Technology, 17(1), 1-7. https://doi.org/10.3126/kuset.v17i1.62382
-
Makinde-Isola, B. A., Taiwo, A. S., Oladele, I. O., Akinwekomi, A. D., Adelani, S. O., & Onuh, L. N. (2023). Development of sustainable and biodegradable materials: A review on banana and sisal fibre based polymer composites. Journal of Thermoplastic Composite Materials, 37(4), 1-21. https://doi.org/10.1177/08927057231186324
-
Mustapha, K., Sogoye, M., Ottan, A. S., Danyuo, Y., Azeko, S. T., & Annan, E. (2021). Strength and fracture resistance of cellulose fiber reinforced cement composite. Technoscience Journal for Community Development in Africa, 2(1), 29-37.
-
Nguyen, D. D., Vadivel, M., Shobana, S., Arvindnarayan, S., Dharmaraja, J., Priya, R. K., Nguyen-Tri, P., Kumar, G., & Chang, S. W. (2020). Fabrication and modeling of prototype bike silencer using hybrid glass and chicken feather fiber/hydroxyapatite reinforced epoxy composites. Progress in Organic Coatings, 148, Article 105871. https://doi.org/10.1016/j.porgcoat.2020.105871
-
Ni, Z., Shi, J., Li, M., Lei, W., & Yu, W. (2023). FDM 3D printing and soil-burial-degradation behaviors of residue of Astragalus particles/thermoplastic starch/poly(lactic acid) biocomposites. Polymers, 15(10), Article 2382. https://doi.org/10.3390/polym15102382
-
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