Benzene, toluene, ethylbenzene, and xylenes surrounding a crude oil production plant: Concentrations, health risks, and ozone formation potentials
Abstract
The global economy relies heavily on crude oil as a primary source of energy and a key component in the production of many everyday products. However, the production of crude oil can release BTEX (benzene, toluene, ethylbenzene, and xylenes) into the atmosphere, thereby contributing to air pollution and negatively affecting the health of oil workers. To improve the understanding of BTEX pollution in the vicinity of a crude oil production plant, this study examines the concentrations, health risks, and ozone formation potential of BTEX in a crude oil production plant located in Diyarbakır, Türkiye. The research employed passive samplers and chromatographic analysis to collect and analyze BTEX samples, revealing concentrations that ranged from 3.46 to 30.06 μg/m3. Statistical analysis revealed higher concentrations of BTEX within the plant perimeter in comparison to the surrounding area, indicating the plant as a primary source of these compounds in the region. Among BTEX, toluene was identified as the dominant compound, as observed in some studies conducted in areas with heavy traffic and industrial activity. The health risk assessment indicates that the inhalation of BTEX poses negligible cancer and non-cancer risks for oil workers. Additionally, the ozone formation potential of BTEX in the Diyarbakır Plant is found to be 56.8 μg/m3, which is generally lower than the values reported in the relevant literature. Overall, the findings suggest that monitoring and reducing emissions from crude oil production is vital for the protection of air quality and the occupational health of workers.
Keywords
Supporting Institution
Turkish Petroleum Corporation
Ethical Statement
Not applicable.
Thanks
We thank the Turkish Petroleum Corporation for financial support and access to its facilities for this study.
References
- K. Saarela, T. Tirkkonen, J. Laine-Ylijoki, J. Jurvelin, M. J. Nieuwenhuijsen, and M. Jantunen, “Exposure of population and microenvironmental distributions of volatile organic compound concentrations in the EXPOLIS study,” Atmospheric Environment, Vol. 37(39-40), pp. 5563-5575, 2003.
- A. Zalel, and D. M. Broday, “Revealing source signatures in ambient BTEX concentrations,” Environmental pollution, Vol. 156(2), pp. 553-562, 2008.
- X. Duan, and Y. Li, “Sources and fates of BTEX in the general environment and its distribution in coastal cities of China,” Journal of Environmental Science and Public Health, Vol. 1(2), pp. 86-106, 2017.
- U.S. Environmental Protection Agency. (2003). National emission standards for hazardous air pollutants: Municipal solid waste landfills. Office of Air Quality Planning and Standards, Report 68/FR/2227, Washington, DC. https://www.epa.gov/stationary-sources-air-pollution/municipal-solid-waste-landfills-national-emission-standards.
- B. Caliskan, G. Artun, H. Durmuş, E. O. Gaga, and S. S. Cindoruk, “Atmospheric volatile organic compounds levels in furniture-manufacturing city in Turkey,” Urban Climate, Vol. 43, pp. 101163-101177, 2022.
- L. Tohid, Z. Sabeti, P. Sarbakhsh, K. Z. Benis, M. Shakerkhatibi, Y. Rasoulzadeh, R. Rahimian, and S. Darvishali, “Spatiotemporal variation, ozone formation potential and health risk assessment of ambient air VOCs in an industrialized city in Iran,” Atmospheric Pollution Research, Vol. 10(2), pp. 556-563, 2019.
- Y. Hajizadeh, M. Mokhtari, M. Faraji, A. Mohammadi, S. Nemati, R. Ghanbari, A. Abdolahnejad, R. F. Fard, A. Nikoonahad, N. Jafari, M. Miri, “Trends of BTEX in the central urban area of Iran: A preliminary study of photochemical ozone pollution and health risk assessment,” Atmospheric Pollution Research, Vol. 9(2), pp. 220-229, 2018.
- A. Kumar, D. Singh, K. Kumar, B. B. Singh, and V. K. Jain, “Distribution of VOCs in urban and rural atmospheres of subtropical India: Temporal variation, source attribution, ratios, OFP and risk assessment,” Science of the Total Environment, Vol. 613, pp. 492-501, 2018.
Details
Primary Language
English
Subjects
Environmental Health, Air Pollution Processes and Air Quality Measurement
Journal Section
Research Article
Authors
Early Pub Date
November 18, 2025
Publication Date
December 31, 2025
Submission Date
December 21, 2024
Acceptance Date
January 29, 2025
Published in Issue
Year 2025 Volume: 8 Number: 4
APA
Koçak, T. K. (2025). Benzene, toluene, ethylbenzene, and xylenes surrounding a crude oil production plant: Concentrations, health risks, and ozone formation potentials. Environmental Research and Technology, 8(4), 996-1006. https://doi.org/10.35208/ert.1605266
AMA
1.Koçak TK. Benzene, toluene, ethylbenzene, and xylenes surrounding a crude oil production plant: Concentrations, health risks, and ozone formation potentials. ERT. 2025;8(4):996-1006. doi:10.35208/ert.1605266
Chicago
Koçak, Talha Kemal. 2025. “Benzene, Toluene, Ethylbenzene, and Xylenes Surrounding a Crude Oil Production Plant: Concentrations, Health Risks, and Ozone Formation Potentials”. Environmental Research and Technology 8 (4): 996-1006. https://doi.org/10.35208/ert.1605266.
EndNote
Koçak TK (December 1, 2025) Benzene, toluene, ethylbenzene, and xylenes surrounding a crude oil production plant: Concentrations, health risks, and ozone formation potentials. Environmental Research and Technology 8 4 996–1006.
IEEE
[1]T. K. Koçak, “Benzene, toluene, ethylbenzene, and xylenes surrounding a crude oil production plant: Concentrations, health risks, and ozone formation potentials”, ERT, vol. 8, no. 4, pp. 996–1006, Dec. 2025, doi: 10.35208/ert.1605266.
ISNAD
Koçak, Talha Kemal. “Benzene, Toluene, Ethylbenzene, and Xylenes Surrounding a Crude Oil Production Plant: Concentrations, Health Risks, and Ozone Formation Potentials”. Environmental Research and Technology 8/4 (December 1, 2025): 996-1006. https://doi.org/10.35208/ert.1605266.
JAMA
1.Koçak TK. Benzene, toluene, ethylbenzene, and xylenes surrounding a crude oil production plant: Concentrations, health risks, and ozone formation potentials. ERT. 2025;8:996–1006.
MLA
Koçak, Talha Kemal. “Benzene, Toluene, Ethylbenzene, and Xylenes Surrounding a Crude Oil Production Plant: Concentrations, Health Risks, and Ozone Formation Potentials”. Environmental Research and Technology, vol. 8, no. 4, Dec. 2025, pp. 996-1006, doi:10.35208/ert.1605266.
Vancouver
1.Talha Kemal Koçak. Benzene, toluene, ethylbenzene, and xylenes surrounding a crude oil production plant: Concentrations, health risks, and ozone formation potentials. ERT. 2025 Dec. 1;8(4):996-1006. doi:10.35208/ert.1605266