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Year 2016, Volume: 3 Issue: 3, 0 - 0, 30.09.2016
https://doi.org/10.31202/ecjse.258566

Abstract

References

  • - Herrmann, W.A. ve Kocher, C. “N-heterocyclic carbenes.” Angew. Chem. Int. Ed. Engi. Cilt,36, 2162-2187, 1997
  • - Garrison, J. C. ve Youngs, W. J. “Ag(I) N-Heterocyclic Carbene Complexes: Synthesis, Structure, and Application” Chem. Rev. Cilt: 105, 3978-4008 3978, 2005
  • - Díez-González S., Marion N. ve Nolan S.P, , “N-heterocyclic carbenes in late transition metal catalysis”, Chemical Reviews, Cilt: 109,3612-3676, ISSN: 0009-2665, 2009
  • - Puneet Kumar, Ashish Thakur, Xin Hong, K. N. Houk, and Janis Louie “Ni(NHC)]-Catalyzed Cycloaddition of Diynes and Tropone: Apparent Enone Cycloaddition Involving an 8π Insertion”, J. Am. Chem. Soc., Cilt: 136 (51), 17844–17851, 2014
  • - Kascatan-Nebioglu, A., Panzner, M. J., Tessier, C. A., Cannon, C.L. ve Youngs, W.J. "N-Heterocyclic carbene-silver complexes: A new class of antibiotics", Coordination Chemistry Reviews , Cilt: 251, 884-895, 2007
  • - Özdemir İ. , Özcan, E. Ö. Günal S. ve Gürbüz N., “Synthesis and Antimicrobial Activity of Novel Ag-N-Heterocyclic Carbene Complexes”, Molecules, 15, 2499-2508, 2010
  • - Haque, R. A., Budagumpi, S., Zulikha, H. Z., Hasanudin, N., Ahamed, M.B.K. ve Abdul Majid, A.M.S. “Silver(I)-N-heterocyclic carbene complexes of nitrile-functionalized imidazol-2-ylidene ligands as anticancer agents”, Inorganic Chemistry Communications, Cilt: 44, 128–133, 2014
  • - S. Balcan, S., Balcan M., ve Çetinkaya, B.,” Poly(l-lactide) initiated by silver N-heterocyclic carbene complexes: synthesis, characterization and properties”, Polymer Bulletin, Cilt: 70, 12, 3475-3485, 2013
  • - Taşcı, Z., Kunduracıoğlu, A., Kani,İ. ve Çetinkaya,B. “A New Application Area for Ag-NHCs: CO2 Fixation Catalyst”, ChemCatChem, Cilt: 4, 1–6, 2012
  • - Türkmen H., Ceyhan N, Karabay Yavaşoğlu, U. N, Ozdemir G, ve Cetinkaya B. ”Synthesis and antimicrobial activities of hexahydroimidazo[1,5-a]pyridinium bromides with varying benzyl substituents.” Eur J Med Chem. Cilt: 46(7), 2895-2900, 2011
  • - Bertrand,B. Stefan, L., Pirrotta ,M., Monchaud D., Bodio, E., Richard ,P., Le Gendre, P. Warmerdam, E., de Jager, M.H., Groothuis, G.M.M., Picquet, M., ve Casini ,A. “Caffeine-Based Gold(I) N‑Heterocyclic Carbenes as Possible Anticancer Agents: Synthesis and Biological Properties” Inorg. Chem. Cilt: 53, 2296−2303, 2014
  • - Kunduracıoğlu, A., Tamer, Ö., Avcı, D., Kani, İ., Atalay, Y. ve Çetinkaya, B. “1-Pentamethylbenzyl-3-nbuthylbenzimidazolesilver(I)bromide complex: Synthesis, characterization and DFT calculations”, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Cilt: 121, 35–45, 2014
  • -Spartan 14, Wavefunction Inc. Irvine CA, USA, 2014
  • - Dhandapani, A., Manivarman, S., Subashchandrabose, S. ve H. Saleem” Molecular structure and vibrational analysis on (E)-1-(3-methyl-2,6-diphenyl piperidin-4-ylidene) semicarbazide” Journal of Molecular Structure, Cilt: 1058, , 41-50, 2014
  • - Dereli, Ö., Erdoğdu,Y. ve Güllüoğlu M.T. “Study on molecular structure and vibrational spectra of (triphenylphosphoranylidene) acetaldehyde using DFT: A combined experimental and quantum chemical approach” Journal of Molecular Structure, Cilt: 1012, 105-112,2012
  • - Karakaş-Sarıkaya, E. ve Dereli, Ö . “Molecular structure and vibrational spectra of 7-Methoxy-4-methylcoumarin by density functional method” Journal of Molecular Structure, Cilt: 1052, 25, 214-220, 2013
  • - Sholl, D.S. ve Steckel, J. A. (Çev: Aydın, S., ve Körözlü, N.) Yoğunluk fonksiyonel teorisi: Pratik bir Giriş, Nobel, 2012
  • - Köksal, F. Ve Köseoğlu, R., Kuantum kimyası, Nobel, 2012
  • - Köksal, F. Ve Köseoğlu, R., Spektroskopi ve lazerlere giriş, Nobel, 2010
  • - Haken, H., ve Wolf, H.C.(Çev: Okur, İ.) Molekül Fiziği ve Kuantum Kimyası, Değişim, 2008
  • - Ramachandran, K.I., Deepa, G. ve Namboori, K. , Computational Chemistry and Molecular Modeling Principles and Applications, Springer, 2008

