SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES

Murat Saracoglu; Fatma Kandemirli; Ayhan Özalp; Zülbiye Kökbudak

EN

SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES

Abstract

The 2,4-dioxopentanoic acid derivatives (3d-f) were obtained from the reaction of 4- acetyl-5-(1-naphthyl)furan-2,3-dione (1) with various nitrogenous nucleophiles (2d-f). The structures of these newly synthesized compounds (3d-f) were determined from the FT-IR, 1H and 13C NMR spectroscopic data and elemental analyses. Theoretical Study of derivatives of (3Z)-3-{2-naphthyl[2- (4-nitrophenyl)hydrazino]methylene}-2,4-dioxopentanoic acid (3d-f) were carried out by using DFT/B3LYP method with basis set of the 6-311G(d,p) in order to find molecular properties by Gaussian 03 program [1](see Schemes 1and 2). According to EHOMO and softness values; electronic give trends for investigated molecules can be written as: 3f>3d>3e.The EHOMO and EHOMO energy gap of a measure of stability. Additionally, according to EHOMO and EHOMO energy gap; stability give trends for investigated molecules can be written as: 3e>3d>3f.

Keywords

Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Murat Saracoglu This is me

Fatma Kandemirli This is me

Ayhan Özalp This is me

Zülbiye Kökbudak This is me

Publication Date

August 1, 2016

Submission Date

August 1, 2016

Acceptance Date

-

Published in Issue

Year 2016 Volume: 12 Number: 2

IZ

https://izlik.org/JA73GC34YN

Cite

RIS / Bibtex

APA

Saracoglu, M., Kandemirli, F., Özalp, A., & Kökbudak, Z. (2016). SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES. Electronic Letters on Science and Engineering, 12(2), 24-25. https://izlik.org/JA73GC34YN

AMA

1.Saracoglu M, Kandemirli F, Özalp A, Kökbudak Z. SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES. Electronic Letters on Science and Engineering. 2016;12(2):24-25. https://izlik.org/JA73GC34YN

Chicago

Saracoglu, Murat, Fatma Kandemirli, Ayhan Özalp, and Zülbiye Kökbudak. 2016. “SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES”. Electronic Letters on Science and Engineering 12 (2): 24-25. https://izlik.org/JA73GC34YN.

EndNote

Saracoglu M, Kandemirli F, Özalp A, Kökbudak Z (August 1, 2016) SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES. Electronic Letters on Science and Engineering 12 2 24–25.

IEEE

[1]M. Saracoglu, F. Kandemirli, A. Özalp, and Z. Kökbudak, “SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES”, Electronic Letters on Science and Engineering, vol. 12, no. 2, pp. 24–25, Aug. 2016, [Online]. Available: https://izlik.org/JA73GC34YN

ISNAD

Saracoglu, Murat - Kandemirli, Fatma - Özalp, Ayhan - Kökbudak, Zülbiye. “SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES”. Electronic Letters on Science and Engineering 12/2 (August 1, 2016): 24-25. https://izlik.org/JA73GC34YN.

JAMA

1.Saracoglu M, Kandemirli F, Özalp A, Kökbudak Z. SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES. Electronic Letters on Science and Engineering. 2016;12:24–25.

MLA

Saracoglu, Murat, et al. “SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES”. Electronic Letters on Science and Engineering, vol. 12, no. 2, Aug. 2016, pp. 24-25, https://izlik.org/JA73GC34YN.

Vancouver

1.Murat Saracoglu, Fatma Kandemirli, Ayhan Özalp, Zülbiye Kökbudak. SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES. Electronic Letters on Science and Engineering [Internet]. 2016 Aug. 1;12(2):24-5. Available from: https://izlik.org/JA73GC34YN