Research Article

Conductivity, Dielectric And Modulus Studies Of Methylcellulose-NH4TF Polymer Electrolyte

Volume: 1 Number: 2 December 20, 2018
EN

Conductivity, Dielectric And Modulus Studies Of Methylcellulose-NH4TF Polymer Electrolyte

Abstract

Solid biopolymer electrolyte based on methylcellulose (MC) were prepared with different weight percentage of ammonium triflate (NH4TF) salt via solution casting technique. The film was characterized by impedance spectroscopy to measure its ionic conductivity. Samples with 45% of NH4TF exhibit the highest conductivity of 1.14 x 10-4 S cm-1at ambient. Dielectric data were analysed using complex permittivity and complex electrical modulus for the sample with highest conductivity. Dielectric data proved that the increase in conductivity is mainly due to the increase in number of charge carriers.

Keywords

References

  1. Ariffin N. A., A. S. A. Khiar. 2015. Effect of BMITFSI to the Electrical Properties of Methylcellulose/ Chitosan/ NH4TF Based Polymer Electrolyte. Proc. of SPIE.9668.
  2. Buraidah, M. H., A. K. Arof. 2011. Characterization of Chitosan/PVA Blended Electrolyte Doped with NH4I. Journal of Non-Crystalline Solids, 357:3261-3266.
  3. Buraidah, M. H., L.P. Teo, S.R. Majid, A.K. Arof. 2009. Ionic Conductivity by Correlated Barrier Hopping of NH4I Doped Chitosan Solid Electrolyte. Physica B, 404:1373-1379.
  4. Hafiza, M. N., & Isa, M.I.N., Solid polymer electrolyte production from 2-hydroxyethyl cellulose: Effect of NH4NO3 composition on its structural properties. Carbohydrate Polymers http://dx.doi.org/10.1016/j.carbpol.2017.02.03.
  5. Hamdan K Z, A. S A Khiar. 2014. Conductivity and Dielectric Studies of Methylcellulose/Chitosan- NH4CF3SO3 Polymer Electrolyte. Key Engineering Materials, 594-595: 818-822.
  6. Ibrahim S., S.M. Mohd Yasin, N.M. Nee, R. Ahmad, M.R. Johan. 2011. Conductivity and dielectric behaviour of PEO-based solid nanocomposite polymer electrolytes. Solid State Communications, doi:10.1016/j.ssc.2011.11.037.
  7. Kadir M. F. Z., L.P. Teo, S.R. Majid, A.K. Arof. 2009. Conductivity studies on plasticized PEO/chitosan proton conducting polymer electrolyte, Materials Research Innovations, 13:191-194.
  8. Kaith Balbir S., Reena Sharma, Susheel Kalia and Manpreet S. Bhatti. 2014 Response surface methodology and optimized synthesis of guar gum-based hydrogels with enhanced swelling capacity. Royal Society of Chemistry Advanced 4: 40339.

Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Azwani Sofia Ahmad Khiar This is me
Malaysia

Publication Date

December 20, 2018

Submission Date

April 30, 2018

Acceptance Date

December 16, 2018

Published in Issue

Year 2018 Volume: 1 Number: 2

APA
Mısenan, M. S. B., & Ahmad Khiar, A. S. (2018). Conductivity, Dielectric And Modulus Studies Of Methylcellulose-NH4TF Polymer Electrolyte. Eurasian Journal of Biological and Chemical Sciences, 1(2), 59-62. https://izlik.org/JA29TE88SR
AMA
1.Mısenan MSB, Ahmad Khiar AS. Conductivity, Dielectric And Modulus Studies Of Methylcellulose-NH4TF Polymer Electrolyte. Eurasian J. Bio. Chem. Sci. 2018;1(2):59-62. https://izlik.org/JA29TE88SR
Chicago
Mısenan, Muhammad Syukri Bin, and Azwani Sofia Ahmad Khiar. 2018. “Conductivity, Dielectric And Modulus Studies Of Methylcellulose-NH4TF Polymer Electrolyte”. Eurasian Journal of Biological and Chemical Sciences 1 (2): 59-62. https://izlik.org/JA29TE88SR.
EndNote
Mısenan MSB, Ahmad Khiar AS (December 1, 2018) Conductivity, Dielectric And Modulus Studies Of Methylcellulose-NH4TF Polymer Electrolyte. Eurasian Journal of Biological and Chemical Sciences 1 2 59–62.
IEEE
[1]M. S. B. Mısenan and A. S. Ahmad Khiar, “Conductivity, Dielectric And Modulus Studies Of Methylcellulose-NH4TF Polymer Electrolyte”, Eurasian J. Bio. Chem. Sci., vol. 1, no. 2, pp. 59–62, Dec. 2018, [Online]. Available: https://izlik.org/JA29TE88SR
ISNAD
Mısenan, Muhammad Syukri Bin - Ahmad Khiar, Azwani Sofia. “Conductivity, Dielectric And Modulus Studies Of Methylcellulose-NH4TF Polymer Electrolyte”. Eurasian Journal of Biological and Chemical Sciences 1/2 (December 1, 2018): 59-62. https://izlik.org/JA29TE88SR.
JAMA
1.Mısenan MSB, Ahmad Khiar AS. Conductivity, Dielectric And Modulus Studies Of Methylcellulose-NH4TF Polymer Electrolyte. Eurasian J. Bio. Chem. Sci. 2018;1:59–62.
MLA
Mısenan, Muhammad Syukri Bin, and Azwani Sofia Ahmad Khiar. “Conductivity, Dielectric And Modulus Studies Of Methylcellulose-NH4TF Polymer Electrolyte”. Eurasian Journal of Biological and Chemical Sciences, vol. 1, no. 2, Dec. 2018, pp. 59-62, https://izlik.org/JA29TE88SR.
Vancouver
1.Muhammad Syukri Bin Mısenan, Azwani Sofia Ahmad Khiar. Conductivity, Dielectric And Modulus Studies Of Methylcellulose-NH4TF Polymer Electrolyte. Eurasian J. Bio. Chem. Sci. [Internet]. 2018 Dec. 1;1(2):59-62. Available from: https://izlik.org/JA29TE88SR