Remazol black 5 boyasının Allium scorodoprasum L. biyokütlesi ile biyolojik olarak uzaklaştırılması; biyosorpsiyon izotermleri, kinetik ve termodinamik çalışmalar

Year 2023, Volume: 39 Issue: 2, 223 - 234, 31.08.2023

Dilek Şenol Arslan

Abstract

Öz: Bu çalışma, Allium scorodoprasum L. biyokütlesini Remazol black 5 (RB5) boyasının sulu çözeltilerden biyo-giderimi için bir adsorban olarak kullanmayı amaçlamaktadır. Allium scorodoprasum L. biyosorbentinin RB5'e bağlanma kapasitesi, kesikli yürütülen adsorpsiyon çalışmlarında pH, RB5 boya konsantrasyonu, temas süresi ve sıcaklıktaki değişimler kaydedilerek araştırılmıştır Deneysel verileri açıklamak için Dubinin-Radushkevich (D-R), Freundlich ve Langmuir izoterm modelleri kullanılmıştır. Biyosorbentin maksimum RB5 boya biyosorpsiyon kapasitesi 25 oC'de 19,8 mg g-1 olarak bulunmuştur. Ortalama biyosorpsiyonsuz enerji, biyosorpsiyon olayının kimyasal reaksiyonla gerçekleştiğini ve sırasıyla PFO ve IPD hız kinetiğini takip ettiğini göstermiştir. Sonuç olarak, termodinamik adsorpsiyon çalışmaları RB5 boya biyosorpsiyonunun hem endotermik hem de spontane olduğunu göstermiştir. Allium scorodoprasum L. anyonik RB5 boyası için önemli bir adsorpsiyon kapasitesine sahiptir.
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Keywords

Biyosorpsiyon, izoterm, kinetik, termodinamik

Bioremoval of Remazol black 5 dye by Allium scorodoprasum L. biomass; biosorption isotherms, kinetic and thermodynamic studies

Abstract

The current study aims to use Allium scorodoprasum L. biomass as an adsorbent for the bioremoval of Remazol black 5 (RB5) dye from aqueous solutions. The binding capacity of Allium scorodoprasum L. biosorbent to RB5 was investigated by recording the changes in pH, concentration of RB5 dye, temperature and contact time in batch aqueous solutions. Dubinin-Radushkevich (D-R), Freundlich, and Langmuir isotherm models were used to explain the experimental data. The maximum RB5 dye biosorption capacity of the biosorbent was found to be 19.8 mg g-1 at 25 oC. The average biosorption-free energy indicated that the biosorption event took place by chemical reaction and that it followed the PFO and IPD rate kinetics, respectively. Finally, thermodynamic adsorption studies indicated that the RB5 dye biosorption was both endothermic and spontaneous. The Allium scorodoprasum L. had a significant adsorption capacity for the anionic RB5 dye.

Keywords

biosorption, isotherm, kinetic, thermodynamic

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