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CdSeS/ZnS Kuantum Nokta Katkılı 5CB Nematik Sıvı Kristalinde Optik Bant Aralıklarının İncelenmesi

Year 2018, Volume: 6 Issue: 1, 123 - 130, 31.01.2018
https://doi.org/10.29130/dubited.362037

Abstract

Bu çalışmada, CdSeS/ZnS alaşım
kuantum nokta katkılı 5CB (4-pentyl-4′-cyanobiphenyl) nematik sıvı kristal
yapının optik bant aralığı değerleri incelenmiştir. CdSeS/ZnS alaşım kuantum
nokta, 5CB nematik sıvı kristal yapı içerisine ağırlıkça % 0,05, % 0,1 ve % 0,15
oranlarında katkılanarak optik bant aralığı değerleri elde edilmiştir. Deneysel
sonuçlara göre kuantum nokta katkılanmasıyla optik bant aralığı değerlerinin
azaldığı gözlemlenmiştir. Elde edilen sonuçlar, CdSeS/ZnS alaşım kuantum nokta
yapının sıvı kristal tabanlı cihaz uygulamalarında elektro-optik özellikleri
değiştirebilen alternatif bir malzeme olarak kullanılabileceğini
göstermektedir.

References

  • [1] J. Mirzaei, M. Reznikov, T. Hegmann “Quantum Dots As Liquid Crystal Dopants,” Journal of Materials Chemistry, vol. 22, no. 42, pp. 22350-22365, 2012.
  • [2] A. Kumar, A. M. Biradar, “Effect of Cadmium Telluride Quantum Dots on The Dielectric And Electro-Optical Properties Of Ferroelectric Liquid Crystals,” Physical Review E, vol. 83, no. 4, pp. 041708, 2011.
  • [3] P. K. Tripathi, A. Misra, K. Pandey and R. Manohar, “Study on dielectric and optical properties of ZnO doped nematic liquid crystal in low frequency region,” Chem. Commun, vol. 1, pp. 20-26, 2013.
  • [4] E. A. Konshina, I. F. Galin and E. O. Gavrish, “Reversible capacitance change of nematic liquid crystal cell doped with semiconductor CdSe/ZnS quantum dots,” Universal Journal of Materials Science, vol. 2, no. 1, pp. 1-4, 2014.
  • [5] P. Reiss, M. Protiere and L. Li, “Core/shell semiconductor nanocrystals,” small, vol. 5, no. 2, pp. 154-168, 2009.
  • [6] I. Mora-Sero, S. Giménez, F. Fabregat-Santiago, R. Gómez, Q. Shen, T. Toyoda and J. Bisquert, “Recombination in quantum dot sensitized solar cells,” Accounts of chemical research, vol. 42, no. 11, pp. 1848-1857, 2009.
  • [7] A. J. Nozik, M. C. Beard, J. M. Luther, M. Law, R. J. Ellingson, J. C. Johnson, “Semiconductor quantum dots and quantum dot arrays and applications of multiple exciton generation to third-generation photovoltaic solar cells, “Chemical reviews, vol. 110, no. 11, pp. 6873-6890, 2010.
  • [8] B. A. Kairdolf, A. M. Smith, T. H. Stokes, M. D. Wang, A. N. Young and S. Nie, “Semiconductor quantum dots for bioimaging and biodiagnostic applications,” Annual Review of Analytical Chemistry, vol. 6, pp. 143-162, 2013.
