TiO2'in Anthra Red B ve Acid Black 194 Boyalı Kamgarn Kumaşlara Etkisi

Abstract

Sol-jel yöntemi ile üretilen nano boyutlu Titanyum dioksit (TiO2), Anthra red B ve Acid black 194 ile boyama öncesi ve sonrası mini ramöz kullanılarak kamgarn kumaşlar üzerine uygulanmıştır. TiO2'in kumaşların kopma mukavemeti, yırtılma mukavemeti, dikiş kayması, hidrofobiklik, haslık ve renk değişimi üzerindeki etkisi, uygulama aşaması dikkate alınarak karşılaştırmalı olarak incelenmiştir. TiO2 uygulamasının kumaşların parlaklığı ve boyanması üzerindeki etkisi, sırasıyla spektrofotometre ve FTIR-ATR kullanılarak ölçülmüştür. TiO2 uygulamasının siyah renkli kumaşlarda parlaklığı arttırdığı, pembe renkli kumaşlarda matlaştırdığı görülmüştür.

Keywords

• Nano Boyutlu TiO2
• Kendi Kendini Temizleyen
• Kamgarn Kumaş
• Sol-Jel Yöntemi
• Boyama

The Effect of TiO2 on Anthra Red B and Acid Black 194 Dyed Worsted Fabrics

Abstract

Nano sized Titanium dioxide (TiO2) produced by sol-gel method was applied on worsted fabrics using mini stenter before and after dyeing with Anthra red B and Acid black 194. The effect of TiO2 on breaking strength, tear strength, seam slippage, hydrophobicity, fastness and color change of the fabrics examined comparatively by considering the application step. The effect of TiO2 application on brightness and dyeing of the fabrics were measured using a spectrophotometer and FTIR-ATR, respectively. It was observed that TiO2 application increased the brightness of the black colored fabrics, while it dulled the pink colored fabrics.

Keywords

• Nanosized TiO2
• Self-Cleaning
• Worsted Fabric
• Sol-Gel Method
• Dyeing

References

1. M. L. Gulrajani, Chapter 12: The Use of Nanotechnology in the Finishing of Technical Textiles, 1st ed., Advances in the Dyeing and Fin¬ishing of Technical Textiles, UK : Woodhead Publishing UK, 2013. https://doi.org/10.1533/9780857097613.2.280
2. C. Zhang, X Cai, and F. Wang. “Preparation and evaluation of the self-cleaning poly (lactic acid) (PLA) film blended with Titanium dioxide (TiO2) nano parti¬cles”, Industria Textila, vol. 67(2), pp. 121-126, 2016. http://revistain¬dustriatextila.ro/images/2016/Textila_nr_2_2016.pdf
3. H. Ozdemir. “Influence of Titanium Dioxide Finish Prepared by Sol-Gel Technique on the Ultraviolet Pro¬tection Characteristics of Cotton/Polyester Blend Fab¬rics Used for Clothing”, Industria Textila, vol. 68(3), pp. 213-220, 2017. https://doi.org/10.35530/IT.068.03.1371
4. I. Zgura, S. Frunza, M. Enculescu, C. Florica and F. Coto¬robai. “Deposition of Titanium Dioxide Lay¬ers Upon Polyester Textile Materials: Checking the Ad¬herence By Ultra-Sonication”, Romanian Journal of Physics, vol. 60(3–4), pp. 488–494, 2014. https://rjp.nipne.ro/2015_60_3-4/RomJPhys.60.p488
5. M. Mori. “Effect of Various Chemical Treatments on Handling of Wool Fabric”, Key Engineering Materi¬als, vol. 671, pp. 3-8, 2015. https://doi.org/10.4028/www.scien¬tific.net/KEM.671.3
6. M. Mirkhan, M. E. Yazdanshenas, R. Khajavi, M. Mirjalili. “The Effects of TiO2 Nanoparticles over Time on The Physical and Mechanical Properties of White Cotton Fabrics and Fabrics Dyed with Reactive Dyes”, Oriental Journal of Chemistry, vol. 32(2), pp. 1187-1192, 2016. http://dx.doi.org/10.13005/ojc/320245
7. T. Harifi, M. Montazer. “Free Carrier Dyeing of Polyester Fabric Using Nano TiO2”, Dyes and Pigments, vol. 97(3), pp. 440-445, 2013. https://doi.org/10.1016/j.dyepig.2013.01.015
8. A. Nazari, M. Mirjalili, N. Nasirizadeh, S. Torabian. “Optimization of Nano TiO2 Pretreatment on Free Acid Dyeing of Wool Using Central Composite Design”, Journal of Industrial and Engineering Chem¬istry, vol. 21, pp. 1068-1076, 2015. https://doi.org/10.1016/j.jiec.2014.05.017

9. Z. J. Xu, H. Liu, L. Zhang, X. Zhang, X. “Hydro¬philicity and Self-Cleaning Property of Kroy-Processed Wool Fabric Coated with TiO2/SiO2 Composite Hydro¬sol Stabilized by BTCA”, Advanced Materials Re¬search, vol. 1096, pp. 89-92. 2015. https://doi.org/10.4028/www.sci¬entific.net/AMR.1096.89
10. A. T. Nateri, S. Zandi, V. Motaghitalab and N. Piri. “The effect of TiO2 nanoparticles on color of cotton fab¬ric dyed with reactive dye”, Pigment & Resin Technol¬ogy, vol. 47(5), pp. 431-439, 2018. https://doi.org/10.1108/PRT-08-2017-0072
11. I. Ahmad, C. W. Kan and Z. Yao. “Reactive Blue-25 dye/TiO2 coated cotton fabrics with self-cleaning and UV blocking properties”, Cellulose, vol 26, 2821-2832, 2019. https://doi.org/10.1007/s10570-019-02279-2
12. L. Frunza, V. F. Cotorobai, M. Enculescu, I. Zgura, C. P. Ganea, M. Birzu, D. Mănăilă-Maximean. “Adsorption, Wicking Behavior and Photodegradation Tests of Rhodamine B Solution Upon Wool Substrates”, Advanced Topics in Optoelectronics, Microelectronics and Nanotechnologies X, 11718W, , Constanta, Romania, August 2020. https://doi.org/10.1117/12.2572130
13. A. M. Al-Etaibi and M. A. El-Apasery. “Nano TiO2 Imparting Multifunctional Performance on Dyed Polyester Fabrics with some Disperse Dyes Using High Temperature Dyeing as an Environmentally Benign Method”, International Journal of Environmental Research and Public Health, vol. 17, pp. 1377, 2020. https://doi.org/10.3390/ijerph17041377
14. H. Kafafy, A. Shahin, H. Mashaly, H. Helmy, and A. Zaher. “Treatment of Cotton and Wool Fabrics with Different Nanoparticles for Multifunctional Properties”, Egyptian Journal of Chemistry, vol. 64(9), pp. 5255-5267, 2021. https://doi.org/10.21608/EJCHEM.2021.72780.3609
15. S. Palamutcu, O. Akman, S. Gulmez, I. Aydın, H. Selcuk. “Functionalization of Wool Blend Fabrics Using TiO2”, UTİB Turkish Textile and Clothing Sector VI. International R&D Brokerage Event, Bursa, 3-4 April 2014.