Fitalimid Fonksiyonel Grup İçeren Yeni Bir Benzimidazol Tuzunun Sentezlenmesi, Yapısal Özelliklerinin Spektroskopik ve Hesapsal Yöntemlerle İncelenmesi

Year 2016, Volume: 3 Issue: 3, 0 - 0, 30.09.2016
https://doi.org/10.31202/ecjse.258566

Abstract

Özet:

 

Yeni sentezlenen N-Heterosiklik Karben tuzu; 1,3-bis (N-(2–etil) ftalimid )-1H–benzimidazol–3-yum bromür, DMF (Dimetil Formamid)’in hem çözücü ve hem de baz olarak kullanıldığı bir reaksiyonla sentezlendi. Bileşiğin FT-IR ve NMR ölçümleri deneysel olarak alındı. SPARTAN 14 Hesapsal kimya paket programı kullanılarak kuantum kimyasal hesaplamalar yapıldı. Bağ uzunlukları ve açıları ile FT-IR ve NMR spektrumları hesaplandı. Hesaplanan ve deneysel spektrumlar karşılaştırıldı.

References

  • - Herrmann, W.A. ve Kocher, C. “N-heterocyclic carbenes.” Angew. Chem. Int. Ed. Engi. Cilt,36, 2162-2187, 1997
  • - Garrison, J. C. ve Youngs, W. J. “Ag(I) N-Heterocyclic Carbene Complexes: Synthesis, Structure, and Application” Chem. Rev. Cilt: 105, 3978-4008 3978, 2005
  • - Díez-González S., Marion N. ve Nolan S.P, , “N-heterocyclic carbenes in late transition metal catalysis”, Chemical Reviews, Cilt: 109,3612-3676, ISSN: 0009-2665, 2009
  • - Puneet Kumar, Ashish Thakur, Xin Hong, K. N. Houk, and Janis Louie “Ni(NHC)]-Catalyzed Cycloaddition of Diynes and Tropone: Apparent Enone Cycloaddition Involving an 8π Insertion”, J. Am. Chem. Soc., Cilt: 136 (51), 17844–17851, 2014
  • - Kascatan-Nebioglu, A., Panzner, M. J., Tessier, C. A., Cannon, C.L. ve Youngs, W.J. "N-Heterocyclic carbene-silver complexes: A new class of antibiotics", Coordination Chemistry Reviews , Cilt: 251, 884-895, 2007
  • - Özdemir İ. , Özcan, E. Ö. Günal S. ve Gürbüz N., “Synthesis and Antimicrobial Activity of Novel Ag-N-Heterocyclic Carbene Complexes”, Molecules, 15, 2499-2508, 2010
  • - Haque, R. A., Budagumpi, S., Zulikha, H. Z., Hasanudin, N., Ahamed, M.B.K. ve Abdul Majid, A.M.S. “Silver(I)-N-heterocyclic carbene complexes of nitrile-functionalized imidazol-2-ylidene ligands as anticancer agents”, Inorganic Chemistry Communications, Cilt: 44, 128–133, 2014
  • - S. Balcan, S., Balcan M., ve Çetinkaya, B.,” Poly(l-lactide) initiated by silver N-heterocyclic carbene complexes: synthesis, characterization and properties”, Polymer Bulletin, Cilt: 70, 12, 3475-3485, 2013
  • - Taşcı, Z., Kunduracıoğlu, A., Kani,İ. ve Çetinkaya,B. “A New Application Area for Ag-NHCs: CO2 Fixation Catalyst”, ChemCatChem, Cilt: 4, 1–6, 2012
