NiTiHf-based high temperature shape memory alloys

Abstract

Shape memory alloys are metallic smart materials that have been currently used in many industries including biomedical, aerospace, electronics, construction, oil-gas and automobile and their application areas are predicted to be increased in future. Industries such as aerospace, oil-gas and automobile requires high transformation temperatures (>100 oC ) whereas low transformation temperatures are sufficient in biomedical and electronics. Thus, NiTi alloys are not good candidates for high temperature applications due to their low transformation temperatures. In this review, recent developments on research and application of NiTiHf-based high temperature shape memory alloys are discussed. On the other hand, limitations of NiTiHf-based high temperature shape memory alloys and studies to overcome those limitations are commented.

Keywords

• High temperature shape memory alloys,NiTiHf,martensite,phase transformation,smart materials

NiTiHf-tabanlı yüksek sıcaklıklı şekil hafızalı alaşımlar

Öz

Şekil hafızalı alaşımlar metalik akıllı malzemeler olup biyomedikal, havacılık, elektronik, inşaat, petrol ve otomobil dahil olmak üzere bir çok endüstri alanında kullanılmakta ve gelecekte kullanım alanlarının artacağı tahmin edilmektedir. Biyomedikal ve elektronik gibi bazı alanlarda düşük sıcaklıkta gösterilen hafıza özelliği yeterli olmakla birlikte havacılık, petrol ve otomobil uygulamaları için yüksek sıcaklıkta (>100 oC) şekil hafıza özelliği gösteren malzemelere ihtiyaç duyulmaktadır. Bundan dolayı en çok bilinen Nitinol alaşımları yüksek sıcaklık uygulamaları için uygun olmamaktadır. Bu derleme makalesinde yüksek sıcaklık uygulamaları için geliştirilen NiTiHf-tabanlı (Nikel-Titanyum-Hafniyum tabanlı) şekil hafızalı alaşımlar üzerinde yapılan en son araştırmalar ve kullanım alanlarından bahsedilmektedir. NiTiHf-tabanlı yüksek sıcaklıklı şekil hafızalı alaşımların günümüzde yaygın olarak kullanılmasının önündeki engellerden ve bu engellerin ortadan kaldırılması için yapılan çalışmalar hakkında bilgi verilecektir.

Anahtar Kelimeler

• Yüksek sıcaklıklı şekil hafızalı alaşımlar,NiTiHf,martenzit,faz dönüşümü

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