Determination of Adsorption Parameters in Removal of Methylene Blue from Aqueous Solution Using Activated Zeolite and Polyvinylpyrrolidone

Year 2019, , 1 - 14, 31.01.2019

Filiz Kar , Melek Yılgın , Neslihan Duranay

https://doi.org/10.29130/dubited.472089

Cited By: 3

Abstract

In this study, the use of natural zeolite, activated zeolite and Polyvinylpyrrolidone (PVP) as adsorbent was
investigated to remove methylene blue (MM) from aqueous solutions. Natural zeolite; KOH, NaOH, HCl,
purified water, H3PO4 and H3BO3 were activated. In the experiments using zeolite washed with pure water and
activated at 400 oC, the highest adsorption efficiency was reached. The equilibrium data obtained at the end of
the adsorption process at different temperatures were applied to Lanmuir, Freundlich, Temkin and Harkins Jura
models and the model parameters were calculated. Accordingly, it was determined that the model representing
the best adsorption was Langmuir and the adsorption entalps was 12.70 kJ / mol. In the experiments with PVP,
Langmuir was the model that best represents the adsorption. The adsorption enthalpy was determined as
14.32kJ/mol.

Keywords

Zeolite, Methylene Blue, Adsorption Isotherm, Thermodynamic Parameters

Aktifleştirilmiş Zeolit ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi

Abstract

Bu çalışmada, sulu çözeltilerden metilen mavisinin (MM) giderilmesi için adsorban olarak doğal zeolit (DZ) ve
aktifleştirilmiş zeolit (AZ) ile polivinil prolidonun (PVP) kullanımı araştırılmıştır. Doğal zeolit; KOH, NaOH,
HCI, saf su, H3P04 ve H3BO3 ile aktive edilmiştir. Saf su kullanılarak yıkanan ve 400 oC’de aktive edilen
zeolitin kullanıldığı deneylerde en yüksek adsorpsiyon verimine ulaşılmıştır. Farklı sıcaklıklarda adsorpsiyon
işleminin sonunda elde edilen denge verileri Langmuir, Freundlich, Temkin ve Harkins Jura modellerine
uygulanmış ve model parametreleri hesaplanmıştır. Buna göre adsorpsiyonu en iyi temsil eden modelin
Langmuir olduğu ve adsorpsiyon entalpisinin 12.70 kJ/mol olduğu tespit edilmiştir. PVP ile yapılan deneylerde
de adsorpsiyonu en iyi temsil eden modelin Langmuir olduğu görülmüştür. Adsorbent olarak PVP’nin
kullanıldığı adsorpsiyon işleminde adsorpsiyon entalpisi 14.32 kJ/mol olarak belirlenmiştir.

