Year 2020, Volume 8 , Issue 2, Pages 1757 - 1770 2020-04-30

Aggregation-Induced Emission Enhancement of N,N′-bis (Salicylidene)-1,3-Propanediamine Schiff Base
N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı

Ece ERGUN [1] , Ümit ERGUN [2]


In this study, aggregation-induced emission enhancement feature of the solutions prepared from N,N'-bis (salicylidene) -1,3-propanediamine Schiff base was investigated. The ligand solution were prepared at different concentrations with two different solvents and water was added to these solutions at varying percentages (1-50%). It was observed that emission wavelength was red-shifted and the fluorescence intensity was enhanced, as the concentration of water increased in 2×10-4 M ethanolic solution of Schiff base. In addition, time-dependent changes in the fluorescence properties of these solutions were investigated. As a result, it has been suggested that Schiff base can be used for qualitative and quantitative determination of water impurity in ethanol. 

Bu çalışmada, N,N'-bis(salisiliden)-1,3-propandiamin Schiff bazından hazırlanan çözeltilerin agregasyon kaynaklı emisyon artış özelliği incelenmiştir. Ligandın iki farklı çözücü ile farklı konsantrasyonlarda çözeltileri hazırlanmış ve bu çözeltilere değişik yüzdelerde (%1-50) su eklenmiştir. Schiff bazının etanol ile hazırlanmış 2×10-4 M’lık çözeltisinde, su derişimi arttıkça emisyon dalgaboyunun kırmızıya kaydığı ve floresans şiddetinin arttığı görülmüştür. Ayrıca, bu çözeltilerin floresans özelliklerinin zamana bağlı olarak değişimi incelenmiştir. Yapılan çalışmalar sonucunda, Schiff bazının, etanol içindeki su safsızlığının kalitatif ve kantitatif olarak belirlenmesinde kullanılabileceği öne sürülmüştür.
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Primary Language tr
Subjects Engineering
Journal Section Articles
Authors

Orcid: 0000-0001-5645-5571
Author: Ece ERGUN (Primary Author)
Institution: Türkiye Atom Enerjisi Kurumu Radyasyon ve Hızlandırıcı Teknolojileri Dairesi Başkanlığı
Country: Turkey


Orcid: 0000-0002-1830-1181
Author: Ümit ERGUN
Institution: DÜZCE ÜNİVERSİTESİ
Country: Turkey


Dates

Publication Date : April 30, 2020

Bibtex @research article { dubited656807, journal = {Düzce Üniversitesi Bilim ve Teknoloji Dergisi}, issn = {}, eissn = {2148-2446}, address = {}, publisher = {Duzce University}, year = {2020}, volume = {8}, pages = {1757 - 1770}, doi = {10.29130/dubited.656807}, title = {N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı}, key = {cite}, author = {Ergun, Ece and Ergun, Ümit} }
APA Ergun, E , Ergun, Ü . (2020). N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı . Düzce Üniversitesi Bilim ve Teknoloji Dergisi , 8 (2) , 1757-1770 . DOI: 10.29130/dubited.656807
MLA Ergun, E , Ergun, Ü . "N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı" . Düzce Üniversitesi Bilim ve Teknoloji Dergisi 8 (2020 ): 1757-1770 <https://dergipark.org.tr/en/pub/dubited/issue/55096/656807>
Chicago Ergun, E , Ergun, Ü . "N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı". Düzce Üniversitesi Bilim ve Teknoloji Dergisi 8 (2020 ): 1757-1770
RIS TY - JOUR T1 - N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı AU - Ece Ergun , Ümit Ergun Y1 - 2020 PY - 2020 N1 - doi: 10.29130/dubited.656807 DO - 10.29130/dubited.656807 T2 - Düzce Üniversitesi Bilim ve Teknoloji Dergisi JF - Journal JO - JOR SP - 1757 EP - 1770 VL - 8 IS - 2 SN - -2148-2446 M3 - doi: 10.29130/dubited.656807 UR - https://doi.org/10.29130/dubited.656807 Y2 - 2020 ER -
EndNote %0 Düzce Üniversitesi Bilim ve Teknoloji Dergisi N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı %A Ece Ergun , Ümit Ergun %T N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı %D 2020 %J Düzce Üniversitesi Bilim ve Teknoloji Dergisi %P -2148-2446 %V 8 %N 2 %R doi: 10.29130/dubited.656807 %U 10.29130/dubited.656807
ISNAD Ergun, Ece , Ergun, Ümit . "N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı". Düzce Üniversitesi Bilim ve Teknoloji Dergisi 8 / 2 (April 2020): 1757-1770 . https://doi.org/10.29130/dubited.656807
AMA Ergun E , Ergun Ü . N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı. DÜBİTED. 2020; 8(2): 1757-1770.
Vancouver Ergun E , Ergun Ü . N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı. Düzce Üniversitesi Bilim ve Teknoloji Dergisi. 2020; 8(2): 1757-1770.