Bazı Geofitlerin İndüktif Eşleşmiş Plazmalı Kütle Spektrometresi (ICP-MS) ile Makro ve Mikro Element Analizi

Year 2021, Volume: 10 Issue: 1, 47 - 58, 10.06.2021

Adil Umaz , Fırat Aydın , Mehmet Fırat , Abdulselam Ertaş

Abstract

Bu çalışmada, yenilebilen ve süs bitkisi olarak kullanılan geofit olan Allium kharputense, Allium pseudo ampeloprasum, Allium rhetoreanum, Allium shatakiense, Allium vineale, Eremurus spectabilis, Fritillaria persica ve Tulipa sintenisii türlerinin Na, K, Mg, Fe, Al, Se, Li, Ba, Be, Cu, Co, Cd, Cr, Mn, Ni, Zn, Pb, B, Mo ve Ti elementlerinin metal içeriği ICP-MS ile tayin edilmiştir. Çalışmada kullanılan türlerin toprak üstü kısımlarından oluşan örnekler ICP-MS ile analiz edilmeden önce mikrodalga çözünürleştirme işleminde derişik nitrik asit ve hidrojen peroksit ilave edilerek hazırlanmıştır. Çalışmada kullanılan türlerin metal analiz sonuçlarına göre tüm türler değerlendirildiğinde, A. kharputense türünün Na (3054 mg/kg) ve Ba (52.68 mg/kg), F. persica türünün K (60065 mg/kg), Cu (18.58 mg/kg), Zn (68.14 mg/kg) ve Mo (2.65 mg/kg), T. sintenisii türünün Fe (2285 mg/kg), Cr (8.19 mg/kg), Mn (91.89 mg/kg), Ni (14.82 mg/kg), Pb (3.24 mg/kg), Mg (30505 mg/kg), Al (2556 mg/kg), Ti (183 mg/kg), Se (49.56 mg/kg), Li (2.69 mg/kg), Be (0.05 mg/kg) ve Co (2.58 mg/kg), A. vineale türünün Cd (4.69 mg/kg), E. spectabilis bitkisinin B (255 mg/kg) metal içeriği daha yüksek olduğu belirlenmiştir. A. rhetoreanum, A. shatakiense, A. vineale, E. spectabilis, F. persica ve T. sintenisii türlerinin Cd içeriği WHO’ya göre yüksek bulunurken, Pb içerikleri düşük olduğu tespit edilmiştir.

Keywords

Makro ve mikro elementler, Geofitler, Bazı yenilebilen ve süs bitkileri, ICP-MS

Supporting Institution

Dicle Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi (DUBAP)

Project Number

FEN.19.011

Thanks

Bu araştırma, Dicle Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi Koordinatörlüğünce (DUBAP) FEN.19.011 nolu proje ile desteklenmiştir. Desteklerinden dolayı teşekkür ederiz.

Macro and Micro Element Analysis of Some Geophytes by Inductively Coupled Plasma Mass Spectrometry (ICP-MS)

Abstract

In this study, metal contents of Na, K, Mg, Fe, Al, Se, Li, Ba, Be, Cu, Co, Cd, Cr, Mn, Ni, Zn, Pb, B, Mo, and Ti elements of species Allium kharputense, Allium pseudo ampeloprasum, Allium rhetoreanum, Allium shatakiense, Allium vineale, Eremurus spectabilis, Fritillaria persica, and Tulipa sintenisii the geophytes which is edible and used as ornamental plants were determined by ICP-MS. Samples consisting of the above-ground parts of the species used in the study were prepared by adding concentrated nitric acid and hydrogen peroxide in the microwave solubilization process before being analyzed by ICP-MS. When all species are evaluated according to the metal analysis results of the species used in the study, Na (3054 mg/kg) and Ba (52.68 mg/kg) of A. kharputense species, K (60065 mg/kg), Cu (18.58 mg/kg), Zn (68.14 mg/kg) and Mo (2.65 mg/kg) of F. persica species, Fe (2285 mg/kg) Cr (8.19 mg/kg), Mn (91.89 mg/kg), Ni (14.82 mg/kg), Pb (3.24 mg/kg), Mg (30505 mg/kg), Al (2556 mg/kg), Ti (183 mg/kg), Se (49.56 mg/kg), Li (2.69 mg/kg), Be (0.05 mg/kg) and Co ( 2.58 mg/kg) of T. sintenisii species, Cd (4.69 mg/kg) of A. vineale species, B (255 mg/kg) of E. spectabilis species were determined to have higher metal contents. While Cd content of A. rhetoreanum, A. shatakiense, A. vineale, E. spectabilis, F. persica and T. sintenisii species were higher than WHO, Pb contents were found to be low.

Keywords

Macro and micro elements, Geophytes, Some edible and ornamental plants, ICP-MS

Project Number

FEN.19.011

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