Doğu Anadolu'da Gıda Olarak Tüketilen Bazı Türlerin Multi-element Analizi: Bu Türlerin Element İçeriklerinin Karşılaştırılması

Year 2022, , 373 - 382, 30.12.2022

Adil Umaz , Fırat Aydın , Mehmet Fırat , Abdulselam Ertaş

https://doi.org/10.55007/dufed.1205827

Abstract

Bu çalışmada, gıda ve tıbbiamaçlar için kullanılan bazı bitki türlerinin (Arum conophalloides,Arum detruncatum, Ornithogalum narbonense Muscari comosumve Lippia citrodora) multi-element içerikleri indüktif eşleşmiş plazmalı kütle spektrometresi (ICP-MS) ile tayin edilmiştir. Çalışmada kullanılan türler önce mikrodalga çözünürleştirme işleminde derişik nitrik asit ve hidrojen peroksit ilave edilerek yakma işlemi yapılmıştır. Daha sonra elde edilen çözelti son hacim 100 mL olacak şekilde seyreltilmiş ve ICP-MS ile analiz edilmiştir. Aynı cinsin farklı türlerinin element içerikleri birbiriyle karşılaştırılmıştır. Bu cinslere ait türlerin element içerikleri birbirinden farklı olduğu ve bu farlılık ise bitkinin genetik yapısı, coğrafi konum, iklim ve çevre koşullarına bağlı olduğu belirlenmiştir. Ayrıca, bu çalışmada metot validasyon çalışması yapılmıştır.

Keywords

Multi-elementler, Tıbbi ve gıda bitkileri, ICP-MS

Multi-element Analysis of Some Species Consumed as Food in Eastern Anatolia: Comparison of Element Contents of These Species

Abstract

In this study, the multi-element contents of some plant species (Arum conophalloides, Arum detruncatum, Ornithogalum narbonense, Muscari comosumve Lippia citrodora) used for food and medicinal purposes were determined by inductively coupled plasma mass spectrometry (ICP-MS). The species used in the study have first incinerated by adding concentrated nitric acid and hydrogen peroxide in the microwave solubilization process. Later, the obtained solution was diluted to a final volume of 100 mL and analyzed by ICP-MS. Element contents of different species of the same genus have compared with each other. It has been determined that the element contents of the species belonging to these genera are different from each other and this difference depends on the genetic structure of the plant, geographical location, climate and environmental conditions. In addition, method validation studies were carried out in this study.

Keywords

Multi-elements, Medicinal and food plants, ICP-MS

References

• A. Umaz, F. Aydin, M. Firat, ve A. Ertas, “Bazı geofitlerin indüktif eşleşmiş plazmalı kütle spektrometresi (ICP-MS) ile makro ve mikro element analizi,” Dicle Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 10, no. 1, pp. 47–58, 2021.
• E. Yabalak, “Radical scavenging activity and chemical composition of methanolic extract from Arum dioscoridis Sm. var. dioscoridis and determination of its mineral and trace elements,” Journal of the Turkish Chemical Society, Section A: Chemistry, vol. 5, no. 1, pp. 205–218, 2018.
• A. Derakhshanfar, J. Moayedi, M. Vahedi, A. Valizadeh,“Arum conophalloides aqueous extract ınduced hepatotoxicity in rat; Histopathological, Biochemical, and mir-122 Assessments,” Microrna, vol. 9, no. 3, pp. 224-231, 2020.
• Wikipedia. Asparagaceae. (2020). Accessed: Oct. 20, 2022.[Online]. Available: https://en.wikipedia.org/w/index.php?title=Asparagaceae&oldid=951588727
• Y. Kiran, S. M. Pınar, G. Dogan, H. Eroğlu, “A karyomorphological study on the subgenus leopoldia of the genus Muscari growing in Turkey, ”Cytologia, vol. 85, no. 1, pp.79-83, 2020.
• R. Mammadov, P. Ili, O. Dusen,“Phenolic contents and antioxidant properties of Muscari parviflorum Desf,” Journal of the Chemical Society of Pakistan, vol. 34, no. 3, pp. 651-655,2012.
• U. O. Karaguzel, C. F. Ozkan, “Soil and plant relations of some Ornithogalum (Endemic/non endemic) species,” Applied Ecology and Environmental Research, vol. 17, no. 2, pp.3107-3121,2019.
• M. Sabti, K. Sasaki, C. Gadhi, and H. Isoda, “Elucidation of the molecular mechanism underlying lippia citriodora (Lim.)-induced relaxation and anti-depression,” International Journal of Molecular Sciences, vol. 20, no. 14, 2019.
• S. Suna, B. Incedayi, C. E. Tamer, G. Ozcan Sinir, Ö. U. Copur, “Lemon Verbena (Lippia Citriodora Kunth) beverages: Physicochemical properties, contents of total phenolics and minerals, and bioaccessibility of antioxidants,” Italian Journal of Food Science, vol. 31, no. 1, pp.40-53, 2019.
• A. Umaz, F. Aydin, M. Firat, and A. Ertas, “Determination and comparison of element analysis in the species belonging to different families by inductively coupled plasma-mass spectrometry (ICP-MS),” International Journal of Chemistry and Technology, vol. 6, no. 1, pp. 38–46, 2022.
• A. Umaz, F. Aydın, O. Ölmez Tokul, M. Fırat, M. Öztürk, A. Ertaş, İ. Alev Aydın, “Determination and comparison of metal contents in simulated body fluid medium conditions of the plant species by flame atomic absorption spectrometry (FAAS),” Journal of Research in Pharmacy, vol. 25, no. 6, pp. 1281–1294, 2022.
• İ. Yener, “Trace element analysis in some plants species by inductively coupled plasma optical emission spectrometry (ICP-OES),” Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 9, no. 3, pp. 1492–1502, 2019.
• B. Köse, M. Uzun, and N. Saltan, “Heavy metal contents of Melissa which is sold in herbalists,” Indian Journal of Pharmaceutical Education and Research, vol. 51, no. 3, pp. S217–S220, 2017.