  • [9] O. Köysal, “Azo boya ve fulleren (C60) katkılı nematik sıvı kristallerin elektro-optik özelliklerinin incelenmesi,” Doktora tezi, Fizik Bölümü, Gebze Yüksek Teknoloji Enstitüsü, Kocaeli, Türkiye, 2007.
  • [10] G. Pathak, S. Pandey, R. Katiyar, A. Srivastava, R. Dabrowski, K. Garbat, R. Manohar “Analysis of photoluminescence, UV absorbance, optical band gap and threshold voltage of TiO 2 nanoparticles dispersed in high birefringence nematic liquid crystal towards its application in display and photovoltaic devices,” Journal of Luminescence.
  • [11] M. Mishra, R. S. Dabrowski, R. Dhar, “Thermodynamical, optical, electrical and electro-optical studies of a room temperature nematic liquid crystal 4-pentyl-4′-cyanobiphenyl dispersed with barium titanate nanoparticles” Journal of Molecular Liquids, vol. 213, pp. 247-254, 2016.
  • [12] P. R. Supreet, S. Kumar, K. K. Raina, “Effect of dispersion of gold nanoparticles on the optical and electrical properties of discotic liquid crystal,” Liquid Crystals, vol. 41, no. 7, pp. 933-939, 2014.
  • [13] E. B. Barmatov, D. A. Pebalk, M. V. Barmatova, “Influence of silver nanoparticles on the order parameter of liquid crystalline polymers. Liquid crystals,” vol. 33, no. 9, pp.059-1063, 2006.
  • [14] U. B. Singh, M. B. Pandey, R. Dhar, R. Verma, S. Kumar, “Effect of dispersion of CdSe quantum dots on phase transition, electrical and electro-optical properties of 4PP4OB,” Liquid Crystals, vol. 43, no. 8, pp. 1075-1082, 2016.
  • [15] R. Manohar, S. Manohar, V. S. Chandel, “Dielectric behaviour of pure and dye doped nematic liquid crystal BKS/B07,” Materials Sciences and Applications, vol. 2, no. 7, pp. 838, 2011.
  • [16] S. E. Hicks, S. P. Hurley, Y. C. Yang, D. K. Yang, “Electric Polarization Frozen By A Polymer Network İn Nematic Liquid Crystals Soft Matter,” vol. 9, no. 14, pp. 3834-3839, 2013.
  • [17] S. Ilıcan, Y. Çağlar, M. Çağlar, “CdZnS ve ZnO Yarı iletken Filmlerinin Yasak Enerji Aralıkları. Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi,” c. 9, s. 1, ss. 48-54,2005.
  • [18] H. Kızılçaoğlu, K. Gökşen, Y. Köysal, “Amorf Hidrojenlenmiş Karbon İnce Filmlerin Yasak Enerji Bant Aralıklarının Optiksel İncelenmesi,” Düzce Üniversitesi Bilim ve Teknoloji Dergisi, c. 4, s. 1, 2016.
  • [19] T. Şimşek, K. Gökşen, “Çeşitli Gaz Akış Hızı Koşullarında Üretilen Hidrojenlenmiş Amorf Karbon İnce Filmlerin Optik Bant Aralıklarının İncelenmesi,” Düzce Üniversitesi Bilim ve Teknoloji Dergisi (Dübited), c. 5, s. 1. 2017.
  • [20] U. B. Singh, D. Singh, S. Kumar, R. Dhar, M. B. “Pandey The optical properties of quantum dots in anisotropic media. Journal of Molecular Liquids,” vol. 241, pp.1009-1012, 2017.