Keywords

Zeolit, Metilen Mavisi, Adsorpsiyon İzotermi, Termodinamik Parametreler

References

• [1] R.M. Pink, Introduction, Water Rights in Southeast Asia and India, Springer, 2016, pp.1–14
• [2] J.L. Gong, B. Wang, G.M. Zeng, C.P. Yang, C.G. Niu, Q.Y. Niu, W.J. Zhou, Y. Liang, “Removal of cationic dyes from aqueous solution using magnetic multiwall carbon nanotube nanocomposite as adsorbent”, Journal of Hazardous Material, vol. 164, pp. 1517–1522, 2009.
• [3] T. Liu, Y. Li, Q. Du, J. Sun, Y. Jiao, G. Yang, Z. Wang, Y. Xia, W. Zhang, K. Wang, “Adsorption of methylene blue from aqueous solution by graphene”, Colloids Surf. B Biointerf., vol. 90, pp. 197–203, 2012.
• [4] P.O. Boamah, Y. Huang, M. Hua, Q. Zhang, J. Wu, J. Onumah, L.K. Sam-Amoah, P.O. Boamah, “Sorption of heavy metal ions onto carboxylate chitosan derivatives—a mini-review”, Ecotoxicol. Environ. Saf., vol.116, pp.113–120, 2015.
• [5] S.P.D.M. Blanco, F.B. Scheufele, A.N. Modenes, F.R.E. Qui nones, P. Marin, A.D. Kroumov, C.E. Borba, “Kinetic, equilibrium and thermodynamic phenomenological modeling of reactive dye adsorption onto polymeric adsorbet”, Chem. Eng. Journal, vol. 307, pp. 466-475, 2017.
• [6] M.A. Badawi, N.A. Negm, M.T.H. Abou Kana, H.H. Hefni, M.M. Abdel Moneem, “Adsorption of aluminum and lead from wastewater by chitosan-tannic acid modified biopolymers: isotherms, kinetics, thermodynamics and process mechanism”, Int. Journal of Biological Macromol. vol. 99 (C), pp.465–476, 2017.
• [7] M. Kobya, Adsorpsiyon Prosesleri, Bölüm 1 ve 6, Gebze İleri Teknoloji Enst., Gebze, Kocaeli, 2001.
• [8] R.S. Juang, F.C. Wu and R.L. Tseng, “The Ability of Activated Clay for the Adsorption of Dyes from Aqueous Solutions”, Environmental Technology, vol.18, no. 5, pp. 525- 531, 1997.
• [9] C. Qin, R. Wang, W. Ma,” Adsorption kinetic studies of calcium ions onto Ca-selective zeolite”, Desalination, vol. 259, pp. 156–160, 2010.
• [10] Z. Xue, Z. Li, J. Ma, X. Bai, Y. Kang, W. Ho, R. Li, “Effective removal of Mg2+ and Ca2+ ions by mesoporous LTA zeolite”, Desalination, vol.341, pp.10–18, 2014.
• [11] M. Alouani, S. Alehyen, M. Achouri, M. Taibi, “Removal of Cationic Dye–methylene Bluefrom Aqueous Solution by Adsorption on Fly Ash-based Geopolymer”, Journal of Mater. Environ. Science, vol. 9, no 1, pp. 32-46, 2018.
• [12] K. Rida, S. Bouraoui, S. Hadnine, “Adsorption of methylene blue from aqueous solution by kaolin and zeolite”, Applied. Clay Science, vol.83–84, pp. 99–105, 2013.
• [13] F. Gönen, D.S. Serin, “Adsorption study on orange peel: removal of Ni (II) ions from aqueous solution”, Afr. Journal Biotechnology, vol. 11, no.5, pp.1250–1258, 2012.
• [14] E. Demirbas, N. Dizge, M.T. Sulak, M. Kobya, “Adsorption kinetics and equilibrium of copper from aqueous solutions using hazelnut shell activated carbon”, Chemical Engineering Journal, vol. 148, no. 2–3, pp. 480-487, 2009.
• [15] P.K. Malik, “Use of activated carbons prepared from sawdust and rice-husk for adsorption of acid dyes: a case study of Acid Yellow 36”, Dyes and Pigments, vol. 56, pp. 239–249, 2003.
• [16] Z. Huang, Y. Li, W. Chen, J. Shi, N. Zhang, X. Wang, Z. Li, L. Gao, Y. Zhang, “Modified bentonite adsorption of organic pollutants of dye wastewater”, Materials Chemistry and Physics, vol. 202, pp.266-276, 2017.
• [17] V. Meshko, L. Markovska, M. Mincheva, and A.E. Rodrigues, “Adsorption of basic dyes on granular acivated carbon and natural zeolite”, Water Research, vol. 35, no.14, pp. 3357-3366, 2001.
• [18] B. Armağan, O. Özdemir, M. Turan, M.S. Çelik, “The removal of reactive azo dyes by natural and modified zeolites”, Journal of Chemical Technology and Biotechnology, vol.78, no.7, pp.725-732, 2003.
• [19] B. Kırcı, A. Güner, “Effect of phenolic cosolutes on the main parameters, phase separation and theta temperature of dilute aqueous poly(N-vinyl-2- pyrrolidone) solutions”, European Polymer Journal, vol.37, no.2, pp. 361–365, 2001.
• [20] C. Yang, L. Lei, P. Zhou, Z. Zhang, Z. Lei, “Preparation and characterization of poly(AA coPVP)/PGS composite and its application for methylene blue adsorption”, Journal of Colloid and Interface Science, vol.443, pp.97–104, 2015.
