Year 2021, Volume , Issue 21, Pages 43 - 52 2021-01-31

Orange G’nin Sulu Çözeltilerden Uzaklaştırılması için α-Fe2O3 Nanopartiküllerinin Adsorban Olarak Kullanılması; Adsorpsiyon, Kinetik ve Termodinamik Özellikleri

Hakan KIZILTAŞ [1]


Çevre kirliliğinin en önemli kaynaklarından biri de endüstriyel atık sularıyla çevreye salınan boyarmadde atıklarıdır. Endüstride sıklıkla kullanılan boyalardan biri olan Orange G (OG), hidrotermal yöntemle sentezlenmiş α-Fe2O3 nanopartikülleri yardımıyla adsorpsiyon işlemine tabi tutulmuştur. Sentezlenen α-Fe2O3 nanopartiküllerinin karakterizasyonu SEM-EDS ve XRD analizleri ile belirlenmiştir. Adsorpsiyon çalışmaları için, temas süresinin, pH’ın, başlangıç boya konsantrasyonunun, adsorban miktarının ve sıcaklığın etkisi incelenmiştir. Yapılan denemeler sonucunda optimum dengelenme süresi 180 dakika ve optimum pH değeri 6,5 olarak belirlenmiştir. OG’nin α-Fe2O3 nanopartikülleri üzerinde adsorpsiyonundan elde edilen denge verilerine en uygun izoterm modelinin Freundlich modeli ve en uygun kinetik modelin yalancı ikinci mertebe modeli olduğu bulundu. Langmuir modeli yardımıyla maksimum tek tabakalı adsorpsiyon kapasitesinin 334 mg/g olduğu belirlendi. Termodinamik çalışmalarla, OG’nin α-Fe2O3 nanopartiküllerine adsorpsiyonunun endotermik olduğu, fiziksel adsorpsiyonun meydana geldiği ve adsorpsiyon olayının kendiliğinden gerçekleştiği sonucuna varıldı. Sonuç olarak, α-Fe2O3 nanopartiküllerinin endüstriyel atık olarak çevreye salınan atık sulardaki boyarmaddelerin uzaklaştırılması için büyük bir potansiyele sahip olduğu ortaya konuldu.
α-Fe2O3, Orange G, İzoterm, Kinetik, Termodinamik
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Primary Language tr
Subjects Engineering
Journal Section Articles
Authors

Orcid: 0000-0003-3131-6422
Author: Hakan KIZILTAŞ (Primary Author)
Institution: ATATÜRK ÜNİVERSİTESİ, MÜHENDİSLİK FAKÜLTESİ, KİMYA MÜHENDİSLİĞİ BÖLÜMÜ
Country: Turkey


Dates

Publication Date : January 31, 2021

APA Kızıltaş, H . (2021). Orange G’nin Sulu Çözeltilerden Uzaklaştırılması için α-Fe2O3 Nanopartiküllerinin Adsorban Olarak Kullanılması; Adsorpsiyon, Kinetik ve Termodinamik Özellikleri . Avrupa Bilim ve Teknoloji Dergisi , (21) , 43-52 . DOI: 10.31590/ejosat.798223