Jelatin/PAAm-tabanlı IPN Hidrojelleri Kullanarak Sulu Çözeltiden Krom (VI) Uzaklaştırmasının Değerlendirmesi

Year 2023, Volume: 11 Issue: 1, 57 - 77, 31.01.2023

Gülen Oytun Akalın

https://doi.org/10.29130/dubited.949714

Abstract

Bu çalışmada, jelatin (G) -poliakrilamid (PAAm) bazlı, maleik asit (MA) içeren iç içe geçen polimer ağı (IPN) hidrojelleri, radikal polimerizasyon kullanılarak hazırlanmıştır. Tam-IPN ve yarı-IPN hidrojeller, çapraz bağlayıcı olarak glutaraldehit ve etilen glikol dimetakrilat (EGDMA) kullanılarak sentezlendi. Hidrojellerin su emiciliği incelendi ve değerler MA ve G ile arttı. Tam IPN ve yarı IPN hidrojellerin kimyasal yapıları Fourier Dönüşümü Kızılötesi Spektroskopisi (FTIR) ile test edildi. Taramalı Elektron Mikroskobu/ Enerji Dağılımlı X-ışını Spektroskopisi (SEM/EDX) kullanılarak morfolojik test yapıldı. Termal özellikler Diferansiyel taramalı kalorimetre (DSC) analizörü ve Termogravimetrik analiz (TGA) ile incelenmiştir. Mekanik analiz, Zwick Universal Test Makinesi ile yapıldı. Tam IPN hidrojelin termal ve mekanik stabiliteleri yarı IPN'den daha yüksekti. Tam-IPN hidrojelinin Krom (VI) iyonu adsorbe etme özelliği üzerindeki adsorpsiyon parametrelerinin (temas süresi, başlangıç besleme konsantrasyonu ve pH) etkinliği de belirlendi. İzotermler Langmuir veya Freundlich denklemleriyle açıklandı. Her iki izotermin sonucuna göre, hidrojel yüzeyinin homojen olduğu ve Krom (VI) adsorpsiyonunun bir tek tabakada meydana geldiği söylenebilir.

Keywords

Poliakrilamid, Jelatin, Hidrojel, Adsorpsiyon, krom (VI), Metal uzaklaştırma

An Assessment of Chromium (VI) Removal from Aqueous Solution Using Gelatin/PAAm-based IPN Hydrogels

Abstract

In this work, gelatin (G)-polyacrylamide (PAAm)-based interpenetrating polymer network (IPN) hydrogels involving maleic acid (MA) was prepared using by radical polymerization. Full-IPN and semi-IPN hydrogels were synthesized by using glutaraldehyde and ethylene glycol dimethacrylate (EGDMA) as a crosslinker. The water absorbency of hydrogels was investigated, and the values increased with MA and G. The chemical structures of full-IPN and semi-IPN hydrogels were tested by Fourier Transform Infrared Spectroscopy (FTIR). Morphological test was done by using Scanning Electron Microscope/ Energy Dispersive X-ray Spectroscopy (SEM/EDX). Thermal properties were examined with Differential scanning calorimeter (DSC) analyzer and Thermogravimetric analysis (TGA). The mechanical analysis was performed with Zwick Universal Testing Machine. Thermal and mechanical stabilities of full-IPN hydrogel was higher than semi-IPN. The efficiency of adsorption parameters (contact time, initial feed concentration, and pH) on Chromium (VI) ion adsorbing property of Full-IPN hydrogel was also determined. Isotherms were explained with the Langmuir or Freundlich equations. According to the results of both isotherms, it can be said that the hydrogel surface was homogeneous, and the adsorption of Chromium (VI) occurred in a monolayer.

Keywords

Polyacrylamide, Gelatin, hydrogel, adsorption, chromium (VI), metal removal

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