Synthesis and Characterization of Amine Derivative Monomers to be used in Preparing Smart Materials

Abstract

In this study, amine derivative three new monomers forming polymer and metal complex synthesized. As the synthesis reaction, the petasis reaction was chosen. Under optimization conditions, target products (monomer) were obtained without any catalyst and with very high yields. Some parameters, such as temperature, solvent, atmospheric conditions, and substituents, has affected reaction yields.In particular, it observed that the structures containing the electron release substituent were more eager than the compounds containing the electron acceptor and the yield was high. Structural analyses of monomers of the alkylaminophenol class were made with 1H-NMR and 13C-NMR. The synthesized monomers can use as molecular printed polymers in biomolecular recognition. That means to obtain suitable materials for synthesized of target molecules. Therefore, this aspect of the study is important.

Keywords

• Molecular Imprinted Polymers
• Alkylaminophenol
• Petasis Reaction
• smart materials
• monomer

Akıllı Malzemelerin Hazırlanmasında Kullanılacak Amin Türevi Monomerlerin Sentez ve Karakterizasyonu

Öz

Bu çalışmada; polimerleşme ve metal kompleksi oluşturabilme özelliklerine sahip amin türevi; üç yeni monomer sentezlenmiştir.  Sentez reaksiyonu olarak, petasis reaksiyonu seçilmiştir. Uygun optimizasyon koşullarında, herhangi bir katalizör kullanılmadan ve oldukça yüksek verimlerle hedef ürünler(monomer) elde edilmiştir. Reaksiyon verimine; sıcaklık, çözücü, atmosfer koşullarının yanısıra, substitüentlerin de etkili olduğu görülmüştür. Özellikle elektron salıcı substitüent içeren yapıların elektron çekici substitüent içeren bileşiklere göre daha istemli olduğu ve veriminin de yüksek olduğu görülmüştür. Alkilaminofenol bileşik sınıfına ait olan bu monomerlerin yapısal analizleri ise ¹H-NMR ve ¹³C-NMR ile tamamlanmıştır. Sentezi yapılan monomerler, moleküler baskılanmış polimer olarak biyomoleküler tanımada kullanılabilir. Bu durum; bir çok hedef molekül için onları tanıyan uygun materyallerin  elde edilmesi anlamına gelmektedir. Çalışma bu yönüyle oldukça önemlidir. 

Anahtar Kelimeler

• Moleküler Baskılanmış Polimerler
• Alkilaminofenol
• Petasis Reaksiyonu
• Akıllı Malzemeler

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