Research Article

Rheology of Iraqi Asphalt Modified with SBS, Polyphosphoric Acid and Sulfur

Number: 4 December 4, 2018
  • Doha Niethal Saad
  • Eman İsmael Ahmed
EN

Rheology of Iraqi Asphalt Modified with SBS, Polyphosphoric Acid and Sulfur

Abstract

Polymer modified asphalts (PMA) became of great interest over the last years because there are closely related to industrial and constructional fields. To increase the elasticity of asphalt, styrene-butadiene-styrene (SBS) type polymers are used which are elastomeric block copolymers. Although the addition of SBS type block copolymers has economic limits and can show serious technical limitations, it is probably the most appropriate polymer for asphalt modification. The present work seeks to identify the changes on the rheological and physical properties of SBS modified with Dora asphalt. So it is the first study using Iraqi asphalt with styrene-butadiene-styrene. In this paper polyphosphoric acid PPA and sulfur were used to improve the high temperature property and storage stability of SBS modified asphalt.PPA can improve the high temperature performance of the SBS modified Dura asphalt evidently but declain the storage stability. Owing to the gelation of PPA, the phase separation of SBS becomes more serious.

Keywords

References

  1. ASTM D 113, (2007), “Standard Test Method for Ductility of Bituminous Materials”, Annual Book of ASTM Standards, V 4.03. ASTM D 36, (2009), “Standard Test Method for Softening Point of Bitumen (Ring-and Ball Apparatus)”, Annual Book Of ASTM Standards, V4.04. ASTM D 4124-09, Standard Test Method for separation of asphalt into four fractions. ASTM D 5, (2006), “Standard Test Method for Penetration of Bituminous Materials”, Annual Book of ASTM Standards, V 4.03. Babashak JF. US Patent 2005101702; 2005. Baumgardner G.L., Masson J.F., Hardee J.R., Menapace A.M., Williams A.G., Polyphosphoric acid modified asphalt: proposed mechanisms, J. Assoc. Asphalt Paving Technol. 74 (2005) 283–305. Holden G, Bisshop ET, Legge NR. Thermoplastic elastomers. J Polym Sci Part C 1969;31:26–8. Jameson R.F., 151. The composition of the ‘‘strong” phosphoric acids, J. Chem. Soc. (Resumed) (1959) 752–759. Lesueur D., The colloidal structure of bitumen: consequences on the rheology and on the mechanisms of bitumen modification, Adv. Colloid Interface Sci. 145 (1) (2009) 42–82. Lu X, Isacsson U. Rheological characterization of styrene–butadiene–styrene copolymer modified bitumens. Constr Build Mater 1997;11:23–32. Maldonado P. US Patent 2005101702 A1; 2005. Masson J.F., Brief review of the chemistry of polyphosphoric acid (PPA) and bitumen, Energy Fuels 22 (4) (2008) 2637–2640. Orange G., Dupuis D., Martin J.V., Farcas F., Such C., Marcant B., Chemical modification of bitumen through polyphosphoric acid: properties-microstructure relationship, in proceedings of the 3rd eurasphalt and eurobitume congress, vienna (vol. 1), May 2004. Peramanu, S. Pruden B.B., Rahimi P., Molecular weight and specific gravity distributions for Athabasca and Cold Lake bitumens and their saturate, aromatic, resin, and asphaltene fractions, Ind. Eng. Chem. Res. 38 (8) (1999) 3121–3130. Pfeiffer J.P., Saal R.N., Asphaltic bitumen as colloid system, J. Phys. Chem. 44 (2) (1940) 139–149. Shuler TS, Collins TH, Kirkpatrick JP. Polymer-modified asphalt properties related to asphalt concrete performance. Asphalt: Relationship to Mixture, ASTM STP 941 Amercian Society for Testing and Materials, Philadelphia; 1987. p. 179–182. Speight J.G., The Chemistry and Technology of Petroleum, CRC Press, 2014. Wang SF, Zhang Y, Zhang YX. SBS/carbon black compounds give asphalts with improved high-temperature storage stability. Polym Polym Compos 2003;11:477–85. Welborn JT. US Patent 4412019A; 1983.

Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Doha Niethal Saad This is me

Eman İsmael Ahmed This is me

Publication Date

December 4, 2018

Submission Date

November 21, 2018

Acceptance Date

-

Published in Issue

Year 2018 Number: 4

APA
Saad, D. N., & Ahmed, E. İ. (2018). Rheology of Iraqi Asphalt Modified with SBS, Polyphosphoric Acid and Sulfur. The Eurasia Proceedings of Science Technology Engineering and Mathematics, 4, 277-280. https://izlik.org/JA65PF77TP