• [21] M. Javadi, Y. Jafarzadeh, R. Yegani, S. Kazemi, “PVDF membranes embedded with PVP functionalized nanodiamond for pharmaceutical wastewater treatment”, Chemical Engineering Research and Design, vol.140, pp. 241-250, 2018.
• [22] M.M. Younes, I.I. El-sharkawy, A. Kabeel, K. Uddin, B.B. Saha,” Synthesis and characterization of silica gel composite with polymer binders for adsorption cooling applications”, International Journal of Refrigeration, vol. 98, pp. 161-170, 2019.
• [23] C.-X. Yang, L. Lei, P.-X. Zhou, Z. Zhang, Z.-Q. Lei, “Preparation and characterization of poly(AA co PVP)/PGS composite and its application for methylene blue adsorption”, Journal of Colloid and Interface Science, vol. 443, pp. 97–104. 2015.
• [24] G. Crini, F. Gimbert, C. Robert, B. Martel, O. Adam, N. Morin-Crini, F. De Giorgi, P.M. Badot, “The removali Basic Blue 3 from aqueous solutions by chitosan-based adsorbent: Batch studies”, Journal of Hazardous Materials, vol.153, pp. 96-106, 2008.
• [25] N. Özdemir, M. Bağrıaçık, M. Yılgın, A. Biçer, F. Kar, “Aktifleştirilmiş doğal zeolit ile sulu çözeltilerden metilen mavisinin adsorplanması”, 10.Ulusal Kimya Müh. Kongresi, Koç Üniversitesi, İstanbul, 2012.
• [26] D. A. Bal, M. Yılgın, M. Ural, H. Akçin, A. Mergen, “Hydrothermal and Thermal Treatment of Natural Clinoptilolite Zeolite from Bigadiç”, Geochemistry International, vol. 51, no.6, pp. 495-504, 2013.
• [27] K. Chongrak, H. Eric, A. Noureddine, P.G. Jean, “Application of methylene blue adsorption to cotton fiber specific surface area measurement: Part I. Methodology”, The Journal of Cotton Science, vol. 2, pp.164-173, 1998.
• [28] R. Hazzaa, M. Hussein, “Adsorption of cationic dye from aqueous solution onto activated carbon prepared from olive Stones”, Environmental Technology & Innovation, vol. 4, pp. 36–51, 2015.
• [29] K. Okiel, M. El-Sayed, M.Y. El-Kady, “Treatment of oil–water emulsions by adsorption onto activated carbon, bentonite and deposited carbon”, Egyptian Journal of Petroleum, vol. 20, pp. 9–15, 2011.
• [30] M.J. Temkin, V., Pyzhev, “Recent modifications to Langmuir isotherms”, Acta Physiochim, USSR, vol. 12, pp. 217-222, 1940.
• [31] M.Y. Abdelnaeim, I.Y. El Sherif, A.A. Attia, N.A. Fathy, M.F. El-Shahat, “Impact of chemical activation on the adsorption performance of common reed towards Cu(II) and Cd(II)”, International Journal of Miner. Process., vol. 157, pp. 80–88, 2016.
• [32] J. Liu, X. Wang, “Novel silica-based hybrid adsorbents: lead(II) adsorption isotherms”, Science World Journal, vol. 2013, Article ID. 897159, 2013.
• [33] G. Crini, “Studies of adsorption of dyes on beta-cyclodextrin polymer”, Bioresource Technology, vol. 90, pp. 193-198, 2003.
• [34] E. Demirbaş, M.Z. Nas, “Batch kinetic and equilibrium studies of adsorption of Reactive Blue 21 by fly ash and sepiolite”, Desalination, vol. 243, pp. 8-21, 2009.
• [35] O. Abdelwahab, A.El. Nemr, A.El. Sikaily, A. Khaled, “Use of rice husk for adsorption of direct dyes from aqueous solution: a case study of Direct F. Scarlet”, Egypt. Journal of Aquat. Res. vol. 31, pp. 1–11, 2005.
• [36] F.D. Ardejani, Kh. Badii, N.Y. Limaee, N.M. Mahmoodi, M. Arami, S.Z. Shafaei, A.R. Mirhabibi, “Numerical modelling and laboratory studies on the removal of Direct Red 23 and Direct Red 80 dyes from textile effluents using orange peel, a low-cost adsorbent”. Dyes Pigm, vol. 73, pp. 178–185, 2007.
• [37] A. Hebeish, M.A. Ramadan, E. Abdel-Halim, A. Abo-Okeil, “An effective adsorbent based on sawdust for removal of direct dye from aqueous solutions”, Clean Technol. Environ. Policy, vol.13, pp. 713– 718, 2011.
• [38] S. Tunali Akar, A. Gorgulu, T. Akar, S. Celik,” Decolorization of Reactive Blue 49 contaminated solutions by Capsicum annuum seeds: Batch and continuous mode biosorption applications”, Chemical Engineering Journal, vol. 168, pp. 125–133, 2011.
• [39] W. Wang, Application of activated carbon derived from ‘waste’ bamboo culms for the adsorption of azo disperse dye: Kinetic, equilibrium and thermodynamic studies, Journal of Environmental Management, vol.10, pp.79-87, 2012.
• [40] C.H. Giles, T.H. McEven, S.N. Nakuwa, D. Smith, “Studie in adsorption, Part: XI”, Journal of Cehemical Society, vol.4, pp.3973-3993, 1960.