BibTex RIS Cite

Limon kabuğu kullanarak sulu çözeltilerden Cu(II) giderimi

Year 2011, Volume: 27 Issue: 3, 265 - 270, 01.06.2011

Abstract

Bu çalışmada adsorbent olarak limon kabuğu kullanılarak sulu çözeltilerden Cu(II) giderimi araştırılmıştır. Adsorbent olarak kullanılan limon kabuğu üzerine bakırın adsorpsiyonunda 150 devir/dakika karıştırma hızıyla pH=7’de giderim veriminin %83,3 olduğu, en uygun adsorbent dozajının 0,04 g/L olup adsorpsiyon veriminin bu dozajda %95,76 değerine ulaştığı belirlenmiştir. En uygun başlangıç bakır derişiminin ise 400 mg/L olduğu ve adsorpsiyon veriminin bu derişimde en yüksek değerine (%98,3) ulaştığı ayrıca en uygun bekletme süresinin %99 verim ile 120 dakikada gerçekleştiği ve en uygun sıcaklığın ise 250C olduğu tespit edilmiştir.

References

  • Periasamy, K. and Namasivayam, C., ‘Removal of copper(II) by adsorption onto peanut hull carbon from water and copper plating industry wastewater’, Chemosphere, 32, 769-789, 1996.
  • Aman T., Kazi A.A, Sabri M. U., Bano Q., ‘Potato peels as solid waste for the removal of heavy metal copper (II) from waste water/industrial effluent’ Colloids and Surfaces B: Biointerfaces 63, 116–121, 2008.
  • Aksu, Z., Kutsal, T., "Atık Sulardaki Kurşun(II), Krom(VI) ve Bakır(II) İyonlarının Yeşil Alglerden Chlorella vulgaris'e Adsorbsiyonunun Karıştırmalı ve Akışkan Yatak Reaktörlerde İncelenmesi", Türk Mühendislik ve Çevre Bilimleri Dergisi, 18, p. 403-410, 1994.
  • Benaissa, H. and Benguella, B. Effect of anions and cations on cadmium sorption kinetics from aqueous solutions by chitin: experimental studies and modeling, Environ. Pollut. 130, 157–163, 2004.
  • Aksu, Z. ve Donmez, G. Binary biosorption of cadmium(II) and nickel(II) onto dried Chlorella vulgaris: co-ion effect on mono-component isotherm parameters, Proc. Biochem. 41, 860–868, 2006.
  • Jiang Y., Pang H. and Liao B., ‘Removal of copper(II) ions from aqueous solution by modified bagasse’, Journal of Hazardous Materials 164, 1–9, 2009.
  • Ajmal, M., Khan, A.H. and Ahmad, S. Role of sawdust in the removal of copper(II) from industrial wastes, Water Resource, 32, 3085–3091, 1998.
  • Pan, S.C., Lin, C.C. and Pan, D.H.T. Reusing sewage sludge ash as adsorbent for copper removal from wastewater. Resources, Conservation and Recycling 39, 79-90, 2003.
  • Veglio, F., Beolchini, F. And Prisciandaro M. Sorption of copper by olive mill residues. Water Research. 37, 4895-4903, 2003.
  • Subramaniam, K. and Yiocoumi, S. Modeling kinetics of copper uptake by inorganic colloids under high surface coverage conditions Colloids Surf. 191, 145-159, 2001.
  • Lopez-Delgado, A.,Perez, C. and Lopez, F.A. Sorption of heavy metals on blast furnace sludge. Water Research. 32 , 989-996, 1998.
  • Goyal, M., Rattan, V.K., Aggarwal, D. and Bansal, R.C. Removal of copper from aqueous solutions by adsorption on activared carbon, Colloids and Surfaces, 190, 229- 238, 2001.
  • 13.Anonymous, http://tr.wikipedia.org/wiki/Limon_(a%C4%9Fa%C3%A 7), 2010.
