Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu

Sevim Demirözü Şenol; Melike İmamoğlu

doi:10.29130/dubited.816181

Research Article

Synthesis and Characterization of Pr3+doped ZnO Nanoparticles by Hydrothermal Method

Year 2021, , 393 - 405, 29.05.2021

Sevim Demirözü Şenol , Melike İmamoğlu

https://doi.org/10.29130/dubited.816181

Abstract

In this study, Pr dopedZnO [Zn1-x PrxO (where x = 0.01,0.02,0.03,0.04,0.05)] nanoparticles with praseodymium (Pr3+) doped were synthesized by hydrothermal technique. The hydrothermal technique for the preparation of Pr doped ZnO nanostructures at different concentrationsis to an easy, fast and efficient method. The crystal structures, crystal morphologies and optical properties of synthesized nanoparticles were characterized by X-ray diffraction (XRD), Energy dispersive X-ray (EDX), surface morphology scanning electronmicroscope (SEM) and DiffusereflactanceUV-VIS spectroscopy.XRD studies showed that all Pr doped ZnO samples had hexagona lcrystal structure and Pr3+ ions were successfully incorporated into ZnO nanostructures, and there were nopeaks of Pr or praseodymiumoxide diffraction peaks in the pattern. From the SEM images, it was seen that ZnO becomes denser and more compact as the Pr concentrationin creases in the crystal structure. In the EDX results, the presence of Zn, O and Pr peaks in the composition of the synthesized samples were detected. Energy band gaps were calculated from the optical measurements of all samples and it was observed that the calculated energy band gap values increased with the praseodymium concentration.

Keywords

Zincoxide, Hydrothermal method, Optical properties, DRS_UV-VIS

References

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Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu

Year 2021, , 393 - 405, 29.05.2021

Sevim Demirözü Şenol , Melike İmamoğlu

https://doi.org/10.29130/dubited.816181

Abstract

Bu çalışmada Praseodimyum(Pr3+) katkılı ZnO [Zn1-xPrxO(x=0.01,0.02,0.03,0.04,0.05)] nanoparçacıklar kolay, hızlı ve verimli bir yöntem olan hidrotermal yöntem ile sentezlenmiştir. Sentezlenen nanoparçacıkların, kristal yapıları X-ışını kırınımıyla (XRD), yüzey morfolojileri taramalı elektron mikroskobu (SEM) ve enerji dağıtıcı X-ışını dağılımlarıyla (EDX), optik özellikleri ise dağılma yansıma (DRS UV-VIS) spektroskopisi kullanılarak karakterize edilmiştir. XRD karakterizasyonunda tüm Pr3+katkılı ZnO örneklerinin hekzagonal (wurzite) yapıda oluştuğu, praseodimyum veya praseodimyumoksit’e ait herhangi bir kırınım pikinin oluşmadığı gözlemlenmiştir. SEM görüntülerinden ZnO'in kristal yapısında Pr konsantrasyonu arttıkça daha yoğun ve daha kompakt halde olduğu görülmüştür. EDX sonuçlarından ise, sentezlenen örneklerin bileşiminde Zn, O ve Pr piklerinin varlığı tespit edilmiştir. Tüm numunelerin optik ölçümlerinden enerji bant aralıkları hesaplanmış ve hesaplanan enerji bant aralığı değerlerinin, praseodimyum konsantrasyonu ile arttığı görülmüştür.

Keywords

Çinko oksit, Hidrotermal metot, Optik özellikler, DRS_UV-VIS.

References

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[2] D. Kouyate, J. C. R. Haret ve J. Kossanyi “Electroluminescence of rareearths-doped semi conducting zincoxide electrodes: Kinetic aspects of the energy transfer between Sm3+and Eu3+”J. Lumin., c. 55, ss. 209-216,1993.
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[3] Y. Hayashi, H. Narahara, T. Uchida, T. Noguchi ve S. Ibuki, “Photoluminescence of Eu-doped znophosphors,” Jpn. J. Appl. Phys., c. 34, ss. 1878, 1995.
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Primary Language	Turkish
Subjects	Engineering
Journal Section	Articles
Authors	Sevim Demirözü Şenol 0000-0002-5322-963X Melike İmamoğlu This is me 0000-0001-8489-976X
Publication Date	May 29, 2021
Published in Issue	Year 2021

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APA	Demirözü Şenol, S., & İmamoğlu, M. (2021). Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu. Duzce University Journal of Science and Technology, 9(3), 393-405. https://doi.org/10.29130/dubited.816181
AMA	Demirözü Şenol S, İmamoğlu M. Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu. DÜBİTED. May 2021;9(3):393-405. doi:10.29130/dubited.816181
Chicago	Demirözü Şenol, Sevim, and Melike İmamoğlu. “Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi Ve Karakterizasyonu”. Duzce University Journal of Science and Technology 9, no. 3 (May 2021): 393-405. https://doi.org/10.29130/dubited.816181.
EndNote	Demirözü Şenol S, İmamoğlu M (May 1, 2021) Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu. Duzce University Journal of Science and Technology 9 3 393–405.
IEEE	S. Demirözü Şenol and M. İmamoğlu, “Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu”, DÜBİTED, vol. 9, no. 3, pp. 393–405, 2021, doi: 10.29130/dubited.816181.
ISNAD	Demirözü Şenol, Sevim - İmamoğlu, Melike. “Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi Ve Karakterizasyonu”. Duzce University Journal of Science and Technology 9/3 (May 2021), 393-405. https://doi.org/10.29130/dubited.816181.
JAMA	Demirözü Şenol S, İmamoğlu M. Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu. DÜBİTED. 2021;9:393–405.
MLA	Demirözü Şenol, Sevim and Melike İmamoğlu. “Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi Ve Karakterizasyonu”. Duzce University Journal of Science and Technology, vol. 9, no. 3, 2021, pp. 393-05, doi:10.29130/dubited.816181.
Vancouver	Demirözü Şenol S, İmamoğlu M. Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu. DÜBİTED. 2021;9(3):393-405.

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