Investigation of Optical Band Gap of CdSeS/ZnS Quantum Dot Doped 5CB Nematic Liquid Crystals

Year 2018, Volume: 6 Issue: 1, 123 - 130, 31.01.2018
https://doi.org/10.29130/dubited.362037

Abstract

In this study, optical band gap values of 5CB (4-pentyl-4 'cyanobiphenyl) nematic liquid crystal structure doped with CdSeS/ZnS alloyed quantum dots are investigated. The CdSeS/ZnS alloyed quantum dot was doped into the 5CB nematic liquid crystal structure at 0.05, 0.1 and 0.15 % wt/wt and optical band gap values were obtained. According to experimental results, optical band gap values decrease with quantum dot doping. The results show that the CdSeS/ZnS alloyed quantum dots can be alternative materials used in liquid crystal based device applications whose electro-optical properties are able to be easily modified.

References

  • [1] J. Mirzaei, M. Reznikov, T. Hegmann “Quantum Dots As Liquid Crystal Dopants,” Journal of Materials Chemistry, vol. 22, no. 42, pp. 22350-22365, 2012.
  • [2] A. Kumar, A. M. Biradar, “Effect of Cadmium Telluride Quantum Dots on The Dielectric And Electro-Optical Properties Of Ferroelectric Liquid Crystals,” Physical Review E, vol. 83, no. 4, pp. 041708, 2011.
  • [3] P. K. Tripathi, A. Misra, K. Pandey and R. Manohar, “Study on dielectric and optical properties of ZnO doped nematic liquid crystal in low frequency region,” Chem. Commun, vol. 1, pp. 20-26, 2013.
  • [4] E. A. Konshina, I. F. Galin and E. O. Gavrish, “Reversible capacitance change of nematic liquid crystal cell doped with semiconductor CdSe/ZnS quantum dots,” Universal Journal of Materials Science, vol. 2, no. 1, pp. 1-4, 2014.
  • [5] P. Reiss, M. Protiere and L. Li, “Core/shell semiconductor nanocrystals,” small, vol. 5, no. 2, pp. 154-168, 2009.
  • [6] I. Mora-Sero, S. Giménez, F. Fabregat-Santiago, R. Gómez, Q. Shen, T. Toyoda and J. Bisquert, “Recombination in quantum dot sensitized solar cells,” Accounts of chemical research, vol. 42, no. 11, pp. 1848-1857, 2009.
  • [7] A. J. Nozik, M. C. Beard, J. M. Luther, M. Law, R. J. Ellingson, J. C. Johnson, “Semiconductor quantum dots and quantum dot arrays and applications of multiple exciton generation to third-generation photovoltaic solar cells, “Chemical reviews, vol. 110, no. 11, pp. 6873-6890, 2010.
  • [8] B. A. Kairdolf, A. M. Smith, T. H. Stokes, M. D. Wang, A. N. Young and S. Nie, “Semiconductor quantum dots for bioimaging and biodiagnostic applications,” Annual Review of Analytical Chemistry, vol. 6, pp. 143-162, 2013.
  • [9] O. Köysal, “Azo boya ve fulleren (C60) katkılı nematik sıvı kristallerin elektro-optik özelliklerinin incelenmesi,” Doktora tezi, Fizik Bölümü, Gebze Yüksek Teknoloji Enstitüsü, Kocaeli, Türkiye, 2007.
  • [10] G. Pathak, S. Pandey, R. Katiyar, A. Srivastava, R. Dabrowski, K. Garbat, R. Manohar “Analysis of photoluminescence, UV absorbance, optical band gap and threshold voltage of TiO 2 nanoparticles dispersed in high birefringence nematic liquid crystal towards its application in display and photovoltaic devices,” Journal of Luminescence.
  • [11] M. Mishra, R. S. Dabrowski, R. Dhar, “Thermodynamical, optical, electrical and electro-optical studies of a room temperature nematic liquid crystal 4-pentyl-4′-cyanobiphenyl dispersed with barium titanate nanoparticles” Journal of Molecular Liquids, vol. 213, pp. 247-254, 2016.
  • [12] P. R. Supreet, S. Kumar, K. K. Raina, “Effect of dispersion of gold nanoparticles on the optical and electrical properties of discotic liquid crystal,” Liquid Crystals, vol. 41, no. 7, pp. 933-939, 2014.
  • [13] E. B. Barmatov, D. A. Pebalk, M. V. Barmatova, “Influence of silver nanoparticles on the order parameter of liquid crystalline polymers. Liquid crystals,” vol. 33, no. 9, pp.059-1063, 2006.
  • [14] U. B. Singh, M. B. Pandey, R. Dhar, R. Verma, S. Kumar, “Effect of dispersion of CdSe quantum dots on phase transition, electrical and electro-optical properties of 4PP4OB,” Liquid Crystals, vol. 43, no. 8, pp. 1075-1082, 2016.
  • [15] R. Manohar, S. Manohar, V. S. Chandel, “Dielectric behaviour of pure and dye doped nematic liquid crystal BKS/B07,” Materials Sciences and Applications, vol. 2, no. 7, pp. 838, 2011.
  • [16] S. E. Hicks, S. P. Hurley, Y. C. Yang, D. K. Yang, “Electric Polarization Frozen By A Polymer Network İn Nematic Liquid Crystals Soft Matter,” vol. 9, no. 14, pp. 3834-3839, 2013.
  • [17] S. Ilıcan, Y. Çağlar, M. Çağlar, “CdZnS ve ZnO Yarı iletken Filmlerinin Yasak Enerji Aralıkları. Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi,” c. 9, s. 1, ss. 48-54,2005.
  • [18] H. Kızılçaoğlu, K. Gökşen, Y. Köysal, “Amorf Hidrojenlenmiş Karbon İnce Filmlerin Yasak Enerji Bant Aralıklarının Optiksel İncelenmesi,” Düzce Üniversitesi Bilim ve Teknoloji Dergisi, c. 4, s. 1, 2016.
  • [19] T. Şimşek, K. Gökşen, “Çeşitli Gaz Akış Hızı Koşullarında Üretilen Hidrojenlenmiş Amorf Karbon İnce Filmlerin Optik Bant Aralıklarının İncelenmesi,” Düzce Üniversitesi Bilim ve Teknoloji Dergisi (Dübited), c. 5, s. 1. 2017.
  • [20] U. B. Singh, D. Singh, S. Kumar, R. Dhar, M. B. “Pandey The optical properties of quantum dots in anisotropic media. Journal of Molecular Liquids,” vol. 241, pp.1009-1012, 2017.
There are 20 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Articles
Authors