  • Kumar, K. V. and Porkodi, K. ‘Relation between some two- and three-parameter isotherm models for the sorption of methylene blue onto lemon peel Journal of Hazardous Materials, 138(3), 633-635, 2006.
  • Ververis, C., Georghiou, K., Danielidis, D.,
  • Hatzinikolaou, D.G., Santas, P., Santas, R. and Corleti,
  • V. ‘Cellulose, hemicelluloses, lignin and ash content of
  • some organic materials and their suitability for use as
  • paper pulp supplements’, Bioresource Technology, 98, 296-301, 2007.
  • Arslanoglu, H., Altundoğan H.S., Tumen,F., ‘Preparation of cation exchanger from lemon and sorption of divalent heavy metals’ Bioresource Technology, 99, 2699–2705, 2008.
  • El-Helow, E.R and El-Ahawany, M.A.,’ Lichenase production by catabolite repression-resistant Bacillus subtilis mutants: Optimization and formulation of an agro-industrial by-product medium’, Enzyme and Microbial Technology, 24:325–331, 1999.
  • Bhatnagar, A.K. and Minocha, M.S.’ Adsorptive removal of cobalt from aqueous solution by utilizing lemon peel as biosorbent’ .Biochemical Engineering Journal 48, 181–186, 2010.
  • Arslanoglu, H., Altundogan, H.S. and Tumen, F. ‘Heavy metals binding properties of esterified lemon’. Journal of Hazardous Materials, 164, 1406–1413, 2009.
  • El-Ashtoukhya, S.Z., Amina, N.K., Abdelwahabb, O. ‘Removal of lead (II) and copper (II) from aqueous solution using pomegranate peel as a new adsorbent’ Desalination, 223, 162–173, 2008.
  • Qian, Q., Mochidzuki, K., Fujii, T. and Sakoda, A. ‘Removal of copper from aqueous solution using iron- containing adsorbents derived from methane fermentation sludge.’ Journal of Hazardous Materials, 172, 1137–1144, 2009.
  • Aydın, H., Buluta, Y. and Yerlikaya Ç. ‘Removal of copper (II) from aqueous solution by adsorption onto low-cost adsorbents’. Journal of Environmental Management, 87, 37–45, 2008.
  • Wang, S., Lin, L. and Zhu, Z.H. ‘Solid-state conversion of fly ash to effective adsorbents for Cu removal from wastewater’. Journal of Hazardous Materials, B (139), 254-259, 2007.
  • Amarasinghe, B.M.W.P.K. and Williams, R.A. ‘Tea waste as a low cost adsorbent for the removal of Cu and Pb from wastewater, Chemical Engineering Journal, 132, 299-309, 2007.
  • Ding, S., Sun, Y., Yang, C. and Xu, B. ‘Removal of copper from aqueous solutions by bentonites and the factors affecting it.’ Mining Science and Technology, 19, 489-492, 2009.
  • Demirbaş, Ö., Karadağ, A., Alkan, M. ve Doğan, M. ‘Removal of copper ions from aqueous solutions by hazelnut shell’, Journal of Hazardous Materials, 153, 677-684, 2008.
  • Singh, V., Pandey, S., Singh, S. K. and Sanghi, R.’ Removal of cadmium from aqueous solutions by adsorption using poly (acyrlamide) modified guar gum- silica nanocomposites.’ Seperation and Purification Technology, 67, 251-261, 2009.
  • Akar, S.T. ve Uysal, R.’Untreated clay with high adsorption capacity for effective removal of C.I. Acid Red 88 from aqueous solutions: Batch and dynamic flow mode studies’ Chemical Engineering Journal, 162, 591- 598, 2010.

