Sulu Çözeltiden Metilen Mavisinin Giderilmesi için ARCFe3O4 Nanokompozitlerinin Sentezlenmesi

Year 2020, Volume: 7 Issue: 2, 667 - 678, 31.05.2020

Kadriye Bozgeyik Atakan Toprak

https://doi.org/10.31202/ecjse.689309

Abstract

Tek basamakta termal yöntem ile elde edilen manyetik (Fe3O4) kömür nanokompozitleri üzerine metilen mavisinin (MB) adsorpsiyonu incelenmiştir. ARCFe3O4 x kompozitleri Fe(NO3)3. 9H2O’ün dört farklı (x = 0.5, 1, 2 ve 3) oran olacak şekilde sentezlenmiştir. Nanokompozitler, taramalı elektron mikroskobu (SEM), X-ışını kırınımı (XRD) ve N2 adsorpsiyonu ile karakterize edilmişlerdir. ARCFe3O4 x kompozitlerinin denge ve hız deneyleri kesikli sistemde gerçekleştirilmiştir. Deneysel denge verileri Langmuir ve Freundlich izoterm modelleri ile karşılaştırılmıştır. Ayrıca nanokompozitlerin/MB pseudo-birinci ve ikinci derece kinetik modellere uygunluğu analiz edilmiştir. Tüm ARCFe3O4 x/MB sistemlerinin pseudo-birinci derece kinetik modeli ile uyumlu olduğu bulunmuştur.

Keywords

Kömür, manyetik nanokompozit, adsorpsiyon izotermleri

Synthesis of ARCFe3O4 Nanocomposites for Removal of Hazardous Dye from Aqueous Media

Abstract

Magnetic (Fe3O4) coal nanocomposites obtained using thermal method in one-step and the removal of methylene blue (MB) was investigated. ARCFe3O4 x composites were synthesized in four different ratios (x = 0.5, 1, 2 and 3) of Fe(NO3)3. 9H2O. The nanocomposites were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and N2 adsorption. Equilibrium and rate experiments of ARCFe3O4 x composites were carried out in batch system. Experimental equilibrium analysis was compared with Langmuir and Freundlich isotherm models. In addition, nanocomposite/MB system has been determined for pseudo-first and second degree kinetic models. It was found that all ARCFe3O4 x/MB systems are compatible with the pseudo-first order kinetic model.

Keywords

Coal; magnetic nanocomposite; adsorption isotherms.

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