Gülsüm Kocakülah

Kadir Gökşen

Oğuz Köysal

Publication Date January 31, 2018
Published in Issue Year 2018 Volume: 6 Issue: 1

Cite

APA Kocakülah, G., Gökşen, K., & Köysal, O. (2018). CdSeS/ZnS Kuantum Nokta Katkılı 5CB Nematik Sıvı Kristalinde Optik Bant Aralıklarının İncelenmesi. Duzce University Journal of Science and Technology, 6(1), 123-130. https://doi.org/10.29130/dubited.362037
AMA Kocakülah G, Gökşen K, Köysal O. CdSeS/ZnS Kuantum Nokta Katkılı 5CB Nematik Sıvı Kristalinde Optik Bant Aralıklarının İncelenmesi. DUBİTED. January 2018;6(1):123-130. doi:10.29130/dubited.362037
Chicago Kocakülah, Gülsüm, Kadir Gökşen, and Oğuz Köysal. “CdSeS/ZnS Kuantum Nokta Katkılı 5CB Nematik Sıvı Kristalinde Optik Bant Aralıklarının İncelenmesi”. Duzce University Journal of Science and Technology 6, no. 1 (January 2018): 123-30. https://doi.org/10.29130/dubited.362037.
EndNote Kocakülah G, Gökşen K, Köysal O (January 1, 2018) CdSeS/ZnS Kuantum Nokta Katkılı 5CB Nematik Sıvı Kristalinde Optik Bant Aralıklarının İncelenmesi. Duzce University Journal of Science and Technology 6 1 123–130.
IEEE G. Kocakülah, K. Gökşen, and O. Köysal, “CdSeS/ZnS Kuantum Nokta Katkılı 5CB Nematik Sıvı Kristalinde Optik Bant Aralıklarının İncelenmesi”, DUBİTED, vol. 6, no. 1, pp. 123–130, 2018, doi: 10.29130/dubited.362037.
ISNAD Kocakülah, Gülsüm et al. “CdSeS/ZnS Kuantum Nokta Katkılı 5CB Nematik Sıvı Kristalinde Optik Bant Aralıklarının İncelenmesi”. Duzce University Journal of Science and Technology 6/1 (January 2018), 123-130. https://doi.org/10.29130/dubited.362037.
JAMA Kocakülah G, Gökşen K, Köysal O. CdSeS/ZnS Kuantum Nokta Katkılı 5CB Nematik Sıvı Kristalinde Optik Bant Aralıklarının İncelenmesi. DUBİTED. 2018;6:123–130.
MLA Kocakülah, Gülsüm et al. “CdSeS/ZnS Kuantum Nokta Katkılı 5CB Nematik Sıvı Kristalinde Optik Bant Aralıklarının İncelenmesi”. Duzce University Journal of Science and Technology, vol. 6, no. 1, 2018, pp. 123-30, doi:10.29130/dubited.362037.
Vancouver Kocakülah G, Gökşen K, Köysal O. CdSeS/ZnS Kuantum Nokta Katkılı 5CB Nematik Sıvı Kristalinde Optik Bant Aralıklarının İncelenmesi. DUBİTED. 2018;6(1):123-30.