Removal of Cu(II) from aqueous solutions by using lemon peel

Year 2011, Volume: 27 Issue: 3, 265 - 270, 01.06.2011

Abstract

In this study removal of Cu(II) from aqueous solutions by using lemon peel was investigated. When limon peel was used as an adsorbent removal efficiency of Cu(II) was determined to be 83.3% at 150 rpm stirring speed and pH=7; optimum dosage of adsorbent was 0.04 g/L and adsorption efficiency at this dose was determined to be 95.76% .The optimum initial concentration of copper was 400 mg/L and at this concentration the adsorption efficiency reached the highest value (98.3%). Also 99% removal efficiency was reached when retention time was 120 minutes and temperature of 25 0C.

References

  • Periasamy, K. and Namasivayam, C., ‘Removal of copper(II) by adsorption onto peanut hull carbon from water and copper plating industry wastewater’, Chemosphere, 32, 769-789, 1996.
  • Aman T., Kazi A.A, Sabri M. U., Bano Q., ‘Potato peels as solid waste for the removal of heavy metal copper (II) from waste water/industrial effluent’ Colloids and Surfaces B: Biointerfaces 63, 116–121, 2008.
  • Aksu, Z., Kutsal, T., "Atık Sulardaki Kurşun(II), Krom(VI) ve Bakır(II) İyonlarının Yeşil Alglerden Chlorella vulgaris'e Adsorbsiyonunun Karıştırmalı ve Akışkan Yatak Reaktörlerde İncelenmesi", Türk Mühendislik ve Çevre Bilimleri Dergisi, 18, p. 403-410, 1994.
  • Benaissa, H. and Benguella, B. Effect of anions and cations on cadmium sorption kinetics from aqueous solutions by chitin: experimental studies and modeling, Environ. Pollut. 130, 157–163, 2004.
  • Aksu, Z. ve Donmez, G. Binary biosorption of cadmium(II) and nickel(II) onto dried Chlorella vulgaris: co-ion effect on mono-component isotherm parameters, Proc. Biochem. 41, 860–868, 2006.
  • Jiang Y., Pang H. and Liao B., ‘Removal of copper(II) ions from aqueous solution by modified bagasse’, Journal of Hazardous Materials 164, 1–9, 2009.
  • Ajmal, M., Khan, A.H. and Ahmad, S. Role of sawdust in the removal of copper(II) from industrial wastes, Water Resource, 32, 3085–3091, 1998.
  • Pan, S.C., Lin, C.C. and Pan, D.H.T. Reusing sewage sludge ash as adsorbent for copper removal from wastewater. Resources, Conservation and Recycling 39, 79-90, 2003.
  • Veglio, F., Beolchini, F. And Prisciandaro M. Sorption of copper by olive mill residues. Water Research. 37, 4895-4903, 2003.
  • Subramaniam, K. and Yiocoumi, S. Modeling kinetics of copper uptake by inorganic colloids under high surface coverage conditions Colloids Surf. 191, 145-159, 2001.
  • Lopez-Delgado, A.,Perez, C. and Lopez, F.A. Sorption of heavy metals on blast furnace sludge. Water Research. 32 , 989-996, 1998.
  • Goyal, M., Rattan, V.K., Aggarwal, D. and Bansal, R.C. Removal of copper from aqueous solutions by adsorption on activared carbon, Colloids and Surfaces, 190, 229- 238, 2001.
  • 13.Anonymous, http://tr.wikipedia.org/wiki/Limon_(a%C4%9Fa%C3%A 7), 2010.
  • Kumar, K. V. and Porkodi, K. ‘Relation between some two- and three-parameter isotherm models for the sorption of methylene blue onto lemon peel Journal of Hazardous Materials, 138(3), 633-635, 2006.
  • Ververis, C., Georghiou, K., Danielidis, D.,
  • Hatzinikolaou, D.G., Santas, P., Santas, R. and Corleti,
  • V. ‘Cellulose, hemicelluloses, lignin and ash content of
  • some organic materials and their suitability for use as
  • paper pulp supplements’, Bioresource Technology, 98, 296-301, 2007.
  • Arslanoglu, H., Altundoğan H.S., Tumen,F., ‘Preparation of cation exchanger from lemon and sorption of divalent heavy metals’ Bioresource Technology, 99, 2699–2705, 2008.
  • El-Helow, E.R and El-Ahawany, M.A.,’ Lichenase production by catabolite repression-resistant Bacillus subtilis mutants: Optimization and formulation of an agro-industrial by-product medium’, Enzyme and Microbial Technology, 24:325–331, 1999.
  • Bhatnagar, A.K. and Minocha, M.S.’ Adsorptive removal of cobalt from aqueous solution by utilizing lemon peel as biosorbent’ .Biochemical Engineering Journal 48, 181–186, 2010.
  • Arslanoglu, H., Altundogan, H.S. and Tumen, F. ‘Heavy metals binding properties of esterified lemon’. Journal of Hazardous Materials, 164, 1406–1413, 2009.
  • El-Ashtoukhya, S.Z., Amina, N.K., Abdelwahabb, O. ‘Removal of lead (II) and copper (II) from aqueous solution using pomegranate peel as a new adsorbent’ Desalination, 223, 162–173, 2008.
  • Qian, Q., Mochidzuki, K., Fujii, T. and Sakoda, A. ‘Removal of copper from aqueous solution using iron- containing adsorbents derived from methane fermentation sludge.’ Journal of Hazardous Materials, 172, 1137–1144, 2009.
  • Aydın, H., Buluta, Y. and Yerlikaya Ç. ‘Removal of copper (II) from aqueous solution by adsorption onto low-cost adsorbents’. Journal of Environmental Management, 87, 37–45, 2008.
  • Wang, S., Lin, L. and Zhu, Z.H. ‘Solid-state conversion of fly ash to effective adsorbents for Cu removal from wastewater’. Journal of Hazardous Materials, B (139), 254-259, 2007.
  • Amarasinghe, B.M.W.P.K. and Williams, R.A. ‘Tea waste as a low cost adsorbent for the removal of Cu and Pb from wastewater, Chemical Engineering Journal, 132, 299-309, 2007.
  • Ding, S., Sun, Y., Yang, C. and Xu, B. ‘Removal of copper from aqueous solutions by bentonites and the factors affecting it.’ Mining Science and Technology, 19, 489-492, 2009.
  • Demirbaş, Ö., Karadağ, A., Alkan, M. ve Doğan, M. ‘Removal of copper ions from aqueous solutions by hazelnut shell’, Journal of Hazardous Materials, 153, 677-684, 2008.
  • Singh, V., Pandey, S., Singh, S. K. and Sanghi, R.’ Removal of cadmium from aqueous solutions by adsorption using poly (acyrlamide) modified guar gum- silica nanocomposites.’ Seperation and Purification Technology, 67, 251-261, 2009.
  • Akar, S.T. ve Uysal, R.’Untreated clay with high adsorption capacity for effective removal of C.I. Acid Red 88 from aqueous solutions: Batch and dynamic flow mode studies’ Chemical Engineering Journal, 162, 591- 598, 2010.
There are 32 citations in total.