  • - Türkmen H., Ceyhan N, Karabay Yavaşoğlu, U. N, Ozdemir G, ve Cetinkaya B. ”Synthesis and antimicrobial activities of hexahydroimidazo[1,5-a]pyridinium bromides with varying benzyl substituents.” Eur J Med Chem. Cilt: 46(7), 2895-2900, 2011
  • - Bertrand,B. Stefan, L., Pirrotta ,M., Monchaud D., Bodio, E., Richard ,P., Le Gendre, P. Warmerdam, E., de Jager, M.H., Groothuis, G.M.M., Picquet, M., ve Casini ,A. “Caffeine-Based Gold(I) N‑Heterocyclic Carbenes as Possible Anticancer Agents: Synthesis and Biological Properties” Inorg. Chem. Cilt: 53, 2296−2303, 2014
  • - Kunduracıoğlu, A., Tamer, Ö., Avcı, D., Kani, İ., Atalay, Y. ve Çetinkaya, B. “1-Pentamethylbenzyl-3-nbuthylbenzimidazolesilver(I)bromide complex: Synthesis, characterization and DFT calculations”, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Cilt: 121, 35–45, 2014
  • -Spartan 14, Wavefunction Inc. Irvine CA, USA, 2014
  • - Dhandapani, A., Manivarman, S., Subashchandrabose, S. ve H. Saleem” Molecular structure and vibrational analysis on (E)-1-(3-methyl-2,6-diphenyl piperidin-4-ylidene) semicarbazide” Journal of Molecular Structure, Cilt: 1058, , 41-50, 2014
  • - Dereli, Ö., Erdoğdu,Y. ve Güllüoğlu M.T. “Study on molecular structure and vibrational spectra of (triphenylphosphoranylidene) acetaldehyde using DFT: A combined experimental and quantum chemical approach” Journal of Molecular Structure, Cilt: 1012, 105-112,2012
  • - Karakaş-Sarıkaya, E. ve Dereli, Ö . “Molecular structure and vibrational spectra of 7-Methoxy-4-methylcoumarin by density functional method” Journal of Molecular Structure, Cilt: 1052, 25, 214-220, 2013
  • - Sholl, D.S. ve Steckel, J. A. (Çev: Aydın, S., ve Körözlü, N.) Yoğunluk fonksiyonel teorisi: Pratik bir Giriş, Nobel, 2012
  • - Köksal, F. Ve Köseoğlu, R., Kuantum kimyası, Nobel, 2012
  • - Köksal, F. Ve Köseoğlu, R., Spektroskopi ve lazerlere giriş, Nobel, 2010
  • - Haken, H., ve Wolf, H.C.(Çev: Okur, İ.) Molekül Fiziği ve Kuantum Kimyası, Değişim, 2008
  • - Ramachandran, K.I., Deepa, G. ve Namboori, K. , Computational Chemistry and Molecular Modeling Principles and Applications, Springer, 2008
There are 21 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Makaleler
Authors

Ahmet Kunduracıoğlu

Publication Date September 30, 2016
Submission Date May 12, 2016
Published in Issue Year 2016 Volume: 3 Issue: 3

Cite

IEEE A. Kunduracıoğlu, “Fitalimid Fonksiyonel Grup İçeren Yeni Bir Benzimidazol Tuzunun Sentezlenmesi, Yapısal Özelliklerinin Spektroskopik ve Hesapsal Yöntemlerle İncelenmesi”, El-Cezeri Journal of Science and Engineering, vol. 3, no. 3, 2016, doi: 10.31202/ecjse.258566.
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