Elektro-eğirme Yöntemiyle ÇCKNT Takviye Edilerek Güçlendirilmiş Naylon-6,6 Nanoelyafların Üretimi ve Karakterizasyonu

Year 2017, , 146 - 155, 31.05.2017

Fırat Durmuş , Mürsel Ekrem Gürol Önal

https://doi.org/10.31202/ecjse.306384

Cited By: 1

Abstract

Bu çalışmada ağırlıkça % 1, 3 ve 5 oranlarında çok
cidarlı karbon nanotüp (ÇCKNT) takviyeli/takviyesiz naylon-6,6 (N-6,6)
nanoelyafların üretimi elektro-eğirme metodu kullanılarak gerçekleştirilmiştir.
Üretilen nanoelyafların N-6,6 ve ÇCKNT ile bir araya gelmesi ile oluşan
sistemde meydana gelen kimyasal değişimleri ve etkileşimleri, Termogravimetrik
analiz (TGA) ve Fourier Dönüşümlü Kızılötesi Spektroskopisi (FT-IR) analizleri yapılmıştır.
Ayrıca ÇCKNT takviyeli/takviyesiz N-6,6 nanoelyafların özelliklerini belirlemek
amacıyla taramalı elektron mikroskobu (SEM) görüntüleri de incelenmiştir.

Keywords

Elektro-eğirme, Çok Cidarlı Karbon Nanotüp, Naylon-6, 6, Nanoelyaf

References

• [1] Saçak M. "Polimer kimyasına giriş," Ankara Üniversitesi Yayınları, Yayın, (50), 1998.
• [2] Rajesh JJ, Bijwe J, Tewari US. "Abrasive wear performance of various polyamides," Wear, 252(9-10), 769-76, 2002.
• [3] Zhao LX, Zheng LY, Zhao SG. "Tribological performance of nano-Al2O3 reinforced polyamide 6 composites," Mater Lett, 60(21-22), 2590-3, 2006. [4] Başer İ. "Elyaf bilgisi," Marmara Üniversitesi; 1992.
• [5] Wang M, Wang W, Liu T, Zhang W-D. "Melt rheological properties of nylon 6/multi-walled carbon nanotube composites," Composites Science and Technology, 68(12), 2498-502, 2008.
• [6] Ekrem M, Ataberk N, Avci A, Akdemir A. "Improving electrical and mechanical properties of a conductive nano adhesive," J Adhes Sci Technol, 31(7), 699-712, 2017.
• [7] Njuguna J, Pielichowski K, Alcock JR. "Epoxy-based fibre reinforced nanocomposites," Adv Eng Mater, 9(10), 835-47, 2007.
• [8] Spitalsky Z, Tasis D, Papagelis K, Galiotis C. "Carbon nanotube-polymer composites: Chemistry, processing, mechanical and electrical properties," Progress in Polymer Science, 35(3), 357-401, 2010.
• [9] Coleman JN, Khan U, Gun'ko YK. "Mechanical reinforcement of polymers using carbon nanotubes," Adv Mater, 18(6), 689-706, 2006.
• [10] Duzcukoglu H, Ekinci S, Sahin OS, Avci A, Ekrem M, Unaldi M. "Enhancement of Wear and Friction Characteristics of Epoxy Resin by Multiwalled Carbon Nanotube and Boron Nitride Nanoparticles," Tribol T, 58(4), 635-42, 2015.
• [11] Greiner A, Wendorff JH. "Electrospinning: A fascinating method for the preparation of ultrathin fibres," Angew Chem Int Edit, 46(30), 5670-703, 2007.
• [12] Subbiah T, Bhat GS, Tock RW, Pararneswaran S, Ramkumar SS. "Electrospinning of nanofibers," J Appl Polym Sci, 96(2), 557-69, 2005.
• [13] Zhang J, Lin T, Wang XG. "Electrospun nanofibre toughened carbon/epoxy composites: Effects of polyetherketone cardo (PEK-C) nanofibre diameter and interlayer thickness," Composites Science and Technology, 70(11), 1660-6, 2010.
• [14] Ekrem M. "Fracture Behavior of Epoxy Adhesives Reinforced with Carbon Nanotubes and Polyvinyl Alcohol Nanofibers in Aluminum Joints," PhD Dissertation, Konya: Selcuk University; 2015.
• [15] Sinha M, Das B, Srivastava A, Saxena A. "Study of Electrospun Poly\ acrylonitrile (PAN) and PAN/CNT Composite Nanofibrous Webs," Research Journal of Textile and Apparel, 19(1), 36-45, 2015.
• [16] Hapuarachchi TD, Peijs T. "Multiwalled carbon nanotubes and sepiolite nanoclays as flame retardants for polylactide and its natural fibre reinforced composites," Compos Part a-Appl S, 41(8), 954-63, 2010.
• [17] Abbasi A, Nasef MM, Takeshi M, Faridi-Majidi R. "Electrospinning of nylon-6,6 solutions into nanofibers: Rheology and morphology relationships," Chinese J Polym Sci, 32(6), 793-804, 2014.