Details

Other ID JA82BF33SE
Journal Section Article
Authors

Murat Topal This is me

E. İşıl Arslan Topal This is me

Sibel Aslan This is me

Publication Date June 1, 2011
Published in Issue Year 2011 Volume: 27 Issue: 3

Cite

APA Topal, M., Arslan Topal, E. İ., & Aslan, S. (2011). Limon kabuğu kullanarak sulu çözeltilerden Cu(II) giderimi. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi, 27(3), 265-270.
AMA Topal M, Arslan Topal Eİ, Aslan S. Limon kabuğu kullanarak sulu çözeltilerden Cu(II) giderimi. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi. June 2011;27(3):265-270.
Chicago Topal, Murat, E. İşıl Arslan Topal, and Sibel Aslan. “Limon kabuğu Kullanarak Sulu çözeltilerden Cu(II) Giderimi”. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi 27, no. 3 (June 2011): 265-70.
EndNote Topal M, Arslan Topal Eİ, Aslan S (June 1, 2011) Limon kabuğu kullanarak sulu çözeltilerden Cu(II) giderimi. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi 27 3 265–270.
IEEE M. Topal, E. İ. Arslan Topal, and S. Aslan, “Limon kabuğu kullanarak sulu çözeltilerden Cu(II) giderimi”, Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi, vol. 27, no. 3, pp. 265–270, 2011.
ISNAD Topal, Murat et al. “Limon kabuğu Kullanarak Sulu çözeltilerden Cu(II) Giderimi”. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi 27/3 (June 2011), 265-270.
JAMA Topal M, Arslan Topal Eİ, Aslan S. Limon kabuğu kullanarak sulu çözeltilerden Cu(II) giderimi. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi. 2011;27:265–270.
MLA Topal, Murat et al. “Limon kabuğu Kullanarak Sulu çözeltilerden Cu(II) Giderimi”. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi, vol. 27, no. 3, 2011, pp. 265-70.
Vancouver Topal M, Arslan Topal Eİ, Aslan S. Limon kabuğu kullanarak sulu çözeltilerden Cu(II) giderimi. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi. 2011;27(3):265-70.

✯ Etik kurul izni gerektiren, tüm bilim dallarında yapılan araştırmalar için etik kurul onayı alınmış olmalı, bu onay makalede belirtilmeli ve belgelendirilmelidir.
✯ Etik kurul izni gerektiren araştırmalarda, izinle ilgili bilgilere (kurul adı, tarih ve sayı no) yöntem bölümünde, ayrıca makalenin ilk/son sayfalarından birinde; olgu sunumlarında, bilgilendirilmiş gönüllü olur/onam formunun imzalatıldığına dair bilgiye makalede yer verilmelidir.
✯ Dergi web sayfasında, makalelerde Araştırma ve Yayın Etiğine uyulduğuna dair ifadeye yer verilmelidir.
✯ Dergi web sayfasında, hakem, yazar ve editör için ayrı başlıklar altında etik kurallarla ilgili bilgi verilmelidir.
✯ Dergide ve/veya web sayfasında, ulusal ve uluslararası standartlara atıf yaparak, dergide ve/veya web sayfasında etik ilkeler ayrı başlık altında belirtilmelidir. Örneğin; dergilere gönderilen bilimsel yazılarda, ICMJE (International Committee of Medical Journal Editors) tavsiyeleri ile COPE (Committee on Publication Ethics)’un Editör ve Yazarlar için Uluslararası Standartları dikkate alınmalıdır.
✯ Kullanılan fikir ve sanat eserleri için telif hakları düzenlemelerine riayet edilmesi gerekmektedir.